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Timestamp:
Mar 11, 2020 4:06:51 AM (3 years ago)
Author:
vondreele
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Tutorials/RMCProfile-I
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  • Tutorials/RMCProfile-I/RMCProfile-I.htm

    r4296 r4357  
    2323  <o:Author>vondreele</o:Author>
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    12121212<div class=WordSection1>
    12131213
    1214 <h1><span class=SpellE><span style='mso-fareast-font-family:"Times New Roman"'>RMCProfile</span></span><span
    1215 style='mso-fareast-font-family:"Times New Roman"'> – I<o:p></o:p></span></h1>
     1214<h1><span style='mso-fareast-font-family:"Times New Roman"'>RMCProfile – I<o:p></o:p></span></h1>
    12161215
    12171216<h2><span style='mso-fareast-font-family:"Times New Roman"'>Introduction<o:p></o:p></span></h2>
    … …  
    12191218<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>In
    12201219this and subsequent tutorials, we will show how to use GSAS-II in conjunction
    1221 with <span class=SpellE>RMCProfile</span> (“<span class=SpellE>RMCProfile</span>:
    1222 Reverse Monte Carlo for polycrystalline materials”, M.G. Tucker, D.A. Keen,
    1223 M.T. Dove, A.L. Goodwin and Q. Hui, (2007) Jour. Phys.: Cond. Matter, <b
    1224 style='mso-bidi-font-weight:normal'>19</b>, 335218. <span class=SpellE>doi</span>:
    1225 <a href="https://doi.org/10.1088/0953-8984/19/33/335218">https://doi.org/10.1088/0953-8984/19/33/335218</a>)
     1220with RMCProfile (“RMCProfile: Reverse Monte Carlo for polycrystalline
     1221materials”, M.G. Tucker, D.A. Keen, M.T. Dove, A.L. Goodwin and Q. Hui, (2007)
     1222Jour. Phys.: Cond. Matter, <b style='mso-bidi-font-weight:normal'>19</b>,
     1223335218. <span class=SpellE>doi</span>: <a
     1224href="https://doi.org/10.1088/0953-8984/19/33/335218">https://doi.org/10.1088/0953-8984/19/33/335218</a>)
    12261225to fit both powder diffraction data and a pair distribution function (PDF)
    12271226created from it with a “big box” disordered model. <o:p></o:p></span></p>
    … …  
    12301229
    12311230<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>Before
    1232 getting started you must obtain the most recent Version 6 of the <span
    1233 class=SpellE>RMCProfile</span> executable (at this writing this is <span
    1234 class=SpellE>RMCProfile</span> V6.7.6 Beta Serial). Obtain this from <a
    1235 href="http://www.rmcprofile.org">www.rmcprofile.org</a> by following the
    1236 prompts from Downloads. This version is available for Windows, Mac OSX and
     1231getting started you must obtain the most recent Version 6 of the RMCProfile
     1232executable (at this writing this is RMCProfile V6.7.6 Beta Serial). Obtain this
     1233from <a href="http://www.rmcprofile.org">www.rmcprofile.org</a> by following
     1234the prompts from Downloads. This version is available for Windows, Mac OSX and
    12371235Linux. The download will be a zip file; save it somewhere convenient. Pull from
    12381236it only the </span><span class=SpellE><span class=SubtitleChar><span
    … …  
    12411239style='mso-fareast-font-family:"Times New Roman"'> and place it in the GSASII
    12421240main directory or in a new subdirectory (e.g. </span><span class=SubtitleChar><span
    1243 style='font-size:11.0pt'>GSASII/<span class=SpellE>RMCProfile</span></span></span><span
    1244 style='mso-fareast-font-family:"Times New Roman"'>); no other files are needed
    1245 although you may wish to also retrieve the contents of the tutorial
    1246 subdirectory. It contains </span><span class=SubtitleChar><span
    1247 style='font-size:11.0pt'>rmcprofilemanual.pdf</span></span><span
     1241style='font-size:11.0pt'>GSASII/RMCProfile</span></span><span style='mso-fareast-font-family:
     1242"Times New Roman"'>); no other files are needed although you may wish to also
     1243retrieve the contents of the tutorial subdirectory. It contains </span><span
     1244class=SubtitleChar><span style='font-size:11.0pt'>rmcprofilemanual.pdf</span></span><span
    12481245style='mso-fareast-font-family:"Times New Roman"'> and </span><span
    12491246class=SubtitleChar><span style='font-size:11.0pt'>rmcprofile_tutorial.pdf</span></span><span
    12501247style='mso-fareast-font-family:"Times New Roman"'> which may be of interest
    1251 since the GSAS-II/<span class=SpellE>RMCProfile</span> tutorials are based on
    1252 the latter.<o:p></o:p></span></p>
     1248since the GSAS-II/RMCProfile tutorials are based on the latter.<o:p></o:p></span></p>
    12531249
    12541250<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'><o:p>&nbsp;</o:p></span></p>
    12551251
    12561252<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The
    1257 process for using <span class=SpellE>RMCProfile</span> begins with a normal
    1258 Rietveld refinement of the average structure. For the kind of disordered
    1259 materials of interest here, this may give bond lengths that are frequently too
    1260 short for the atoms involved and sometimes extreme apparent thermal motion for
    1261 some of the atoms. These effects arise because the average structure places
    1262 these atoms too close to one another; a more localized view would show
    1263 coordinated atom displacements or reorientation of groups of atoms to avoid the
    1264 close contacts. <span class=SpellE>RMCProfile</span> is then used to
    1265 characterize these local displacements by fitting to the diffraction data and
    1266 its Fourier transform as a PDF.<o:p></o:p></span></p>
     1253process for using RMCProfile begins with a normal Rietveld refinement of the
     1254average structure. For the kind of disordered materials of interest here, this
     1255may give bond lengths that are frequently too short for the atoms involved and
     1256sometimes extreme apparent thermal motion for some of the atoms. These effects
     1257arise because the average structure places these atoms too close to one
     1258another; a more localized view would show coordinated atom displacements or
     1259reorientation of groups of atoms to avoid the close contacts. RMCProfile is
     1260then used to characterize these local displacements by fitting to the
     1261diffraction data and its Fourier transform as a PDF.<o:p></o:p></span></p>
    12671262
    12681263<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'><o:p>&nbsp;</o:p></span></p>
    12691264
    12701265<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The
    1271 material used in this tutorial is the same as described in the <span
    1272 class=SpellE>RMCProfile</span> tutorial Exercises 1-3, sulfur hexafluoride (SF<sub>6</sub>).
    1273 The average structure of SF<sub>6 </sub>is a molecular crystal at low
    1274 temperatures with the SF<sub>6 </sub>octahedra arranged in a body centered cubic
    1275 lattice with the S-F bonds aligned with the crystal axes. The structural
    1276 frustration induced by close F-F contacts forces the octahedra to locally
    1277 rotate in different directions and this disorder gives rise to considerable
    1278 diffuse scattering. The data used here was obtained at 190K on the GEM
    1279 diffractometer at ISIS, Rutherford-Appleton Laboratory, <span class=GramE>Harwell</span>
    1280 Campus, UK.<o:p></o:p></span></p>
     1266material used in this tutorial is the same as described in the RMCProfile
     1267tutorial Exercises 1-3, sulfur hexafluoride (SF<sub>6</sub>). The average
     1268structure of SF<sub>6 </sub>is a molecular crystal at low temperatures with the
     1269SF<sub>6 </sub>octahedra arranged in a body centered cubic lattice with the S-F
     1270bonds aligned with the crystal axes. The structural frustration induced by
     1271close F-F contacts forces the octahedra to locally rotate in different
     1272directions and this disorder gives rise to considerable diffuse scattering. The
     1273data used here was obtained at 190K on the GEM diffractometer at ISIS,
     1274Rutherford-Appleton Laboratory, <span class=GramE>Harwell</span> Campus, UK.<o:p></o:p></span></p>
    12811275
    12821276<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'><o:p>&nbsp;</o:p></span></p>
    … …  
    13101304style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    13111305mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>xye</span></b></span>
    1312 format (angles in degrees) used by <span class=SpellE>topas</span>, etc. to see
    1313 them. Because you used <span style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:
    1314 minor-latin'>the </span><b style='mso-bidi-font-weight:normal'><span
    1315 style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    1316 mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:
    1317 minor-latin'>Help/Download tutorial</span></b><span style='mso-fareast-font-family:
    1318 Calibri;mso-fareast-theme-font:minor-latin'> menu entry to open this page and
    1319 downloaded the exercise files (recommended), then the </span><span
    1320 class=SpellE><b style='mso-bidi-font-weight:normal'><span style='font-family:
     1306format to see them. Because you used <span style='mso-fareast-font-family:Calibri;
     1307mso-fareast-theme-font:minor-latin'>the </span><b style='mso-bidi-font-weight:
     1308normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
     1309minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;
     1310mso-hansi-theme-font:minor-latin'>Help/Download tutorial</span></b><span
     1311style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'>
     1312menu entry to open this page and downloaded the exercise files (recommended),
     1313then the </span><b style='mso-bidi-font-weight:normal'><span style='font-family:
    13211314"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-fareast-font-family:
    1322 Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin'>RMCProfile</span></b></span><b
    1323 style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    1324 mso-ascii-theme-font:minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:
    1325 minor-latin;mso-hansi-theme-font:minor-latin'>-I/data/...</span></b><span
     1315Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin'>RMCProfile-I/data/...</span></b><span
    13261316style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'>
    13271317entry will bring you to the location where the files have been downloaded. (It
    … …  
    13871377 <v:imagedata src="RMCProfile-I_files/image001.png" o:title=""/>
    13881378</v:shape><![endif]--><![if !vml]><img border=0 width=241 height=303
    1389 src="RMCProfile-I_files/image068.gif" v:shapes="Picture_x0020_1"><![endif]></span><span
     1379src="RMCProfile-I_files/image002.gif" v:shapes="Picture_x0020_1"><![endif]></span><span
    13901380style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    13911381
    … …  
    14051395<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    14061396mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_2" o:spid="_x0000_i1065"
    1407  type="#_x0000_t75" style='width:287.25pt;height:262.5pt;visibility:visible;
     1397 type="#_x0000_t75" style='width:287.25pt;height:263.25pt;visibility:visible;
    14081398 mso-wrap-style:square'>
    14091399 <v:imagedata src="RMCProfile-I_files/image003.png" o:title=""/>
    1410 </v:shape><![endif]--><![if !vml]><img border=0 width=383 height=350
    1411 src="RMCProfile-I_files/image069.gif" v:shapes="Picture_x0020_2"><![endif]></span><span
     1400</v:shape><![endif]--><![if !vml]><img border=0 width=383 height=351
     1401src="RMCProfile-I_files/image004.gif" v:shapes="Picture_x0020_2"><![endif]></span><span
    14121402style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    14131403
    … …  
    14331423 <v:imagedata src="RMCProfile-I_files/image005.png" o:title=""/>
    14341424</v:shape><![endif]--><![if !vml]><img border=0 width=384 height=179
    1435 src="RMCProfile-I_files/image070.gif" v:shapes="Picture_x0020_3"><![endif]></span><span
     1425src="RMCProfile-I_files/image006.gif" v:shapes="Picture_x0020_3"><![endif]></span><span
    14361426style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    14371427
    … …  
    14651455style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'>
    14661456menu entry to open this page and downloaded the exercise files (recommended),
    1467 then the </span><span class=SpellE><b style='mso-bidi-font-weight:normal'><span
    1468 style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    1469 mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:
    1470 minor-latin'>RMCProfile</span></b></span><b style='mso-bidi-font-weight:normal'><span
    1471 style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    1472 mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:
    1473 minor-latin'>-I/data/...</span></b><span style='mso-fareast-font-family:Calibri;
    1474 mso-fareast-theme-font:minor-latin'> entry will bring you to the location where
    1475 the files have been downloaded. (It is also possible to download them manually
    1476 from <a
     1457then the </span><b style='mso-bidi-font-weight:normal'><span style='font-family:
     1458"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-fareast-font-family:
     1459Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin'>RMCProfile-I/data/...</span></b><span
     1460style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'>
     1461entry will bring you to the location where the files have been downloaded. (It
     1462is also possible to download them manually from <a
    14771463href="https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/RMCProfile-I/data/">https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/RMCProfile-I/data/</a>.
    14781464In this case you will need to navigate to the download location manually.)
    … …  
    14811467mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:
    14821468minor-latin;mso-bidi-theme-font:minor-latin'>SF6_190K.EXP</span></b><span
    1483 style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'> file
    1484 (only one there) </span>There will be a Dialog box asking <span class=GramE><b
     1469style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'>
     1470file (only one there) </span>There will be a Dialog box asking <span
     1471class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family:
     1472"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:
     1473minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b
    14851474style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    14861475mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:
    1487 minor-latin'>Is</span></b></span><b style='mso-bidi-font-weight:normal'><span
    1488 style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    1489 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'> this the
    1490 file you want?</span></b> Press <span class=GramE><b style='mso-bidi-font-weight:
    1491 normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
    1492 minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Yes</span></b></span>
    1493 button to proceed. You will get the opportunity to change the phase name next
    1494 (I left it alone; NB: because of restrictions in <span class=SpellE>RMCProfile</span>
    1495 it is important that the phase name not have any spaces); press <b
     1476minor-latin'> this the file you want?</span></b> Press <span class=GramE><b
    14961477style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    14971478mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:
    1498 minor-latin'>OK</span></b> to continue. Next is the histogram selection window;
    1499 this connects the phase to the data so it can be used in subsequent
    1500 calculations.</p>
     1479minor-latin'>Yes</span></b></span> button to proceed. You will get the
     1480opportunity to change the phase name next (I left it alone; NB: because of
     1481restrictions in RMCProfile it is important that the phase name not have any
     1482spaces); press <b style='mso-bidi-font-weight:normal'><span style='font-family:
     1483"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:
     1484minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> to continue. Next is
     1485the histogram selection window; this connects the phase to the data so it can
     1486be used in subsequent calculations.</p>
    15011487
    15021488<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    … …  
    15061492 <v:imagedata src="RMCProfile-I_files/image007.png" o:title=""/>
    15071493</v:shape><![endif]--><![if !vml]><img border=0 width=241 height=193
    1508 src="RMCProfile-I_files/image071.gif" v:shapes="Picture_x0020_4"><![endif]></span><span
     1494src="RMCProfile-I_files/image008.gif" v:shapes="Picture_x0020_4"><![endif]></span><span
    15091495style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    15101496
    … …  
    15231509 <v:imagedata src="RMCProfile-I_files/image009.png" o:title=""/>
    15241510</v:shape><![endif]--><![if !vml]><img border=0 width=482 height=254
    1525 src="RMCProfile-I_files/image072.gif" v:shapes="Picture_x0020_5"><![endif]></span><span
     1511src="RMCProfile-I_files/image010.gif" v:shapes="Picture_x0020_5"><![endif]></span><span
    15261512style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    15271513
    … …  
    15441530 <v:imagedata src="RMCProfile-I_files/image011.png" o:title=""/>
    15451531</v:shape><![endif]--><![if !vml]><img border=0 width=482 height=252
    1546 src="RMCProfile-I_files/image073.gif" v:shapes="Picture_x0020_6"><![endif]></span><span
     1532src="RMCProfile-I_files/image012.gif" v:shapes="Picture_x0020_6"><![endif]></span><span
    15471533style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    15481534
    15491535<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>Be
    1550 sure that “chebyschev-1” is used for the background function; <span
    1551 class=SpellE>RMCProfile</span> only recognizes that form to compute the
    1552 background for the diffraction pattern. Select </span><b style='mso-bidi-font-weight:
    1553 normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
    1554 minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
    1555 minor-latin;mso-bidi-theme-font:minor-latin'>15</span></b><span
     1536sure that “chebyschev-1” is used for the background function; RMCProfile only
     1537recognizes that form to compute the background for the diffraction pattern.
     1538Select </span><b style='mso-bidi-font-weight:normal'><span style='font-family:
     1539"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-fareast-font-family:
     1540"Times New Roman";mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>15</span></b><span
    15561541style='mso-fareast-font-family:"Times New Roman"'> for the number of terms.<o:p></o:p></span></p>
    15571542
    … …  
    15701555mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:minor-latin;
    15711556mso-bidi-theme-font:minor-latin'>SF6_190K</span></b><span style='mso-fareast-font-family:
    1572 "Times New Roman"'>”; do not use the phase name for this purpose because <span
    1573 class=SpellE>RMCProfile</span> will use that as the root for the many files it
    1574 creates. Also, you should create a new directory for this exercise while in
    1575 this dialog box; it will be rapidly filled up with <span class=SpellE>RMCProfile</span>
    1576 files which can lead to considerable confusion if mixed in with other files.
    1577 For Windows after navigating to a suitable location, a new directory can be
    1578 made by a right mouse click and selecting “</span><b style='mso-bidi-font-weight:
     1557"Times New Roman"'>”; do not use the phase name for this purpose because
     1558RMCProfile will use that as the root for the many files it creates. Also, you
     1559should create a new directory for this exercise while in this dialog box; it
     1560will be rapidly filled up with RMCProfile files which can lead to considerable
     1561confusion if mixed in with other files. For Windows after navigating to a
     1562suitable location, a new directory can be made by a right mouse click and
     1563selecting “</span><b style='mso-bidi-font-weight:normal'><span
     1564style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
     1565mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:minor-latin;
     1566mso-bidi-theme-font:minor-latin'>New/Folder</span></b><span style='mso-fareast-font-family:
     1567"Times New Roman"'>” from the popup menu. It will appear with the name “New
     1568Folder”; change the name and select it (it will be empty). Other operating
     1569systems will have similar methods. Finally press </span><b style='mso-bidi-font-weight:
    15791570normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
    15801571minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
    1581 minor-latin;mso-bidi-theme-font:minor-latin'>New/Folder</span></b><span
    1582 style='mso-fareast-font-family:"Times New Roman"'>” from the popup menu. It
    1583 will appear with the name “New Folder”; change the name and select it (it will
    1584 be empty). Other operating systems will have similar methods. Finally press </span><b
    1585 style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    1586 mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    1587 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b><span
     1572minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b><span
    15881573style='mso-fareast-font-family:"Times New Roman"'> to save the GSAS-II project
    15891574(SF6_190K.gpx) and start the refinement. It will quickly converge to give a
    … …  
    15931578<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    15941579mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_7" o:spid="_x0000_i1060"
    1595  type="#_x0000_t75" style='width:288.75pt;height:263.25pt;visibility:visible;
     1580 type="#_x0000_t75" style='width:4in;height:263.25pt;visibility:visible;
    15961581 mso-wrap-style:square'>
    15971582 <v:imagedata src="RMCProfile-I_files/image013.png" o:title=""/>
    1598 </v:shape><![endif]--><![if !vml]><img border=0 width=385 height=351
    1599 src="RMCProfile-I_files/image074.gif" v:shapes="Picture_x0020_7"><![endif]></span><span
     1583</v:shape><![endif]--><![if !vml]><img border=0 width=384 height=351
     1584src="RMCProfile-I_files/image014.gif" v:shapes="Picture_x0020_7"><![endif]></span><span
    16001585style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    16011586
    … …  
    16181603<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    16191604mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_9" o:spid="_x0000_i1059"
    1620  type="#_x0000_t75" style='width:288.75pt;height:263.25pt;visibility:visible;
     1605 type="#_x0000_t75" style='width:4in;height:263.25pt;visibility:visible;
    16211606 mso-wrap-style:square'>
    16221607 <v:imagedata src="RMCProfile-I_files/image015.png" o:title=""/>
    1623 </v:shape><![endif]--><![if !vml]><img border=0 width=385 height=351
    1624 src="RMCProfile-I_files/image075.gif" v:shapes="Picture_x0020_9"><![endif]></span><span
     1608</v:shape><![endif]--><![if !vml]><img border=0 width=384 height=351
     1609src="RMCProfile-I_files/image016.gif" v:shapes="Picture_x0020_9"><![endif]></span><span
    16251610style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    16261611
    … …  
    16911676mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:minor-latin;
    16921677mso-bidi-theme-font:minor-latin'>sig-q</span></b><span style='mso-fareast-font-family:
    1693 "Times New Roman"'> must be zero since <span class=SpellE>RMCProfile</span>
    1694 V6.7.6 Beta Serial does not know how to use them in computing a powder profile.
    1695 <o:p></o:p></span></p>
     1678"Times New Roman"'> must be zero since RMCProfile V6.7.6 Beta Serial does not
     1679know how to use them in computing a powder profile. <o:p></o:p></span></p>
    16961680
    16971681<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>Do </span><b
    … …  
    17181702 <v:imagedata src="RMCProfile-I_files/image017.png" o:title=""/>
    17191703</v:shape><![endif]--><![if !vml]><img border=0 width=477 height=127
    1720 src="RMCProfile-I_files/image076.gif" v:shapes="Picture_x0020_10"><![endif]></span><span
     1704src="RMCProfile-I_files/image018.gif" v:shapes="Picture_x0020_10"><![endif]></span><span
    17211705style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    17221706
    … …  
    17271711 <v:imagedata src="RMCProfile-I_files/image019.png" o:title=""/>
    17281712</v:shape><![endif]--><![if !vml]><img border=0 width=382 height=387
    1729 src="RMCProfile-I_files/image077.gif" v:shapes="Picture_x0020_11"><![endif]></span><span
     1713src="RMCProfile-I_files/image020.gif" v:shapes="Picture_x0020_11"><![endif]></span><span
    17301714style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    17311715
    … …  
    18101794 <v:imagedata src="RMCProfile-I_files/image021.png" o:title=""/>
    18111795</v:shape><![endif]--><![if !vml]><img border=0 width=387 height=391
    1812 src="RMCProfile-I_files/image078.gif" v:shapes="Picture_x0020_12"><![endif]></span><span
     1796src="RMCProfile-I_files/image022.gif" v:shapes="Picture_x0020_12"><![endif]></span><span
    18131797style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    18141798
    … …  
    18161800style='mso-fareast-font-family:"Times New Roman"'> is what one expects for <span
    18171801class=SpellE>orientational</span> disorder for the SF<sub>6</sub> molecules.
    1818 Next we will explore this with <span class=GramE>a</span> <span class=SpellE>RMCProfile</span>
     1802Next we will explore this with <span class=GramE>a</span> RMCProfile
    18191803simulation. To keep this drawing, you may want to save the GSAS-II project.<o:p></o:p></span></p>
    18201804
    … …  
    18221806Simulation of SF<sub>6<o:p></o:p></sub></span></h2>
    18231807
    1824 <p class=MsoNormal><span class=SpellE><span style='mso-fareast-font-family:
    1825 "Times New Roman"'>RMCProfile</span></span><span style='mso-fareast-font-family:
    1826 "Times New Roman"'> is most effective if a large box is used for the modelling;
    1827 this requires very long running times (10-20 <span class=SpellE>hrs</span> for
    1828 SF<sub>6</sub>) before a meaningful result is obtained. However, for the
    1829 purposes of this tutorial, we will be using a small box model that converges in
    1830 a more reasonable time (~10min). The result will clearly fit the data but the
    1831 model is too small to give enough molecular orientations to be meaningful,
    1832 however this exercise will show you how to set up <span class=SpellE>RMCProfile</span>
    1833 from within GSAS-II.<o:p></o:p></span></p>
     1808<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>RMCProfile
     1809is most effective if a large box is used for the modelling; this requires very
     1810long running times (10-20 <span class=SpellE>hrs</span> for SF<sub>6</sub>)
     1811before a meaningful result is obtained. However, for the purposes of this
     1812tutorial, we will be using a smaller big box model that converges in a more
     1813reasonable time (~10min). The result will clearly fit the data but the model is
     1814too small to give enough molecular orientations to be meaningful, however this
     1815exercise will show you how to set up RMCProfile from within GSAS-II.<o:p></o:p></span></p>
    18341816
    18351817<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>To
    … …  
    18471829 <v:imagedata src="RMCProfile-I_files/image023.png" o:title=""/>
    18481830</v:shape><![endif]--><![if !vml]><img border=0 width=479 height=287
    1849 src="RMCProfile-I_files/image079.gif" v:shapes="Picture_x0020_13"><![endif]></span><span
     1831src="RMCProfile-I_files/image024.gif" v:shapes="Picture_x0020_13"><![endif]></span><span
    18501832style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    18511833
    … …  
    18531835
    18541836<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>At
    1855 the top is a radio button selection for </span><span class=SpellE><b
    1856 style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    1857 mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    1858 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>RMCProfile</span></b></span><span
     1837the top is a radio button selection for </span><b style='mso-bidi-font-weight:
     1838normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
     1839minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
     1840minor-latin;mso-bidi-theme-font:minor-latin'>RMCProfile</span></b><span
    18591841style='mso-fareast-font-family:"Times New Roman"'> and </span><span
    18601842class=SpellE><b style='mso-bidi-font-weight:normal'><span style='font-family:
    … …  
    18621844"Times New Roman";mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>fullrmc</span></b></span><span
    18631845style='mso-fareast-font-family:"Times New Roman"'>. The latter is an
    1864 alternative big box modeling program (not working – under development); <span
    1865 class=SpellE>RMCProfile</span> is selected by default and all below are its
    1866 setup controls. There are four major sections (metadata, major controls,
    1867 restraints &amp; constraints and data controls); we will work through each of
    1868 these in turn. The information you enter here is retained in the GSAS-II
    1869 project so you can easily try alternative setups without having to enter
    1870 everything over again. <o:p></o:p></span></p>
     1846alternative big box modeling program (not working – under development);
     1847RMCProfile is selected by default and all below are its setup controls. There
     1848are four major sections (metadata, major controls, restraints &amp; constraints
     1849and data controls); we will work through each of these in turn. The information
     1850you enter here is retained in the GSAS-II project so you can easily try
     1851alternative setups without having to enter everything over again. <o:p></o:p></span></p>
    18711852
    18721853<h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 1. Set
    … …  
    18751856<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The
    18761857entries here are for your convenience; there is no explicit use made of any of
    1877 these, but they will appear in some of the output files from <span
    1878 class=SpellE>RMCProfile</span> and of course will show here on subsequent views
    1879 of this window. Fill out as many of them as you see fit. I entered some things
    1880 for each as the defaults are somewhat nonsensical.<o:p></o:p></span></p>
     1858these, but they will appear in some of the output files from RMCProfile and of
     1859course will show here on subsequent views of this window. Fill out as many of
     1860them as you see fit. I entered some things for each as the defaults are
     1861somewhat nonsensical.<o:p></o:p></span></p>
    18811862
    18821863<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    … …  
    18861867 <v:imagedata src="RMCProfile-I_files/image025.png" o:title=""/>
    18871868</v:shape><![endif]--><![if !vml]><img border=0 width=479 height=288
    1888 src="RMCProfile-I_files/image080.gif" v:shapes="Picture_x0020_14"><![endif]></span><span
     1869src="RMCProfile-I_files/image026.gif" v:shapes="Picture_x0020_14"><![endif]></span><span
    18891870style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    18901871
    … …  
    19021883minor-latin;mso-bidi-theme-font:minor-latin'>1</span></b><span
    19031884style='mso-fareast-font-family:"Times New Roman"'> minute. At each save time a
    1904 number of files are written by <span class=SpellE>RMCProfile</span>; these can
    1905 be viewed by using the Operations/View command (more about this later – don’t
    1906 bother trying it now, there is nothing to see). For the purposes of this
    1907 tutorial leave them at their defaults. <o:p></o:p></span></p>
     1885number of files are written by RMCProfile; these can be viewed by using the
     1886Operations/View command (more about this later – don’t bother trying it now,
     1887there is nothing to see). For the purposes of this tutorial leave them at their
     1888defaults. <o:p></o:p></span></p>
    19081889
    19091890<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The
    1910 big box model used by <span class=SpellE>RMCProfile</span> is described as
    1911 multiples of the unit cell axes. In this case we want a 3x3x3 box so enter </span><b
    1912 style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    1913 mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    1914 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>3</span></b><span
     1891big box model used by RMCProfile is described as multiples of the unit cell
     1892axes. In this case we want a 3x3x3 box so enter </span><b style='mso-bidi-font-weight:
     1893normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
     1894minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
     1895minor-latin;mso-bidi-theme-font:minor-latin'>3</span></b><span
    19151896style='mso-fareast-font-family:"Times New Roman"'> for each of </span><b
    19161897style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    … …  
    19531934 <v:imagedata src="RMCProfile-I_files/image027.png" o:title=""/>
    19541935</v:shape><![endif]--><![if !vml]><img border=0 width=480 height=288
    1955 src="RMCProfile-I_files/image081.gif" v:shapes="Picture_x0020_15"><![endif]></span><span
     1936src="RMCProfile-I_files/image028.gif" v:shapes="Picture_x0020_15"><![endif]></span><span
    19561937style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    19571938
    … …  
    20272008 <v:imagedata src="RMCProfile-I_files/image029.png" o:title=""/>
    20282009</v:shape><![endif]--><![if !vml]><img border=0 width=481 height=289
    2029 src="RMCProfile-I_files/image082.gif" v:shapes="Picture_x0020_16"><![endif]></span><span
     2010src="RMCProfile-I_files/image030.gif" v:shapes="Picture_x0020_16"><![endif]></span><span
    20302011style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    20312012
    … …  
    20372018
    20382019<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>We
    2039 will be using three different types of SF6 data for the fitting by <span
    2040 class=SpellE>RMCProfile</span>. The first is the selection of the powder
    2041 pattern (“Bragg”) for processing. This is taken from the PWDR entries in the
    2042 GSAS-II project and accessed from the pulldown; there is only one “</span><b
    2043 style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    2044 mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    2045 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>PWDR
    2046 sf6_190gsas.dat Bank 3</span></b><span style='mso-fareast-font-family:"Times New Roman"'>”
    2047 that was used earlier in your Rietveld refinement of SF<sub>6</sub>. If you had
    2048 used multiple banks in the Rietveld refinement, all would be shown in the
    2049 pulldown, but only one can be selected. Set the weight to </span><b
    2050 style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    2051 mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    2052 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>0.1</span></b><span
    2053 style='mso-fareast-font-family:"Times New Roman"'> (NB: smaller numbers means a
    2054 heavier weight).<o:p></o:p></span></p>
     2020will be using three different types of SF<sub>6</sub> data for the fitting by
     2021RMCProfile. The first is the selection of the powder pattern (“Bragg”) for
     2022processing. This is taken from the PWDR entries in the GSAS-II project and
     2023accessed from the pulldown; there is only one “</span><b style='mso-bidi-font-weight:
     2024normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
     2025minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
     2026minor-latin;mso-bidi-theme-font:minor-latin'>PWDR sf6_190gsas.dat Bank 3</span></b><span
     2027style='mso-fareast-font-family:"Times New Roman"'>” that was used earlier in
     2028your Rietveld refinement of SF<sub>6</sub>. If you had used multiple banks in
     2029the Rietveld refinement, all would be shown in the pulldown, but only one can
     2030be selected. Set the weight to </span><b style='mso-bidi-font-weight:normal'><span
     2031style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
     2032mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:minor-latin;
     2033mso-bidi-theme-font:minor-latin'>0.1</span></b><span style='mso-fareast-font-family:
     2034"Times New Roman"'> (NB: smaller numbers means a heavier weight).<o:p></o:p></span></p>
    20552035
    20562036<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>Next
    … …  
    20702050style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'>
    20712051menu entry to open this page and downloaded the exercise files (recommended),
    2072 then the </span><span class=SpellE><b style='mso-bidi-font-weight:normal'><span
    2073 style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    2074 mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:
    2075 minor-latin'>RMCProfile</span></b></span><b style='mso-bidi-font-weight:normal'><span
    2076 style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    2077 mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:
    2078 minor-latin'>-I/data/...</span></b><span style='mso-fareast-font-family:Calibri;
    2079 mso-fareast-theme-font:minor-latin'> entry will bring you to the location where
    2080 the files have been downloaded. (It is also possible to download them manually
    2081 from <a
     2052then the </span><b style='mso-bidi-font-weight:normal'><span style='font-family:
     2053"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-fareast-font-family:
     2054Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin'>RMCProfile-I/data/...</span></b><span
     2055style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'>
     2056entry will bring you to the location where the files have been downloaded. (It
     2057is also possible to download them manually from <a
    20822058href="https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/RMCProfile-I/data/">https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/RMCProfile-I/data/</a>.
    20832059In this case you will need to navigate to the download location manually.)<o:p></o:p></span></p>
    … …  
    20882064<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    20892065mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_17" o:spid="_x0000_i1051"
    2090  type="#_x0000_t75" style='width:357.75pt;height:132.75pt;visibility:visible;
     2066 type="#_x0000_t75" style='width:358.5pt;height:132.75pt;visibility:visible;
    20912067 mso-wrap-style:square'>
    20922068 <v:imagedata src="RMCProfile-I_files/image031.png" o:title=""/>
    2093 </v:shape><![endif]--><![if !vml]><img border=0 width=477 height=177
    2094 src="RMCProfile-I_files/image083.gif" v:shapes="Picture_x0020_17"><![endif]></span><span
     2069</v:shape><![endif]--><![if !vml]><img border=0 width=478 height=177
     2070src="RMCProfile-I_files/image032.gif" v:shapes="Picture_x0020_17"><![endif]></span><span
    20952071style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    20962072
    … …  
    21002076mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>sf6_190k_gr.dat</span></b><span
    21012077style='mso-fareast-font-family:"Times New Roman"'>; it will be copied from this
    2102 location to your working directory for this tutorial (<span class=SpellE>RMCProfile</span>
    2103 requires all its files to be local). The window will be redrawn showing the new
    2104 entry; the weight is fine.<o:p></o:p></span></p>
     2078location to your working directory for this tutorial (RMCProfile requires all
     2079its files to be local). The window will be redrawn showing the new entry; the
     2080weight is fine.<o:p></o:p></span></p>
    21052081
    21062082<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    … …  
    21102086 <v:imagedata src="RMCProfile-I_files/image033.png" o:title=""/>
    21112087</v:shape><![endif]--><![if !vml]><img border=0 width=480 height=288
    2112 src="RMCProfile-I_files/image084.gif" v:shapes="Picture_x0020_18"><![endif]></span><span
     2088src="RMCProfile-I_files/image034.gif" v:shapes="Picture_x0020_18"><![endif]></span><span
    21132089style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    21142090
    … …  
    21272103 <v:imagedata src="RMCProfile-I_files/image035.png" o:title=""/>
    21282104</v:shape><![endif]--><![if !vml]><img border=0 width=478 height=178
    2129 src="RMCProfile-I_files/image085.gif" v:shapes="Picture_x0020_19"><![endif]></span><span
     2105src="RMCProfile-I_files/image036.gif" v:shapes="Picture_x0020_19"><![endif]></span><span
    21302106style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    21312107
    … …  
    21432119 <v:imagedata src="RMCProfile-I_files/image037.png" o:title=""/>
    21442120</v:shape><![endif]--><![if !vml]><img border=0 width=483 height=290
    2145 src="RMCProfile-I_files/image086.gif" v:shapes="Picture_x0020_20"><![endif]></span><span
     2121src="RMCProfile-I_files/image038.gif" v:shapes="Picture_x0020_20"><![endif]></span><span
    21462122style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    21472123
    … …  
    21592135 <v:imagedata src="RMCProfile-I_files/image039.png" o:title=""/>
    21602136</v:shape><![endif]--><![if !vml]><img border=0 width=481 height=184
    2161 src="RMCProfile-I_files/image087.gif" v:shapes="Picture_x0020_21"><![endif]></span><span
     2137src="RMCProfile-I_files/image040.gif" v:shapes="Picture_x0020_21"><![endif]></span><span
    21622138style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    21632139
    2164 <h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 5. Setup <span
    2165 class=SpellE>RMCProfile</span> files<o:p></o:p></span></h3>
    2166 
    2167 <p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>You are
    2168 now ready to setup the <span class=SpellE>RMCProfile</span> input files<span
    2169 class=GramE>..</span> Do </span><b style='mso-bidi-font-weight:normal'><span
    2170 style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    2171 mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:minor-latin;
    2172 mso-bidi-theme-font:minor-latin'>Operations/Setup RMC</span></b><span
    2173 style='mso-fareast-font-family:"Times New Roman"'> from the menu; the console
    2174 should report that files were written<o:p></o:p></span></p>
     2140<h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 5. Setup
     2141RMCProfile files<o:p></o:p></span></h3>
     2142
     2143<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>You
     2144are now ready to setup the RMCProfile input files<span class=GramE>..</span> Do
     2145</span><b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
     2146mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
     2147mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Operations/Setup
     2148RMC</span></b><span style='mso-fareast-font-family:"Times New Roman"'> from the
     2149menu; the console should report that files were written<o:p></o:p></span></p>
    21752150
    21762151<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    … …  
    21802155 <v:imagedata src="RMCProfile-I_files/image041.png" o:title=""/>
    21812156</v:shape><![endif]--><![if !vml]><img border=0 width=390 height=174
    2182 src="RMCProfile-I_files/image088.gif" v:shapes="Picture_x0020_23"><![endif]></span><span
     2157src="RMCProfile-I_files/image042.gif" v:shapes="Picture_x0020_23"><![endif]></span><span
    21832158style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    21842159
    … …  
    21932168 <v:imagedata src="RMCProfile-I_files/image043.png" o:title=""/>
    21942169</v:shape><![endif]--><![if !vml]><img border=0 width=482 height=235
    2195 src="RMCProfile-I_files/image089.gif" v:shapes="Picture_x0020_24"><![endif]></span><span
     2170src="RMCProfile-I_files/image044.gif" v:shapes="Picture_x0020_24"><![endif]></span><span
    21962171style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    21972172
    21982173<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>These
    2199 text files contain data needed by <span class=SpellE>RMCProfile</span> for the
    2200 fitting of SF6. They are:<o:p></o:p></span></p>
     2174text files contain data needed by RMCProfile for the fitting of SF6. They are:<o:p></o:p></span></p>
    22012175
    22022176<p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span
    … …  
    22132187<p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span
    22142188style='mso-fareast-font-family:"Times New Roman"'>SF6.dat</span></b><span
    2215 style='mso-fareast-font-family:"Times New Roman"'> – the <span class=SpellE>RMCProfile</span>
    2216 controls file; described in full in the <span class=SpellE>RMCProfile</span>
    2217 User Manual. It can be edited if need be, but remember it is rewritten each
    2218 time Operations/Setup RMC is done.<o:p></o:p></span></p>
     2189style='mso-fareast-font-family:"Times New Roman"'> – the RMCProfile controls
     2190file; described in full in the RMCProfile User Manual. It can be edited if need
     2191be, but remember it is rewritten each time Operations/Setup RMC is done.<o:p></o:p></span></p>
    22192192
    22202193<p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span
    … …  
    22222195style='mso-fareast-font-family:"Times New Roman"'> – the instrument parameter
    22232196coefficients for the neutron TOF peak shape function used by GSAS-II and
    2224 implemented in <span class=SpellE>RMCProfile</span> for computing the Bragg
    2225 pattern.<o:p></o:p></span></p>
     2197implemented in RMCProfile for computing the Bragg pattern.<o:p></o:p></span></p>
    22262198
    22272199<p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span
    … …  
    22312203unless the X-axis, Y-axis, or Z-axis lattice multipliers are changed. Most
    22322204important is that it will contain the set of big box atom positions as updated
    2233 by <span class=SpellE>RMCProfile</span> according to the Save interval (every 1
    2234 min in this case).<o:p></o:p></span></p>
     2205by RMCProfile according to the Save interval (every 1 min in this case).<o:p></o:p></span></p>
    22352206
    22362207<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>You
    2237 are now ready to run <span class=SpellE>RMCProfile</span>.<o:p></o:p></span></p>
    2238 
    2239 <h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 6. Run <span
    2240 class=SpellE>RMCProfile</span><o:p></o:p></span></h3>
     2208are now ready to run RMCProfile.<o:p></o:p></span></p>
     2209
     2210<h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 6. Run
     2211RMCProfile<o:p></o:p></span></h3>
    22412212
    22422213<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>To
    2243 run <span class=SpellE>RMCProfile</span> from inside GSAS-II, do </span><b
     2214run RMCProfile from inside GSAS-II, do </span><b style='mso-bidi-font-weight:
     2215normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
     2216minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
     2217minor-latin;mso-bidi-theme-font:minor-latin'>Operations/Execute</span></b><span
     2218style='mso-fareast-font-family:"Times New Roman"'>. You will first see a “nag”
     2219note asking you to cite the publication describing RMCProfile; press </span><b
    22442220style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    22452221mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    2246 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Operations/Execute</span></b><span
    2247 style='mso-fareast-font-family:"Times New Roman"'>. You will first see a “nag”
    2248 note asking you to cite the publication describing <span class=SpellE>RMCProfile</span>;
    2249 press </span><b style='mso-bidi-font-weight:normal'><span style='font-family:
    2250 "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-fareast-font-family:
    2251 "Times New Roman";mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b><span
     2222mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b><span
    22522223style='mso-fareast-font-family:"Times New Roman"'>.<o:p></o:p></span></p>
    22532224
    … …  
    22572228reports Time used and <span class=GramE>Last</span> saved. Once the latter is
    22582229nonzero you can view intermediate results to see its progress. Note that you
    2259 can exit GSAS-II and <span class=SpellE>RMCProfile</span> will continue
    2260 running. After <span class=SpellE>RMCProfile</span> finishes note that the
    2261 project directory now has ~30 files many of which are just temporary ones
    2262 created by <span class=SpellE>RMCProfile</span>. We will be looking at just the
    2263 *.csv files and the SF6.rmcf6 file; the latter contains the last atom
    2264 configuration acceptable by <span class=SpellE>RMCProfile</span> thus
    2265 representing a best disordered model.<o:p></o:p></span></p>
     2230can exit GSAS-II and RMCProfile will continue running. After RMCProfile
     2231finishes note that the project directory now has ~30 files many of which are
     2232just temporary ones created by RMCProfile. We will be looking at just the *.csv
     2233files and the SF6.rmcf6 file; the latter contains the last atom configuration
     2234acceptable by RMCProfile thus representing a best disordered model.<o:p></o:p></span></p>
    22662235
    22672236<h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 7. Viewing
    2268 results from <span class=SpellE>RMCProfile</span><o:p></o:p></span></h3>
     2237results from RMCProfile<o:p></o:p></span></h3>
    22692238
    22702239<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>Do </span><b
    … …  
    22812250 <v:imagedata src="RMCProfile-I_files/image045.png" o:title=""/>
    22822251</v:shape><![endif]--><![if !vml]><img border=0 width=480 height=178
    2283 src="RMCProfile-I_files/image090.gif" v:shapes="Picture_x0020_25"><![endif]></span><span
     2252src="RMCProfile-I_files/image046.gif" v:shapes="Picture_x0020_25"><![endif]></span><span
    22842253style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    22852254
    … …  
    22882257from the GSAS-II project file. Select any one of them – it doesn’t matter. All
    22892258of them will be read and their contents displayed as individual plots. For
    2290 example the chi^2 plot shows the progress of the <span class=SpellE>RMCProfile</span>
    2291 fit<o:p></o:p></span></p>
     2259example the chi^2 plot shows the progress of the RMCProfile fit<o:p></o:p></span></p>
    22922260
    22932261<p class=MsoNormal><!--[if mso & !supportInlineShapes & supportFields]><span
    … …  
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    … …  
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    … …  
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    … …  
    41964164 <w:anchorlock/>
    41974165</v:group><![endif]--><![if !vml]><img width=384 height=387
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    … …  
    42034171
    42044172<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The
    4205 inset is the upper 3/4ths of the plot magnified; you can see that <span
    4206 class=SpellE>RMCProfile</span> is still improving the fit slowly even after 10
    4207 minutes of running.<o:p></o:p></span></p>
     4173inset is the upper 3/4ths of the plot magnified; you can see that RMCProfile is
     4174still improving the fit slowly even after 10 minutes of running.<o:p></o:p></span></p>
    42084175
    42094176<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    … …  
    42134180 <v:imagedata src="RMCProfile-I_files/image050.png" o:title=""/>
    42144181</v:shape><![endif]--><![if !vml]><img border=0 width=384 height=386
    4215 src="RMCProfile-I_files/image092.gif" v:shapes="Picture_x0020_29"><![endif]></span><span
     4182src="RMCProfile-I_files/image051.gif" v:shapes="Picture_x0020_29"><![endif]></span><span
    42164183style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    42174184
    42184185<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The
    4219 G(R) partials plot shows the identity of each feature; the first 2 sharp peaks arise
    4220 from S-F (1.58Å) and F-F (2.20Å) distances within the SF<sub>6</sub> octahedron
    4221 (cf. 1.457Å and 2.06Å, respectively, for the average structure) while the
    4222 broader one at 2.8-3.1 are from F-F intermolecular contacts.<o:p></o:p></span></p>
     4186G(R) partials plot shows the identity of each feature; the first 2 sharp peaks
     4187arise from S-F (1.58Å) and F-F (2.20Å) distances within the SF<sub>6</sub>
     4188octahedron (cf. 1.457Å and 2.06Å, respectively, for the average structure)
     4189while the broader one at 2.8-3.1 are from F-F intermolecular contacts.<o:p></o:p></span></p>
    42234190
    42244191<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    … …  
    42274194
    42284195<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    4229 mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_31" o:spid="_x0000_i1041"
    4230  type="#_x0000_t75" style='width:287.25pt;height:305.25pt;visibility:visible;
    4231  mso-wrap-style:square'>
     4196mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="_x0000_i1041" type="#_x0000_t75"
     4197 style='width:287.25pt;height:305.25pt;visibility:visible;mso-wrap-style:square'>
    42324198 <v:imagedata src="RMCProfile-I_files/image052.png" o:title=""/>
    42334199</v:shape><![endif]--><![if !vml]><img border=0 width=383 height=407
    4234 src="RMCProfile-I_files/image093.gif" v:shapes="Picture_x0020_31"><![endif]></span><span
     4200src="RMCProfile-I_files/image053.gif" v:shapes="_x0000_i1041"><![endif]></span><span
    42354201style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    42364202
    … …  
    42394205the second frame.<o:p></o:p></span></p>
    42404206
    4241 <h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 8. View the big
    4242 box structural model for SF<sub>6</sub><o:p></o:p></span></h3>
     4207<h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 8. View the
     4208big box structural model for SF<sub>6</sub><o:p></o:p></span></h3>
    42434209
    42444210<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>Next,
    … …  
    42464212normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
    42474213minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
    4248 minor-latin;mso-bidi-theme-font:minor-latin'>Import/Phase/from <span
    4249 class=SpellE>RMCProfile</span> .rmc6f file</span></b><span style='mso-fareast-font-family:
    4250 "Times New Roman"'>; a <span class=SpellE>FileDialog</span> box with one entry
    4251 will show the required file, </span><b style='mso-bidi-font-weight:normal'><span
     4214minor-latin;mso-bidi-theme-font:minor-latin'>Import/Phase/from RMCProfile
     4215.rmc6f file</span></b><span style='mso-fareast-font-family:"Times New Roman"'>;
     4216a <span class=SpellE>FileDialog</span> box with one entry will show the
     4217required file, </span><b style='mso-bidi-font-weight:normal'><span
    42524218style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin;
    42534219mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:minor-latin;
    … …  
    42854251
    42864252<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    4287 mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_32" o:spid="_x0000_i1040"
    4288  type="#_x0000_t75" style='width:358.5pt;height:183pt;visibility:visible;
    4289  mso-wrap-style:square'>
     4253mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="_x0000_i1040" type="#_x0000_t75"
     4254 style='width:358.5pt;height:183pt;visibility:visible;mso-wrap-style:square'>
    42904255 <v:imagedata src="RMCProfile-I_files/image054.png" o:title=""/>
    42914256</v:shape><![endif]--><![if !vml]><img border=0 width=478 height=244
    4292 src="RMCProfile-I_files/image094.gif" v:shapes="Picture_x0020_32"><![endif]></span><span
     4257src="RMCProfile-I_files/image055.gif" v:shapes="_x0000_i1040"><![endif]></span><span
    42934258style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    42944259
    … …  
    43084273style='mso-fareast-font-family:"Times New Roman"'> for them (does take time –
    43094274be patient) and then change all the atoms to ball and stick style. The
    4310 CN-sphere filling works because the <span class=SpellE>RMCProfile</span>
    4311 structure still has translational symmetry across its 3x3x3 lattice. You should
    4312 see something like<o:p></o:p></span></p>
     4275CN-sphere filling works because the RMCProfile structure still has
     4276translational symmetry across its 3x3x3 lattice. You should see something like<o:p></o:p></span></p>
    43134277
    43144278<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    4315 mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_33" o:spid="_x0000_i1039"
    4316  type="#_x0000_t75" style='width:288.75pt;height:306pt;visibility:visible;
    4317  mso-wrap-style:square'>
     4279mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="_x0000_i1039" type="#_x0000_t75"
     4280 style='width:288.75pt;height:306pt;visibility:visible;mso-wrap-style:square'>
    43184281 <v:imagedata src="RMCProfile-I_files/image056.png" o:title=""/>
    43194282</v:shape><![endif]--><![if !vml]><img border=0 width=385 height=408
    4320 src="RMCProfile-I_files/image095.gif" v:shapes="Picture_x0020_33"><![endif]></span><span
     4283src="RMCProfile-I_files/image057.gif" v:shapes="_x0000_i1039"><![endif]></span><span
    43214284style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    43224285
    … …  
    43294292
    43304293<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>NB:
    4331 this import facility can be used to load any rmc6f file, e.g. from a <span
    4332 class=SpellE>RMCProfile</span> run done outside of GSAS-II; all the plotting
    4333 and tools in this and the following steps are available for these big box
    4334 models.<o:p></o:p></span></p>
     4294this import facility can be used to load any rmc6f file, e.g. from a RMCProfile
     4295run done outside of GSAS-II; all the plotting and tools in this and the
     4296following steps are available for these big box models.<o:p></o:p></span></p>
    43354297
    43364298<h3><span style='mso-fareast-font-family:"Times New Roman"'>Step 9. View the
    … …  
    43564318 <v:imagedata src="RMCProfile-I_files/image058.png" o:title=""/>
    43574319</v:shape><![endif]--><![if !vml]><img border=0 width=376 height=430
    4358 src="RMCProfile-I_files/image096.gif" v:shapes="Picture_x0020_34"><![endif]></span><span
     4320src="RMCProfile-I_files/image059.gif" v:shapes="Picture_x0020_34"><![endif]></span><span
    43594321style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    43604322
    43614323<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>This
    4362 is the general tool inside GSAS-II for all sorts of structure transformations.
    4363 Here we will use it to push all the big box atoms back into the average
    4364 structure unit cell. Recalling that the big box model is 3x3x3 the original
    4365 unit cell, we simply want to reverse the process. Enter </span><b
    4366 style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif;
    4367 mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    4368 mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1/3</span></b><span
     4324is the general tool inside GSAS-II for all sorts of structure transformations. Here
     4325we will use it to push all the big box atoms back into the average structure
     4326unit cell. Recalling that the big box model is 3x3x3 the original unit cell, we
     4327simply want to reverse the process. Enter </span><b style='mso-bidi-font-weight:
     4328normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:
     4329minor-latin;mso-fareast-font-family:"Times New Roman";mso-hansi-theme-font:
     4330minor-latin;mso-bidi-theme-font:minor-latin'>1/3</span></b><span
    43694331style='mso-fareast-font-family:"Times New Roman"'> into the diagonal elements
    43704332of the M matrix. The GUI will convert them to the decimal equivalent (0.333
    … …  
    43784340 <v:imagedata src="RMCProfile-I_files/image060.png" o:title=""/>
    43794341</v:shape><![endif]--><![if !vml]><img border=0 width=376 height=430
    4380 src="RMCProfile-I_files/image097.gif" v:shapes="Picture_x0020_35"><![endif]></span><span
     4342src="RMCProfile-I_files/image061.gif" v:shapes="Picture_x0020_35"><![endif]></span><span
    43814343style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    43824344
    … …  
    43954357
    43964358<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    4397 mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="_x0000_i1036" type="#_x0000_t75"
    4398  style='width:286.5pt;height:303.75pt;visibility:visible;mso-wrap-style:square'>
     4359mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_31" o:spid="_x0000_i1036"
     4360 type="#_x0000_t75" style='width:286.5pt;height:303.75pt;visibility:visible;
     4361 mso-wrap-style:square'>
    43994362 <v:imagedata src="RMCProfile-I_files/image062.png" o:title=""/>
    44004363</v:shape><![endif]--><![if !vml]><img border=0 width=382 height=405
    4401 src="RMCProfile-I_files/image098.gif" v:shapes="_x0000_i1036"><![endif]></span><span
     4364src="RMCProfile-I_files/image063.gif" v:shapes="Picture_x0020_31"><![endif]></span><span
    44024365style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    44034366
    … …  
    44184381
    44194382<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    4420 mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="_x0000_i1035" type="#_x0000_t75"
    4421  style='width:286.5pt;height:303.75pt;visibility:visible;mso-wrap-style:square'>
     4383mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_32" o:spid="_x0000_i1035"
     4384 type="#_x0000_t75" style='width:286.5pt;height:303.75pt;visibility:visible;
     4385 mso-wrap-style:square'>
    44224386 <v:imagedata src="RMCProfile-I_files/image064.png" o:title=""/>
    44234387</v:shape><![endif]--><![if !vml]><img border=0 width=382 height=405
    4424 src="RMCProfile-I_files/image099.gif" v:shapes="_x0000_i1035"><![endif]></span><span
     4388src="RMCProfile-I_files/image065.gif" v:shapes="Picture_x0020_32"><![endif]></span><span
    44254389style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    44264390
    … …  
    44304394
    44314395<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    4432 mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="_x0000_i1034" type="#_x0000_t75"
    4433  style='width:4in;height:305.25pt;visibility:visible;mso-wrap-style:square'>
     4396mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_33" o:spid="_x0000_i1034"
     4397 type="#_x0000_t75" style='width:4in;height:305.25pt;visibility:visible;
     4398 mso-wrap-style:square'>
    44344399 <v:imagedata src="RMCProfile-I_files/image066.png" o:title=""/>
    44354400</v:shape><![endif]--><![if !vml]><img border=0 width=384 height=407
    4436 src="RMCProfile-I_files/image100.gif" v:shapes="_x0000_i1034"><![endif]></span><span
     4401src="RMCProfile-I_files/image067.gif" v:shapes="Picture_x0020_33"><![endif]></span><span
    44374402style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    44384403
    … …  
    44584423 <v:imagedata src="RMCProfile-I_files/image101.png" o:title=""/>
    44594424</v:shape><![endif]--><![if !vml]><img border=0 width=479 height=244
    4460 src="RMCProfile-I_files/image102.gif" v:shapes="Picture_x0020_36"><![endif]></span><span
     4425src="RMCProfile-I_files/image119.gif" v:shapes="Picture_x0020_36"><![endif]></span><span
    44614426style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    44624427
    … …  
    44704435 <v:imagedata src="RMCProfile-I_files/image103.png" o:title=""/>
    44714436</v:shape><![endif]--><![if !vml]><img border=0 width=477 height=244
    4472 src="RMCProfile-I_files/image104.gif" v:shapes="Picture_x0020_37"><![endif]></span><span
     4437src="RMCProfile-I_files/image120.gif" v:shapes="Picture_x0020_37"><![endif]></span><span
    44734438style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    44744439
    … …  
    44964461mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman";
    44974462mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Compute/Compare</span></b><span
    4498 style='mso-fareast-font-family:"Times New Roman"'> from the menu; a popup for setting
    4499 Distance Angle Controls will appear<o:p></o:p></span></p>
     4463style='mso-fareast-font-family:"Times New Roman"'> from the menu; a popup for
     4464setting Distance Angle Controls will appear<o:p></o:p></span></p>
    45004465
    45014466<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    … …  
    45054470 <v:imagedata src="RMCProfile-I_files/image105.png" o:title=""/>
    45064471</v:shape><![endif]--><![if !vml]><img border=0 width=275 height=234
    4507 src="RMCProfile-I_files/image106.gif" v:shapes="Picture_x0020_38"><![endif]></span><span
     4472src="RMCProfile-I_files/image121.gif" v:shapes="Picture_x0020_38"><![endif]></span><span
    45084473style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    45094474
    … …  
    45314496 <v:imagedata src="RMCProfile-I_files/image107.png" o:title=""/>
    45324497</v:shape><![endif]--><![if !vml]><img border=0 width=484 height=247
    4533 src="RMCProfile-I_files/image108.gif" v:shapes="Picture_x0020_39"><![endif]></span><span
     4498src="RMCProfile-I_files/image122.gif" v:shapes="Picture_x0020_39"><![endif]></span><span
    45344499style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    45354500
    … …  
    45534518 <v:imagedata src="RMCProfile-I_files/image109.png" o:title=""/>
    45544519</v:shape><![endif]--><![if !vml]><img border=0 width=485 height=405
    4555 src="RMCProfile-I_files/image110.gif" v:shapes="Picture_x0020_40"><![endif]></span><span
     4520src="RMCProfile-I_files/image123.gif" v:shapes="Picture_x0020_40"><![endif]></span><span
    45564521style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    45574522
    … …  
    45684533 <v:imagedata src="RMCProfile-I_files/image111.png" o:title=""/>
    45694534</v:shape><![endif]--><![if !vml]><img border=0 width=289 height=89
    4570 src="RMCProfile-I_files/image112.gif" v:shapes="Picture_x0020_41"><![endif]></span><span
     4535src="RMCProfile-I_files/image124.gif" v:shapes="Picture_x0020_41"><![endif]></span><span
    45714536style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    45724537
    … …  
    45844549 <v:imagedata src="RMCProfile-I_files/image113.png" o:title=""/>
    45854550</v:shape><![endif]--><![if !vml]><img border=0 width=480 height=400
    4586 src="RMCProfile-I_files/image114.gif" v:shapes="Picture_x0020_42"><![endif]></span><span
     4551src="RMCProfile-I_files/image125.gif" v:shapes="Picture_x0020_42"><![endif]></span><span
    45874552style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    45884553
    … …  
    46114576 <v:imagedata src="RMCProfile-I_files/image115.png" o:title=""/>
    46124577</v:shape><![endif]--><![if !vml]><img border=0 width=480 height=400
    4613 src="RMCProfile-I_files/image116.gif" v:shapes="Picture_x0020_43"><![endif]></span><span
     4578src="RMCProfile-I_files/image126.gif" v:shapes="Picture_x0020_43"><![endif]></span><span
    46144579style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    46154580
    … …  
    46274592
    46284593<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman";
    4629 mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_44" o:spid="_x0000_i1025"
    4630  type="#_x0000_t75" style='width:357.75pt;height:298.5pt;visibility:visible;
     4594mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_45" o:spid="_x0000_i1025"
     4595 type="#_x0000_t75" style='width:286.5pt;height:218.25pt;visibility:visible;
    46314596 mso-wrap-style:square'>
    4632  <v:imagedata src="RMCProfile-I_files/image117.png" o:title=""/>
    4633 </v:shape><![endif]--><![if !vml]><img border=0 width=477 height=398
    4634 src="RMCProfile-I_files/image118.gif" v:shapes="Picture_x0020_44"><![endif]></span><span
     4597 <v:imagedata src="RMCProfile-I_files/image127.png" o:title=""/>
     4598</v:shape><![endif]--><![if !vml]><img border=0 width=382 height=291
     4599src="RMCProfile-I_files/image128.gif" v:shapes="Picture_x0020_45"><![endif]></span><span
    46354600style='mso-fareast-font-family:"Times New Roman"'><o:p></o:p></span></p>
    46364601
    4637 <p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The ‘x’
     4602<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>The sticks
    46384603marks show the directions of the unit vectors about which the SF<sub>6</sub>
    4639 molecules are tilted with respect to the reference octahedron. In this case
    4640 they are quite random; they cover all directions because the algorithm selects
    4641 the shortest F atom to octahedral vertex for the tilt calculation. That could
    4642 be any one of the six possible along +/- xyz axes. <o:p></o:p></span></p>
     4604molecules are tilted with respect to the reference octahedron and the colors
     4605indicate the angle of rotation according to the color bar on the right. In this
     4606case they are quite random; they cover all directions and rotations. Note that the
     4607algorithm selects the shortest F atom to octahedral vertex for the tilt
     4608calculation. That could be any one of the six possible along +/- xyz axes. <o:p></o:p></span></p>
    46434609
    46444610<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'><o:p>&nbsp;</o:p></span></p>
    46454611
    46464612<p class=MsoNormal><span style='mso-fareast-font-family:"Times New Roman"'>This
    4647 completes this <span class=SpellE>RMCProfile</span> tutorial; you should save
    4648 the project.<o:p></o:p></span></p>
     4613completes this RMCProfile tutorial; you should save the project.<o:p></o:p></span></p>
    46494614
    46504615<h2><span style='mso-fareast-font-family:"Times New Roman"'>Final note<o:p></o:p></span></h2>

  • Tutorials/RMCProfile-I/RMCProfile-I_files/filelist.xml

    r4296 r4357  
    44 <o:File HRef="colorschememapping.xml"/>
    55 <o:File HRef="image001.png"/>
    6  <o:File HRef="image068.gif"/>
     6 <o:File HRef="image002.gif"/>
    77 <o:File HRef="image003.png"/>
    8  <o:File HRef="image069.gif"/>
     8 <o:File HRef="image004.gif"/>
    99 <o:File HRef="image005.png"/>
    10  <o:File HRef="image070.gif"/>
     10 <o:File HRef="image006.gif"/>
    1111 <o:File HRef="image007.png"/>
    12  <o:File HRef="image071.gif"/>
     12 <o:File HRef="image008.gif"/>
    1313 <o:File HRef="image009.png"/>
    14  <o:File HRef="image072.gif"/>
     14 <o:File HRef="image010.gif"/>
    1515 <o:File HRef="image011.png"/>
    16  <o:File HRef="image073.gif"/>
     16 <o:File HRef="image012.gif"/>
    1717 <o:File HRef="image013.png"/>
    18  <o:File HRef="image074.gif"/>
     18 <o:File HRef="image014.gif"/>
    1919 <o:File HRef="image015.png"/>
    20  <o:File HRef="image075.gif"/>
     20 <o:File HRef="image016.gif"/>
    2121 <o:File HRef="image017.png"/>
    22  <o:File HRef="image076.gif"/>
     22 <o:File HRef="image018.gif"/>
    2323 <o:File HRef="image019.png"/>
    24  <o:File HRef="image077.gif"/>
     24 <o:File HRef="image020.gif"/>
    2525 <o:File HRef="image021.png"/>
    26  <o:File HRef="image078.gif"/>
     26 <o:File HRef="image022.gif"/>
    2727 <o:File HRef="image023.png"/>
    28  <o:File HRef="image079.gif"/>
     28 <o:File HRef="image024.gif"/>
    2929 <o:File HRef="image025.png"/>
    30  <o:File HRef="image080.gif"/>
     30 <o:File HRef="image026.gif"/>
    3131 <o:File HRef="image027.png"/>
    32  <o:File HRef="image081.gif"/>
     32 <o:File HRef="image028.gif"/>
    3333 <o:File HRef="image029.png"/>
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