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6 | |
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7 | <head> |
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9 | <meta name=ProgId content=Word.Document> |
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10 | <meta name=Generator content="Microsoft Word 15"> |
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11 | <meta name=Originator content="Microsoft Word 15"> |
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12 | <link rel=File-List href="Magnetic-V_files/filelist.xml"> |
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13 | <link rel=Edit-Time-Data href="Magnetic-V_files/editdata.mso"> |
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14 | <!--[if !mso]> |
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16 | v\:* {behavior:url(#default#VML);} |
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17 | o\:* {behavior:url(#default#VML);} |
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18 | w\:* {behavior:url(#default#VML);} |
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19 | .shape {behavior:url(#default#VML);} |
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20 | </style> |
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21 | <![endif]--><!--[if gte mso 9]><xml> |
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22 | <o:DocumentProperties> |
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23 | <o:Author>Von Dreele</o:Author> |
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24 | <o:LastAuthor>vondreele</o:LastAuthor> |
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25 | <o:Revision>17</o:Revision> |
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26 | <o:TotalTime>1824</o:TotalTime> |
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27 | <o:Created>2018-10-01T19:16:00Z</o:Created> |
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28 | <o:LastSaved>2018-10-05T20:07:00Z</o:LastSaved> |
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29 | <o:Pages>1</o:Pages> |
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30 | <o:Words>3964</o:Words> |
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31 | <o:Characters>22601</o:Characters> |
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32 | <o:Lines>188</o:Lines> |
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33 | <o:Paragraphs>53</o:Paragraphs> |
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34 | <o:CharactersWithSpaces>26512</o:CharactersWithSpaces> |
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35 | <o:Version>16.00</o:Version> |
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36 | </o:DocumentProperties> |
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48 | <w:TrackFormatting/> |
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49 | <w:PunctuationKerning/> |
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52 | <w:IgnoreMixedContent>false</w:IgnoreMixedContent> |
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57 | <w:LidThemeComplexScript>X-NONE</w:LidThemeComplexScript> |
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58 | <w:Compatibility> |
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59 | <w:BreakWrappedTables/> |
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60 | <w:SnapToGridInCell/> |
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109 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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111 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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112 | Name="index 3"/> |
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113 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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114 | Name="index 4"/> |
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115 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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116 | Name="index 5"/> |
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117 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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119 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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121 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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131 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
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132 | UnhideWhenUsed="true" Name="toc 4"/> |
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133 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
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134 | UnhideWhenUsed="true" Name="toc 5"/> |
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135 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
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137 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
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138 | UnhideWhenUsed="true" Name="toc 7"/> |
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139 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
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140 | UnhideWhenUsed="true" Name="toc 8"/> |
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141 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
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142 | UnhideWhenUsed="true" Name="toc 9"/> |
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143 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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145 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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147 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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148 | Name="annotation text"/> |
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149 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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150 | Name="header"/> |
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151 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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152 | Name="footer"/> |
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153 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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154 | Name="index heading"/> |
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155 | <w:LsdException Locked="false" Priority="35" SemiHidden="true" |
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156 | UnhideWhenUsed="true" QFormat="true" Name="caption"/> |
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157 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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158 | Name="table of figures"/> |
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159 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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160 | Name="envelope address"/> |
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161 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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162 | Name="envelope return"/> |
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163 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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164 | Name="footnote reference"/> |
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165 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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166 | Name="annotation reference"/> |
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167 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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169 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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170 | Name="page number"/> |
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171 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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172 | Name="endnote reference"/> |
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173 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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174 | Name="endnote text"/> |
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175 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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176 | Name="table of authorities"/> |
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177 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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179 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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180 | Name="toa heading"/> |
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181 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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182 | Name="List"/> |
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183 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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184 | Name="List Bullet"/> |
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185 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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186 | Name="List Number"/> |
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187 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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188 | Name="List 2"/> |
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189 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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190 | Name="List 3"/> |
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191 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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192 | Name="List 4"/> |
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193 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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194 | Name="List 5"/> |
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195 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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196 | Name="List Bullet 2"/> |
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197 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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198 | Name="List Bullet 3"/> |
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199 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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200 | Name="List Bullet 4"/> |
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201 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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202 | Name="List Bullet 5"/> |
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203 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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204 | Name="List Number 2"/> |
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205 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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206 | Name="List Number 3"/> |
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207 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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208 | Name="List Number 4"/> |
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209 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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210 | Name="List Number 5"/> |
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211 | <w:LsdException Locked="false" Priority="10" QFormat="true" Name="Title"/> |
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212 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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213 | Name="Closing"/> |
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214 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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215 | Name="Signature"/> |
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216 | <w:LsdException Locked="false" Priority="1" SemiHidden="true" |
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217 | UnhideWhenUsed="true" Name="Default Paragraph Font"/> |
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218 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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219 | Name="Body Text"/> |
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220 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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221 | Name="Body Text Indent"/> |
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222 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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223 | Name="List Continue"/> |
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224 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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225 | Name="List Continue 2"/> |
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226 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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227 | Name="List Continue 3"/> |
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228 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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229 | Name="List Continue 4"/> |
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230 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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231 | Name="List Continue 5"/> |
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232 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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233 | Name="Message Header"/> |
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234 | <w:LsdException Locked="false" Priority="11" QFormat="true" Name="Subtitle"/> |
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235 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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236 | Name="Salutation"/> |
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237 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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238 | Name="Date"/> |
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239 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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240 | Name="Body Text First Indent"/> |
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241 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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242 | Name="Body Text First Indent 2"/> |
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243 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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244 | Name="Note Heading"/> |
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245 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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246 | Name="Body Text 2"/> |
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247 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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248 | Name="Body Text 3"/> |
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249 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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250 | Name="Body Text Indent 2"/> |
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251 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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252 | Name="Body Text Indent 3"/> |
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253 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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254 | Name="Block Text"/> |
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255 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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256 | Name="Hyperlink"/> |
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257 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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258 | Name="FollowedHyperlink"/> |
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259 | <w:LsdException Locked="false" Priority="22" QFormat="true" Name="Strong"/> |
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260 | <w:LsdException Locked="false" Priority="20" QFormat="true" Name="Emphasis"/> |
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261 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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262 | Name="Document Map"/> |
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263 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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264 | Name="Plain Text"/> |
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265 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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266 | Name="E-mail Signature"/> |
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267 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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268 | Name="HTML Top of Form"/> |
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269 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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270 | Name="HTML Bottom of Form"/> |
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271 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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272 | Name="Normal (Web)"/> |
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273 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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274 | Name="HTML Acronym"/> |
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275 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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276 | Name="HTML Address"/> |
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277 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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278 | Name="HTML Cite"/> |
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279 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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280 | Name="HTML Code"/> |
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281 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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282 | Name="HTML Definition"/> |
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283 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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284 | Name="HTML Keyboard"/> |
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285 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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286 | Name="HTML Preformatted"/> |
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287 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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288 | Name="HTML Sample"/> |
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289 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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290 | Name="HTML Typewriter"/> |
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291 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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292 | Name="HTML Variable"/> |
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293 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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294 | Name="Normal Table"/> |
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295 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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296 | Name="annotation subject"/> |
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297 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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298 | Name="No List"/> |
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299 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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300 | Name="Outline List 1"/> |
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301 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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302 | Name="Outline List 2"/> |
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303 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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304 | Name="Outline List 3"/> |
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305 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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306 | Name="Table Simple 1"/> |
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307 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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308 | Name="Table Simple 2"/> |
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309 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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310 | Name="Table Simple 3"/> |
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311 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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312 | Name="Table Classic 1"/> |
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313 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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314 | Name="Table Classic 2"/> |
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315 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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316 | Name="Table Classic 3"/> |
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317 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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318 | Name="Table Classic 4"/> |
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319 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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320 | Name="Table Colorful 1"/> |
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321 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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322 | Name="Table Colorful 2"/> |
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323 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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324 | Name="Table Colorful 3"/> |
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325 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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326 | Name="Table Columns 1"/> |
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327 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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328 | Name="Table Columns 2"/> |
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329 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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330 | Name="Table Columns 3"/> |
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331 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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332 | Name="Table Columns 4"/> |
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333 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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334 | Name="Table Columns 5"/> |
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335 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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336 | Name="Table Grid 1"/> |
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337 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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338 | Name="Table Grid 2"/> |
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339 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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340 | Name="Table Grid 3"/> |
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341 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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342 | Name="Table Grid 4"/> |
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343 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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344 | Name="Table Grid 5"/> |
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345 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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346 | Name="Table Grid 6"/> |
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347 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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348 | Name="Table Grid 7"/> |
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349 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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350 | Name="Table Grid 8"/> |
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351 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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352 | Name="Table List 1"/> |
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353 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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354 | Name="Table List 2"/> |
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355 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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356 | Name="Table List 3"/> |
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357 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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358 | Name="Table List 4"/> |
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359 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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360 | Name="Table List 5"/> |
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361 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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362 | Name="Table List 6"/> |
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363 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
364 | Name="Table List 7"/> |
---|
365 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
366 | Name="Table List 8"/> |
---|
367 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
368 | Name="Table 3D effects 1"/> |
---|
369 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
370 | Name="Table 3D effects 2"/> |
---|
371 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
372 | Name="Table 3D effects 3"/> |
---|
373 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
374 | Name="Table Contemporary"/> |
---|
375 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
376 | Name="Table Elegant"/> |
---|
377 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
378 | Name="Table Professional"/> |
---|
379 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
380 | Name="Table Subtle 1"/> |
---|
381 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
382 | Name="Table Subtle 2"/> |
---|
383 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
384 | Name="Table Web 1"/> |
---|
385 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
386 | Name="Table Web 2"/> |
---|
387 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
388 | Name="Table Web 3"/> |
---|
389 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
390 | Name="Balloon Text"/> |
---|
391 | <w:LsdException Locked="false" Priority="59" Name="Table Grid"/> |
---|
392 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
393 | Name="Table Theme"/> |
---|
394 | <w:LsdException Locked="false" SemiHidden="true" Name="Placeholder Text"/> |
---|
395 | <w:LsdException Locked="false" Priority="1" QFormat="true" Name="No Spacing"/> |
---|
396 | <w:LsdException Locked="false" Priority="60" Name="Light Shading"/> |
---|
397 | <w:LsdException Locked="false" Priority="61" Name="Light List"/> |
---|
398 | <w:LsdException Locked="false" Priority="62" Name="Light Grid"/> |
---|
399 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1"/> |
---|
400 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2"/> |
---|
401 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1"/> |
---|
402 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2"/> |
---|
403 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1"/> |
---|
404 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2"/> |
---|
405 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3"/> |
---|
406 | <w:LsdException Locked="false" Priority="70" Name="Dark List"/> |
---|
407 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading"/> |
---|
408 | <w:LsdException Locked="false" Priority="72" Name="Colorful List"/> |
---|
409 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid"/> |
---|
410 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 1"/> |
---|
411 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 1"/> |
---|
412 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 1"/> |
---|
413 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 1"/> |
---|
414 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 1"/> |
---|
415 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 1"/> |
---|
416 | <w:LsdException Locked="false" SemiHidden="true" Name="Revision"/> |
---|
417 | <w:LsdException Locked="false" Priority="34" QFormat="true" |
---|
418 | Name="List Paragraph"/> |
---|
419 | <w:LsdException Locked="false" Priority="29" QFormat="true" Name="Quote"/> |
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420 | <w:LsdException Locked="false" Priority="30" QFormat="true" |
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421 | Name="Intense Quote"/> |
---|
422 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 1"/> |
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423 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 1"/> |
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424 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 1"/> |
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425 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 1"/> |
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426 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 1"/> |
---|
427 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 1"/> |
---|
428 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 1"/> |
---|
429 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 1"/> |
---|
430 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 2"/> |
---|
431 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 2"/> |
---|
432 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 2"/> |
---|
433 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 2"/> |
---|
434 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 2"/> |
---|
435 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 2"/> |
---|
436 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 2"/> |
---|
437 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 2"/> |
---|
438 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 2"/> |
---|
439 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 2"/> |
---|
440 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 2"/> |
---|
441 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 2"/> |
---|
442 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 2"/> |
---|
443 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 2"/> |
---|
444 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 3"/> |
---|
445 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 3"/> |
---|
446 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 3"/> |
---|
447 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 3"/> |
---|
448 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 3"/> |
---|
449 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 3"/> |
---|
450 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 3"/> |
---|
451 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 3"/> |
---|
452 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 3"/> |
---|
453 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 3"/> |
---|
454 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 3"/> |
---|
455 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 3"/> |
---|
456 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 3"/> |
---|
457 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 3"/> |
---|
458 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 4"/> |
---|
459 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 4"/> |
---|
460 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 4"/> |
---|
461 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 4"/> |
---|
462 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 4"/> |
---|
463 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 4"/> |
---|
464 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 4"/> |
---|
465 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 4"/> |
---|
466 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 4"/> |
---|
467 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 4"/> |
---|
468 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 4"/> |
---|
469 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 4"/> |
---|
470 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 4"/> |
---|
471 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 4"/> |
---|
472 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 5"/> |
---|
473 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 5"/> |
---|
474 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 5"/> |
---|
475 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 5"/> |
---|
476 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 5"/> |
---|
477 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 5"/> |
---|
478 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 5"/> |
---|
479 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 5"/> |
---|
480 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 5"/> |
---|
481 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 5"/> |
---|
482 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 5"/> |
---|
483 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 5"/> |
---|
484 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 5"/> |
---|
485 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 5"/> |
---|
486 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 6"/> |
---|
487 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 6"/> |
---|
488 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 6"/> |
---|
489 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 6"/> |
---|
490 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 6"/> |
---|
491 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 6"/> |
---|
492 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 6"/> |
---|
493 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 6"/> |
---|
494 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 6"/> |
---|
495 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 6"/> |
---|
496 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 6"/> |
---|
497 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 6"/> |
---|
498 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 6"/> |
---|
499 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 6"/> |
---|
500 | <w:LsdException Locked="false" Priority="19" QFormat="true" |
---|
501 | Name="Subtle Emphasis"/> |
---|
502 | <w:LsdException Locked="false" Priority="21" QFormat="true" |
---|
503 | Name="Intense Emphasis"/> |
---|
504 | <w:LsdException Locked="false" Priority="31" QFormat="true" |
---|
505 | Name="Subtle Reference"/> |
---|
506 | <w:LsdException Locked="false" Priority="32" QFormat="true" |
---|
507 | Name="Intense Reference"/> |
---|
508 | <w:LsdException Locked="false" Priority="33" QFormat="true" Name="Book Title"/> |
---|
509 | <w:LsdException Locked="false" Priority="37" SemiHidden="true" |
---|
510 | UnhideWhenUsed="true" Name="Bibliography"/> |
---|
511 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
---|
512 | UnhideWhenUsed="true" QFormat="true" Name="TOC Heading"/> |
---|
513 | <w:LsdException Locked="false" Priority="41" Name="Plain Table 1"/> |
---|
514 | <w:LsdException Locked="false" Priority="42" Name="Plain Table 2"/> |
---|
515 | <w:LsdException Locked="false" Priority="43" Name="Plain Table 3"/> |
---|
516 | <w:LsdException Locked="false" Priority="44" Name="Plain Table 4"/> |
---|
517 | <w:LsdException Locked="false" Priority="45" Name="Plain Table 5"/> |
---|
518 | <w:LsdException Locked="false" Priority="40" Name="Grid Table Light"/> |
---|
519 | <w:LsdException Locked="false" Priority="46" Name="Grid Table 1 Light"/> |
---|
520 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2"/> |
---|
521 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3"/> |
---|
522 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4"/> |
---|
523 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark"/> |
---|
524 | <w:LsdException Locked="false" Priority="51" Name="Grid Table 6 Colorful"/> |
---|
525 | <w:LsdException Locked="false" Priority="52" Name="Grid Table 7 Colorful"/> |
---|
526 | <w:LsdException Locked="false" Priority="46" |
---|
527 | Name="Grid Table 1 Light Accent 1"/> |
---|
528 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 1"/> |
---|
529 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 1"/> |
---|
530 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 1"/> |
---|
531 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 1"/> |
---|
532 | <w:LsdException Locked="false" Priority="51" |
---|
533 | Name="Grid Table 6 Colorful Accent 1"/> |
---|
534 | <w:LsdException Locked="false" Priority="52" |
---|
535 | Name="Grid Table 7 Colorful Accent 1"/> |
---|
536 | <w:LsdException Locked="false" Priority="46" |
---|
537 | Name="Grid Table 1 Light Accent 2"/> |
---|
538 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 2"/> |
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539 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 2"/> |
---|
540 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 2"/> |
---|
541 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 2"/> |
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542 | <w:LsdException Locked="false" Priority="51" |
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543 | Name="Grid Table 6 Colorful Accent 2"/> |
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544 | <w:LsdException Locked="false" Priority="52" |
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545 | Name="Grid Table 7 Colorful Accent 2"/> |
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546 | <w:LsdException Locked="false" Priority="46" |
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547 | Name="Grid Table 1 Light Accent 3"/> |
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548 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 3"/> |
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549 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 3"/> |
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550 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 3"/> |
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551 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 3"/> |
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552 | <w:LsdException Locked="false" Priority="51" |
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553 | Name="Grid Table 6 Colorful Accent 3"/> |
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554 | <w:LsdException Locked="false" Priority="52" |
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555 | Name="Grid Table 7 Colorful Accent 3"/> |
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556 | <w:LsdException Locked="false" Priority="46" |
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557 | Name="Grid Table 1 Light Accent 4"/> |
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558 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 4"/> |
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559 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 4"/> |
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560 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 4"/> |
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561 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 4"/> |
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562 | <w:LsdException Locked="false" Priority="51" |
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563 | Name="Grid Table 6 Colorful Accent 4"/> |
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564 | <w:LsdException Locked="false" Priority="52" |
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565 | Name="Grid Table 7 Colorful Accent 4"/> |
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566 | <w:LsdException Locked="false" Priority="46" |
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567 | Name="Grid Table 1 Light Accent 5"/> |
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568 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 5"/> |
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569 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 5"/> |
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570 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 5"/> |
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571 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 5"/> |
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572 | <w:LsdException Locked="false" Priority="51" |
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573 | Name="Grid Table 6 Colorful Accent 5"/> |
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574 | <w:LsdException Locked="false" Priority="52" |
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575 | Name="Grid Table 7 Colorful Accent 5"/> |
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576 | <w:LsdException Locked="false" Priority="46" |
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577 | Name="Grid Table 1 Light Accent 6"/> |
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578 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 6"/> |
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579 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 6"/> |
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580 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 6"/> |
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581 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 6"/> |
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582 | <w:LsdException Locked="false" Priority="51" |
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583 | Name="Grid Table 6 Colorful Accent 6"/> |
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584 | <w:LsdException Locked="false" Priority="52" |
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585 | Name="Grid Table 7 Colorful Accent 6"/> |
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586 | <w:LsdException Locked="false" Priority="46" Name="List Table 1 Light"/> |
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587 | <w:LsdException Locked="false" Priority="47" Name="List Table 2"/> |
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588 | <w:LsdException Locked="false" Priority="48" Name="List Table 3"/> |
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589 | <w:LsdException Locked="false" Priority="49" Name="List Table 4"/> |
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590 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark"/> |
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591 | <w:LsdException Locked="false" Priority="51" Name="List Table 6 Colorful"/> |
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592 | <w:LsdException Locked="false" Priority="52" Name="List Table 7 Colorful"/> |
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593 | <w:LsdException Locked="false" Priority="46" |
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594 | Name="List Table 1 Light Accent 1"/> |
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595 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 1"/> |
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596 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 1"/> |
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597 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 1"/> |
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598 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 1"/> |
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599 | <w:LsdException Locked="false" Priority="51" |
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600 | Name="List Table 6 Colorful Accent 1"/> |
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601 | <w:LsdException Locked="false" Priority="52" |
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602 | Name="List Table 7 Colorful Accent 1"/> |
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603 | <w:LsdException Locked="false" Priority="46" |
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604 | Name="List Table 1 Light Accent 2"/> |
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605 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 2"/> |
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606 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 2"/> |
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607 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 2"/> |
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608 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 2"/> |
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609 | <w:LsdException Locked="false" Priority="51" |
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610 | Name="List Table 6 Colorful Accent 2"/> |
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611 | <w:LsdException Locked="false" Priority="52" |
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612 | Name="List Table 7 Colorful Accent 2"/> |
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613 | <w:LsdException Locked="false" Priority="46" |
---|
614 | Name="List Table 1 Light Accent 3"/> |
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615 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 3"/> |
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616 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 3"/> |
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617 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 3"/> |
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618 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 3"/> |
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619 | <w:LsdException Locked="false" Priority="51" |
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620 | Name="List Table 6 Colorful Accent 3"/> |
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621 | <w:LsdException Locked="false" Priority="52" |
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622 | Name="List Table 7 Colorful Accent 3"/> |
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623 | <w:LsdException Locked="false" Priority="46" |
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624 | Name="List Table 1 Light Accent 4"/> |
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625 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 4"/> |
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626 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 4"/> |
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627 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 4"/> |
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628 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 4"/> |
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629 | <w:LsdException Locked="false" Priority="51" |
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630 | Name="List Table 6 Colorful Accent 4"/> |
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631 | <w:LsdException Locked="false" Priority="52" |
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632 | Name="List Table 7 Colorful Accent 4"/> |
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633 | <w:LsdException Locked="false" Priority="46" |
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634 | Name="List Table 1 Light Accent 5"/> |
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635 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 5"/> |
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636 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 5"/> |
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637 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 5"/> |
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638 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 5"/> |
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639 | <w:LsdException Locked="false" Priority="51" |
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640 | Name="List Table 6 Colorful Accent 5"/> |
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641 | <w:LsdException Locked="false" Priority="52" |
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642 | Name="List Table 7 Colorful Accent 5"/> |
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643 | <w:LsdException Locked="false" Priority="46" |
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644 | Name="List Table 1 Light Accent 6"/> |
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645 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 6"/> |
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646 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 6"/> |
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647 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 6"/> |
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648 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 6"/> |
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649 | <w:LsdException Locked="false" Priority="51" |
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650 | Name="List Table 6 Colorful Accent 6"/> |
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651 | <w:LsdException Locked="false" Priority="52" |
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652 | Name="List Table 7 Colorful Accent 6"/> |
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653 | </w:LatentStyles> |
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654 | </xml><![endif]--> |
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655 | <style> |
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656 | <!-- |
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657 | /* Font Definitions */ |
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658 | @font-face |
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659 | {font-family:Calibri; |
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660 | panose-1:2 15 5 2 2 2 4 3 2 4; |
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661 | mso-font-charset:0; |
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662 | mso-generic-font-family:swiss; |
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663 | mso-font-pitch:variable; |
---|
664 | mso-font-signature:-536859905 -1073732485 9 0 511 0;} |
---|
665 | @font-face |
---|
666 | {font-family:Tahoma; |
---|
667 | panose-1:2 11 6 4 3 5 4 4 2 4; |
---|
668 | mso-font-charset:0; |
---|
669 | mso-generic-font-family:swiss; |
---|
670 | mso-font-pitch:variable; |
---|
671 | mso-font-signature:-520081665 -1073717157 41 0 66047 0;} |
---|
672 | /* Style Definitions */ |
---|
673 | p.MsoNormal, li.MsoNormal, div.MsoNormal |
---|
674 | {mso-style-unhide:no; |
---|
675 | mso-style-qformat:yes; |
---|
676 | mso-style-parent:""; |
---|
677 | margin:0in; |
---|
678 | margin-bottom:.0001pt; |
---|
679 | mso-pagination:widow-orphan; |
---|
680 | font-size:12.0pt; |
---|
681 | font-family:"Times New Roman",serif; |
---|
682 | mso-fareast-font-family:"Times New Roman"; |
---|
683 | mso-fareast-theme-font:minor-fareast;} |
---|
684 | h1 |
---|
685 | {mso-style-priority:9; |
---|
686 | mso-style-unhide:no; |
---|
687 | mso-style-qformat:yes; |
---|
688 | mso-style-link:"Heading 1 Char"; |
---|
689 | mso-margin-top-alt:auto; |
---|
690 | margin-right:0in; |
---|
691 | mso-margin-bottom-alt:auto; |
---|
692 | margin-left:0in; |
---|
693 | mso-pagination:widow-orphan; |
---|
694 | mso-outline-level:1; |
---|
695 | font-size:24.0pt; |
---|
696 | font-family:"Times New Roman",serif; |
---|
697 | mso-fareast-font-family:"Times New Roman"; |
---|
698 | mso-fareast-theme-font:minor-fareast; |
---|
699 | font-weight:bold;} |
---|
700 | h2 |
---|
701 | {mso-style-priority:9; |
---|
702 | mso-style-qformat:yes; |
---|
703 | mso-style-link:"Heading 2 Char"; |
---|
704 | mso-margin-top-alt:auto; |
---|
705 | margin-right:0in; |
---|
706 | mso-margin-bottom-alt:auto; |
---|
707 | margin-left:0in; |
---|
708 | mso-pagination:widow-orphan; |
---|
709 | mso-outline-level:2; |
---|
710 | font-size:18.0pt; |
---|
711 | font-family:"Times New Roman",serif; |
---|
712 | mso-fareast-font-family:"Times New Roman"; |
---|
713 | mso-fareast-theme-font:minor-fareast; |
---|
714 | font-weight:bold;} |
---|
715 | h3 |
---|
716 | {mso-style-priority:9; |
---|
717 | mso-style-qformat:yes; |
---|
718 | mso-style-link:"Heading 3 Char"; |
---|
719 | mso-margin-top-alt:auto; |
---|
720 | margin-right:0in; |
---|
721 | mso-margin-bottom-alt:auto; |
---|
722 | margin-left:0in; |
---|
723 | mso-pagination:widow-orphan; |
---|
724 | mso-outline-level:3; |
---|
725 | font-size:13.5pt; |
---|
726 | font-family:"Times New Roman",serif; |
---|
727 | mso-fareast-font-family:"Times New Roman"; |
---|
728 | mso-fareast-theme-font:minor-fareast; |
---|
729 | font-weight:bold;} |
---|
730 | h4 |
---|
731 | {mso-style-noshow:yes; |
---|
732 | mso-style-priority:9; |
---|
733 | mso-style-qformat:yes; |
---|
734 | mso-style-link:"Heading 4 Char"; |
---|
735 | mso-style-next:Normal; |
---|
736 | margin-top:10.0pt; |
---|
737 | margin-right:0in; |
---|
738 | margin-bottom:0in; |
---|
739 | margin-left:0in; |
---|
740 | margin-bottom:.0001pt; |
---|
741 | mso-pagination:widow-orphan lines-together; |
---|
742 | page-break-after:avoid; |
---|
743 | mso-outline-level:4; |
---|
744 | font-size:13.0pt; |
---|
745 | font-family:"Cambria",serif; |
---|
746 | mso-ascii-font-family:Cambria; |
---|
747 | mso-ascii-theme-font:major-latin; |
---|
748 | mso-fareast-font-family:"Times New Roman"; |
---|
749 | mso-fareast-theme-font:major-fareast; |
---|
750 | mso-hansi-font-family:Cambria; |
---|
751 | mso-hansi-theme-font:major-latin; |
---|
752 | mso-bidi-font-family:"Times New Roman"; |
---|
753 | mso-bidi-theme-font:major-bidi; |
---|
754 | color:#4F81BD; |
---|
755 | mso-themecolor:accent1; |
---|
756 | font-weight:bold; |
---|
757 | font-style:italic;} |
---|
758 | h5 |
---|
759 | {mso-style-noshow:yes; |
---|
760 | mso-style-priority:9; |
---|
761 | mso-style-qformat:yes; |
---|
762 | mso-style-link:"Heading 5 Char"; |
---|
763 | mso-margin-top-alt:auto; |
---|
764 | margin-right:0in; |
---|
765 | mso-margin-bottom-alt:auto; |
---|
766 | margin-left:0in; |
---|
767 | mso-pagination:widow-orphan; |
---|
768 | mso-outline-level:5; |
---|
769 | font-size:12.0pt; |
---|
770 | font-family:"Times New Roman",serif; |
---|
771 | mso-fareast-font-family:"Times New Roman"; |
---|
772 | mso-fareast-theme-font:minor-fareast; |
---|
773 | color:#4F4FFF; |
---|
774 | font-weight:bold;} |
---|
775 | a:link, span.MsoHyperlink |
---|
776 | {mso-style-noshow:yes; |
---|
777 | mso-style-priority:99; |
---|
778 | color:blue; |
---|
779 | text-decoration:underline; |
---|
780 | text-underline:single;} |
---|
781 | a:visited, span.MsoHyperlinkFollowed |
---|
782 | {mso-style-noshow:yes; |
---|
783 | mso-style-priority:99; |
---|
784 | color:purple; |
---|
785 | text-decoration:underline; |
---|
786 | text-underline:single;} |
---|
787 | p.MsoDocumentMap, li.MsoDocumentMap, div.MsoDocumentMap |
---|
788 | {mso-style-noshow:yes; |
---|
789 | mso-style-priority:99; |
---|
790 | mso-style-link:"Document Map Char"; |
---|
791 | margin:0in; |
---|
792 | margin-bottom:.0001pt; |
---|
793 | mso-pagination:widow-orphan; |
---|
794 | font-size:8.0pt; |
---|
795 | font-family:"Tahoma",sans-serif; |
---|
796 | mso-fareast-font-family:"Times New Roman"; |
---|
797 | mso-fareast-theme-font:minor-fareast;} |
---|
798 | p |
---|
799 | {mso-style-noshow:yes; |
---|
800 | mso-style-priority:99; |
---|
801 | mso-margin-top-alt:auto; |
---|
802 | margin-right:0in; |
---|
803 | mso-margin-bottom-alt:auto; |
---|
804 | margin-left:0in; |
---|
805 | mso-pagination:widow-orphan; |
---|
806 | font-size:12.0pt; |
---|
807 | font-family:"Times New Roman",serif; |
---|
808 | mso-fareast-font-family:"Times New Roman"; |
---|
809 | mso-fareast-theme-font:minor-fareast;} |
---|
810 | pre |
---|
811 | {mso-style-noshow:yes; |
---|
812 | mso-style-priority:99; |
---|
813 | mso-style-link:"HTML Preformatted Char"; |
---|
814 | margin:0in; |
---|
815 | margin-bottom:.0001pt; |
---|
816 | mso-pagination:widow-orphan; |
---|
817 | tab-stops:45.8pt 91.6pt 137.4pt 183.2pt 229.0pt 274.8pt 320.6pt 366.4pt 412.2pt 458.0pt 503.8pt 549.6pt 595.4pt 641.2pt 687.0pt 732.8pt; |
---|
818 | font-size:10.0pt; |
---|
819 | font-family:"Courier New"; |
---|
820 | mso-fareast-font-family:"Times New Roman";} |
---|
821 | p.MsoAcetate, li.MsoAcetate, div.MsoAcetate |
---|
822 | {mso-style-noshow:yes; |
---|
823 | mso-style-priority:99; |
---|
824 | mso-style-link:"Balloon Text Char"; |
---|
825 | margin:0in; |
---|
826 | margin-bottom:.0001pt; |
---|
827 | mso-pagination:widow-orphan; |
---|
828 | font-size:8.0pt; |
---|
829 | font-family:"Tahoma",sans-serif; |
---|
830 | mso-fareast-font-family:"Times New Roman"; |
---|
831 | mso-fareast-theme-font:minor-fareast;} |
---|
832 | span.MsoPlaceholderText |
---|
833 | {mso-style-noshow:yes; |
---|
834 | mso-style-priority:99; |
---|
835 | mso-style-unhide:no; |
---|
836 | color:gray;} |
---|
837 | p.MsoNoSpacing, li.MsoNoSpacing, div.MsoNoSpacing |
---|
838 | {mso-style-noshow:yes; |
---|
839 | mso-style-priority:1; |
---|
840 | mso-style-unhide:no; |
---|
841 | mso-style-qformat:yes; |
---|
842 | mso-style-parent:""; |
---|
843 | margin:0in; |
---|
844 | margin-bottom:.0001pt; |
---|
845 | mso-pagination:widow-orphan; |
---|
846 | font-size:12.0pt; |
---|
847 | font-family:"Times New Roman",serif; |
---|
848 | mso-fareast-font-family:"Times New Roman"; |
---|
849 | mso-fareast-theme-font:minor-fareast;} |
---|
850 | p.MsoListParagraph, li.MsoListParagraph, div.MsoListParagraph |
---|
851 | {mso-style-noshow:yes; |
---|
852 | mso-style-priority:34; |
---|
853 | mso-style-unhide:no; |
---|
854 | mso-style-qformat:yes; |
---|
855 | margin-top:0in; |
---|
856 | margin-right:0in; |
---|
857 | margin-bottom:0in; |
---|
858 | margin-left:.5in; |
---|
859 | margin-bottom:.0001pt; |
---|
860 | mso-add-space:auto; |
---|
861 | mso-pagination:widow-orphan; |
---|
862 | font-size:12.0pt; |
---|
863 | font-family:"Times New Roman",serif; |
---|
864 | mso-fareast-font-family:"Times New Roman"; |
---|
865 | mso-fareast-theme-font:minor-fareast;} |
---|
866 | p.MsoListParagraphCxSpFirst, li.MsoListParagraphCxSpFirst, div.MsoListParagraphCxSpFirst |
---|
867 | {mso-style-noshow:yes; |
---|
868 | mso-style-priority:34; |
---|
869 | mso-style-unhide:no; |
---|
870 | mso-style-qformat:yes; |
---|
871 | mso-style-type:export-only; |
---|
872 | margin-top:0in; |
---|
873 | margin-right:0in; |
---|
874 | margin-bottom:0in; |
---|
875 | margin-left:.5in; |
---|
876 | margin-bottom:.0001pt; |
---|
877 | mso-add-space:auto; |
---|
878 | mso-pagination:widow-orphan; |
---|
879 | font-size:12.0pt; |
---|
880 | font-family:"Times New Roman",serif; |
---|
881 | mso-fareast-font-family:"Times New Roman"; |
---|
882 | mso-fareast-theme-font:minor-fareast;} |
---|
883 | p.MsoListParagraphCxSpMiddle, li.MsoListParagraphCxSpMiddle, div.MsoListParagraphCxSpMiddle |
---|
884 | {mso-style-noshow:yes; |
---|
885 | mso-style-priority:34; |
---|
886 | mso-style-unhide:no; |
---|
887 | mso-style-qformat:yes; |
---|
888 | mso-style-type:export-only; |
---|
889 | margin-top:0in; |
---|
890 | margin-right:0in; |
---|
891 | margin-bottom:0in; |
---|
892 | margin-left:.5in; |
---|
893 | margin-bottom:.0001pt; |
---|
894 | mso-add-space:auto; |
---|
895 | mso-pagination:widow-orphan; |
---|
896 | font-size:12.0pt; |
---|
897 | font-family:"Times New Roman",serif; |
---|
898 | mso-fareast-font-family:"Times New Roman"; |
---|
899 | mso-fareast-theme-font:minor-fareast;} |
---|
900 | p.MsoListParagraphCxSpLast, li.MsoListParagraphCxSpLast, div.MsoListParagraphCxSpLast |
---|
901 | {mso-style-noshow:yes; |
---|
902 | mso-style-priority:34; |
---|
903 | mso-style-unhide:no; |
---|
904 | mso-style-qformat:yes; |
---|
905 | mso-style-type:export-only; |
---|
906 | margin-top:0in; |
---|
907 | margin-right:0in; |
---|
908 | margin-bottom:0in; |
---|
909 | margin-left:.5in; |
---|
910 | margin-bottom:.0001pt; |
---|
911 | mso-add-space:auto; |
---|
912 | mso-pagination:widow-orphan; |
---|
913 | font-size:12.0pt; |
---|
914 | font-family:"Times New Roman",serif; |
---|
915 | mso-fareast-font-family:"Times New Roman"; |
---|
916 | mso-fareast-theme-font:minor-fareast;} |
---|
917 | span.MsoIntenseReference |
---|
918 | {mso-style-priority:32; |
---|
919 | mso-style-unhide:no; |
---|
920 | mso-style-qformat:yes; |
---|
921 | font-variant:small-caps; |
---|
922 | color:#C0504D; |
---|
923 | mso-themecolor:accent2; |
---|
924 | letter-spacing:.25pt; |
---|
925 | font-weight:bold; |
---|
926 | text-decoration:underline; |
---|
927 | text-underline:single;} |
---|
928 | span.Heading1Char |
---|
929 | {mso-style-name:"Heading 1 Char"; |
---|
930 | mso-style-priority:9; |
---|
931 | mso-style-unhide:no; |
---|
932 | mso-style-locked:yes; |
---|
933 | mso-style-link:"Heading 1"; |
---|
934 | mso-ansi-font-size:24.0pt; |
---|
935 | mso-bidi-font-size:24.0pt; |
---|
936 | font-family:"Times New Roman",serif; |
---|
937 | mso-ascii-font-family:"Times New Roman"; |
---|
938 | mso-fareast-font-family:"Times New Roman"; |
---|
939 | mso-fareast-theme-font:minor-fareast; |
---|
940 | mso-hansi-font-family:"Times New Roman"; |
---|
941 | mso-bidi-font-family:"Times New Roman"; |
---|
942 | mso-font-kerning:18.0pt; |
---|
943 | font-weight:bold;} |
---|
944 | span.Heading2Char |
---|
945 | {mso-style-name:"Heading 2 Char"; |
---|
946 | mso-style-priority:9; |
---|
947 | mso-style-unhide:no; |
---|
948 | mso-style-locked:yes; |
---|
949 | mso-style-link:"Heading 2"; |
---|
950 | mso-ansi-font-size:18.0pt; |
---|
951 | mso-bidi-font-size:18.0pt; |
---|
952 | font-family:"Times New Roman",serif; |
---|
953 | mso-ascii-font-family:"Times New Roman"; |
---|
954 | mso-fareast-font-family:"Times New Roman"; |
---|
955 | mso-fareast-theme-font:minor-fareast; |
---|
956 | mso-hansi-font-family:"Times New Roman"; |
---|
957 | mso-bidi-font-family:"Times New Roman"; |
---|
958 | font-weight:bold;} |
---|
959 | span.Heading3Char |
---|
960 | {mso-style-name:"Heading 3 Char"; |
---|
961 | mso-style-priority:9; |
---|
962 | mso-style-unhide:no; |
---|
963 | mso-style-locked:yes; |
---|
964 | mso-style-link:"Heading 3"; |
---|
965 | mso-ansi-font-size:13.5pt; |
---|
966 | mso-bidi-font-size:13.5pt; |
---|
967 | font-family:"Times New Roman",serif; |
---|
968 | mso-ascii-font-family:"Times New Roman"; |
---|
969 | mso-fareast-font-family:"Times New Roman"; |
---|
970 | mso-fareast-theme-font:minor-fareast; |
---|
971 | mso-hansi-font-family:"Times New Roman"; |
---|
972 | mso-bidi-font-family:"Times New Roman"; |
---|
973 | font-weight:bold;} |
---|
974 | span.Heading4Char |
---|
975 | {mso-style-name:"Heading 4 Char"; |
---|
976 | mso-style-noshow:yes; |
---|
977 | mso-style-priority:9; |
---|
978 | mso-style-unhide:no; |
---|
979 | mso-style-locked:yes; |
---|
980 | mso-style-link:"Heading 4"; |
---|
981 | mso-ansi-font-size:13.0pt; |
---|
982 | mso-bidi-font-size:13.0pt; |
---|
983 | font-family:"Cambria",serif; |
---|
984 | mso-ascii-font-family:Cambria; |
---|
985 | mso-ascii-theme-font:major-latin; |
---|
986 | mso-fareast-font-family:"Times New Roman"; |
---|
987 | mso-fareast-theme-font:major-fareast; |
---|
988 | mso-hansi-font-family:Cambria; |
---|
989 | mso-hansi-theme-font:major-latin; |
---|
990 | mso-bidi-font-family:"Times New Roman"; |
---|
991 | mso-bidi-theme-font:major-bidi; |
---|
992 | color:#4F81BD; |
---|
993 | mso-themecolor:accent1; |
---|
994 | font-weight:bold; |
---|
995 | font-style:italic;} |
---|
996 | span.Heading5Char |
---|
997 | {mso-style-name:"Heading 5 Char"; |
---|
998 | mso-style-noshow:yes; |
---|
999 | mso-style-priority:9; |
---|
1000 | mso-style-unhide:no; |
---|
1001 | mso-style-locked:yes; |
---|
1002 | mso-style-link:"Heading 5"; |
---|
1003 | mso-ansi-font-size:12.0pt; |
---|
1004 | mso-bidi-font-size:12.0pt; |
---|
1005 | font-family:"Times New Roman",serif; |
---|
1006 | mso-ascii-font-family:"Times New Roman"; |
---|
1007 | mso-fareast-font-family:"Times New Roman"; |
---|
1008 | mso-fareast-theme-font:minor-fareast; |
---|
1009 | mso-hansi-font-family:"Times New Roman"; |
---|
1010 | mso-bidi-font-family:"Times New Roman"; |
---|
1011 | color:#4F4FFF; |
---|
1012 | font-weight:bold;} |
---|
1013 | span.HTMLPreformattedChar |
---|
1014 | {mso-style-name:"HTML Preformatted Char"; |
---|
1015 | mso-style-noshow:yes; |
---|
1016 | mso-style-priority:99; |
---|
1017 | mso-style-unhide:no; |
---|
1018 | mso-style-locked:yes; |
---|
1019 | mso-style-link:"HTML Preformatted"; |
---|
1020 | mso-ansi-font-size:10.0pt; |
---|
1021 | mso-bidi-font-size:10.0pt; |
---|
1022 | font-family:"Courier New"; |
---|
1023 | mso-ascii-font-family:"Courier New"; |
---|
1024 | mso-fareast-font-family:"Times New Roman"; |
---|
1025 | mso-hansi-font-family:"Courier New"; |
---|
1026 | mso-bidi-font-family:"Courier New";} |
---|
1027 | p.msonormal0, li.msonormal0, div.msonormal0 |
---|
1028 | {mso-style-name:msonormal; |
---|
1029 | mso-style-noshow:yes; |
---|
1030 | mso-style-priority:99; |
---|
1031 | mso-style-unhide:no; |
---|
1032 | mso-margin-top-alt:auto; |
---|
1033 | margin-right:0in; |
---|
1034 | mso-margin-bottom-alt:auto; |
---|
1035 | margin-left:0in; |
---|
1036 | mso-pagination:widow-orphan; |
---|
1037 | font-size:12.0pt; |
---|
1038 | font-family:"Times New Roman",serif; |
---|
1039 | mso-fareast-font-family:"Times New Roman"; |
---|
1040 | mso-fareast-theme-font:minor-fareast;} |
---|
1041 | span.DocumentMapChar |
---|
1042 | {mso-style-name:"Document Map Char"; |
---|
1043 | mso-style-noshow:yes; |
---|
1044 | mso-style-priority:99; |
---|
1045 | mso-style-unhide:no; |
---|
1046 | mso-style-locked:yes; |
---|
1047 | mso-style-link:"Document Map"; |
---|
1048 | mso-ansi-font-size:8.0pt; |
---|
1049 | mso-bidi-font-size:8.0pt; |
---|
1050 | font-family:"Tahoma",sans-serif; |
---|
1051 | mso-ascii-font-family:Tahoma; |
---|
1052 | mso-fareast-font-family:"Times New Roman"; |
---|
1053 | mso-fareast-theme-font:minor-fareast; |
---|
1054 | mso-hansi-font-family:Tahoma; |
---|
1055 | mso-bidi-font-family:Tahoma;} |
---|
1056 | span.BalloonTextChar |
---|
1057 | {mso-style-name:"Balloon Text Char"; |
---|
1058 | mso-style-noshow:yes; |
---|
1059 | mso-style-priority:99; |
---|
1060 | mso-style-unhide:no; |
---|
1061 | mso-style-locked:yes; |
---|
1062 | mso-style-link:"Balloon Text"; |
---|
1063 | mso-ansi-font-size:8.0pt; |
---|
1064 | mso-bidi-font-size:8.0pt; |
---|
1065 | font-family:"Tahoma",sans-serif; |
---|
1066 | mso-ascii-font-family:Tahoma; |
---|
1067 | mso-fareast-font-family:"Times New Roman"; |
---|
1068 | mso-fareast-theme-font:minor-fareast; |
---|
1069 | mso-hansi-font-family:Tahoma; |
---|
1070 | mso-bidi-font-family:Tahoma;} |
---|
1071 | span.GSAS-IItextChar |
---|
1072 | {mso-style-name:"GSAS-II text Char"; |
---|
1073 | mso-style-unhide:no; |
---|
1074 | mso-style-locked:yes; |
---|
1075 | mso-style-link:"GSAS-II text"; |
---|
1076 | mso-ansi-font-size:12.0pt; |
---|
1077 | mso-bidi-font-size:12.0pt; |
---|
1078 | font-family:"Times New Roman",serif; |
---|
1079 | mso-ascii-font-family:"Times New Roman"; |
---|
1080 | mso-fareast-font-family:"Times New Roman"; |
---|
1081 | mso-fareast-theme-font:minor-fareast; |
---|
1082 | mso-hansi-font-family:"Times New Roman"; |
---|
1083 | mso-bidi-font-family:Calibri; |
---|
1084 | mso-bidi-theme-font:minor-latin; |
---|
1085 | font-weight:bold; |
---|
1086 | mso-bidi-font-weight:normal;} |
---|
1087 | p.GSAS-IItext, li.GSAS-IItext, div.GSAS-IItext |
---|
1088 | {mso-style-name:"GSAS-II text"; |
---|
1089 | mso-style-noshow:yes; |
---|
1090 | mso-style-priority:99; |
---|
1091 | mso-style-unhide:no; |
---|
1092 | mso-style-link:"GSAS-II text Char"; |
---|
1093 | margin:0in; |
---|
1094 | margin-bottom:.0001pt; |
---|
1095 | mso-pagination:widow-orphan; |
---|
1096 | font-size:12.0pt; |
---|
1097 | font-family:"Calibri",sans-serif; |
---|
1098 | mso-ascii-font-family:Calibri; |
---|
1099 | mso-ascii-theme-font:minor-latin; |
---|
1100 | mso-fareast-font-family:"Times New Roman"; |
---|
1101 | mso-fareast-theme-font:minor-fareast; |
---|
1102 | mso-hansi-font-family:Calibri; |
---|
1103 | mso-hansi-theme-font:minor-latin; |
---|
1104 | mso-bidi-font-family:Calibri; |
---|
1105 | mso-bidi-theme-font:minor-latin; |
---|
1106 | font-weight:bold; |
---|
1107 | mso-bidi-font-weight:normal;} |
---|
1108 | span.SpellE |
---|
1109 | {mso-style-name:""; |
---|
1110 | mso-spl-e:yes;} |
---|
1111 | span.GramE |
---|
1112 | {mso-style-name:""; |
---|
1113 | mso-gram-e:yes;} |
---|
1114 | .MsoChpDefault |
---|
1115 | {mso-style-type:export-only; |
---|
1116 | mso-default-props:yes; |
---|
1117 | font-size:10.0pt; |
---|
1118 | mso-ansi-font-size:10.0pt; |
---|
1119 | mso-bidi-font-size:10.0pt; |
---|
1120 | mso-ascii-font-family:Calibri; |
---|
1121 | mso-ascii-theme-font:minor-latin; |
---|
1122 | mso-fareast-font-family:Calibri; |
---|
1123 | mso-fareast-theme-font:minor-latin; |
---|
1124 | mso-hansi-font-family:Calibri; |
---|
1125 | mso-hansi-theme-font:minor-latin; |
---|
1126 | mso-bidi-font-family:"Times New Roman"; |
---|
1127 | mso-bidi-theme-font:minor-bidi;} |
---|
1128 | @page WordSection1 |
---|
1129 | {size:8.5in 11.0in; |
---|
1130 | margin:1.0in 1.0in 1.0in 1.0in; |
---|
1131 | mso-header-margin:.5in; |
---|
1132 | mso-footer-margin:.5in; |
---|
1133 | mso-paper-source:0;} |
---|
1134 | div.WordSection1 |
---|
1135 | {page:WordSection1;} |
---|
1136 | /* List Definitions */ |
---|
1137 | @list l0 |
---|
1138 | {mso-list-id:202911215; |
---|
1139 | mso-list-type:hybrid; |
---|
1140 | mso-list-template-ids:-373133466 -1909277668 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1141 | @list l0:level1 |
---|
1142 | {mso-level-tab-stop:none; |
---|
1143 | mso-level-number-position:left; |
---|
1144 | margin-left:.25in; |
---|
1145 | text-indent:-.25in;} |
---|
1146 | @list l0:level2 |
---|
1147 | {mso-level-number-format:alpha-lower; |
---|
1148 | mso-level-tab-stop:none; |
---|
1149 | mso-level-number-position:left; |
---|
1150 | margin-left:.75in; |
---|
1151 | text-indent:-.25in;} |
---|
1152 | @list l0:level3 |
---|
1153 | {mso-level-number-format:roman-lower; |
---|
1154 | mso-level-tab-stop:none; |
---|
1155 | mso-level-number-position:right; |
---|
1156 | margin-left:1.25in; |
---|
1157 | text-indent:-9.0pt;} |
---|
1158 | @list l0:level4 |
---|
1159 | {mso-level-tab-stop:none; |
---|
1160 | mso-level-number-position:left; |
---|
1161 | margin-left:1.75in; |
---|
1162 | text-indent:-.25in;} |
---|
1163 | @list l0:level5 |
---|
1164 | {mso-level-number-format:alpha-lower; |
---|
1165 | mso-level-tab-stop:none; |
---|
1166 | mso-level-number-position:left; |
---|
1167 | margin-left:2.25in; |
---|
1168 | text-indent:-.25in;} |
---|
1169 | @list l0:level6 |
---|
1170 | {mso-level-number-format:roman-lower; |
---|
1171 | mso-level-tab-stop:none; |
---|
1172 | mso-level-number-position:right; |
---|
1173 | margin-left:2.75in; |
---|
1174 | text-indent:-9.0pt;} |
---|
1175 | @list l0:level7 |
---|
1176 | {mso-level-tab-stop:none; |
---|
1177 | mso-level-number-position:left; |
---|
1178 | margin-left:3.25in; |
---|
1179 | text-indent:-.25in;} |
---|
1180 | @list l0:level8 |
---|
1181 | {mso-level-number-format:alpha-lower; |
---|
1182 | mso-level-tab-stop:none; |
---|
1183 | mso-level-number-position:left; |
---|
1184 | margin-left:3.75in; |
---|
1185 | text-indent:-.25in;} |
---|
1186 | @list l0:level9 |
---|
1187 | {mso-level-number-format:roman-lower; |
---|
1188 | mso-level-tab-stop:none; |
---|
1189 | mso-level-number-position:right; |
---|
1190 | margin-left:4.25in; |
---|
1191 | text-indent:-9.0pt;} |
---|
1192 | @list l1 |
---|
1193 | {mso-list-id:359747963; |
---|
1194 | mso-list-type:hybrid; |
---|
1195 | mso-list-template-ids:927871442 -757201862 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1196 | @list l1:level1 |
---|
1197 | {mso-level-tab-stop:none; |
---|
1198 | mso-level-number-position:left; |
---|
1199 | margin-left:.25in; |
---|
1200 | text-indent:-.25in;} |
---|
1201 | @list l1:level2 |
---|
1202 | {mso-level-number-format:alpha-lower; |
---|
1203 | mso-level-tab-stop:none; |
---|
1204 | mso-level-number-position:left; |
---|
1205 | margin-left:.75in; |
---|
1206 | text-indent:-.25in;} |
---|
1207 | @list l1:level3 |
---|
1208 | {mso-level-number-format:roman-lower; |
---|
1209 | mso-level-tab-stop:none; |
---|
1210 | mso-level-number-position:right; |
---|
1211 | margin-left:1.25in; |
---|
1212 | text-indent:-9.0pt;} |
---|
1213 | @list l1:level4 |
---|
1214 | {mso-level-tab-stop:none; |
---|
1215 | mso-level-number-position:left; |
---|
1216 | margin-left:1.75in; |
---|
1217 | text-indent:-.25in;} |
---|
1218 | @list l1:level5 |
---|
1219 | {mso-level-number-format:alpha-lower; |
---|
1220 | mso-level-tab-stop:none; |
---|
1221 | mso-level-number-position:left; |
---|
1222 | margin-left:2.25in; |
---|
1223 | text-indent:-.25in;} |
---|
1224 | @list l1:level6 |
---|
1225 | {mso-level-number-format:roman-lower; |
---|
1226 | mso-level-tab-stop:none; |
---|
1227 | mso-level-number-position:right; |
---|
1228 | margin-left:2.75in; |
---|
1229 | text-indent:-9.0pt;} |
---|
1230 | @list l1:level7 |
---|
1231 | {mso-level-tab-stop:none; |
---|
1232 | mso-level-number-position:left; |
---|
1233 | margin-left:3.25in; |
---|
1234 | text-indent:-.25in;} |
---|
1235 | @list l1:level8 |
---|
1236 | {mso-level-number-format:alpha-lower; |
---|
1237 | mso-level-tab-stop:none; |
---|
1238 | mso-level-number-position:left; |
---|
1239 | margin-left:3.75in; |
---|
1240 | text-indent:-.25in;} |
---|
1241 | @list l1:level9 |
---|
1242 | {mso-level-number-format:roman-lower; |
---|
1243 | mso-level-tab-stop:none; |
---|
1244 | mso-level-number-position:right; |
---|
1245 | margin-left:4.25in; |
---|
1246 | text-indent:-9.0pt;} |
---|
1247 | @list l2 |
---|
1248 | {mso-list-id:393742284; |
---|
1249 | mso-list-type:hybrid; |
---|
1250 | mso-list-template-ids:1241536890 67698703 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1251 | @list l2:level1 |
---|
1252 | {mso-level-tab-stop:none; |
---|
1253 | mso-level-number-position:left; |
---|
1254 | text-indent:-.25in;} |
---|
1255 | @list l2:level2 |
---|
1256 | {mso-level-number-format:alpha-lower; |
---|
1257 | mso-level-tab-stop:none; |
---|
1258 | mso-level-number-position:left; |
---|
1259 | text-indent:-.25in;} |
---|
1260 | @list l2:level3 |
---|
1261 | {mso-level-number-format:roman-lower; |
---|
1262 | mso-level-tab-stop:none; |
---|
1263 | mso-level-number-position:right; |
---|
1264 | text-indent:-9.0pt;} |
---|
1265 | @list l2:level4 |
---|
1266 | {mso-level-tab-stop:none; |
---|
1267 | mso-level-number-position:left; |
---|
1268 | text-indent:-.25in;} |
---|
1269 | @list l2:level5 |
---|
1270 | {mso-level-number-format:alpha-lower; |
---|
1271 | mso-level-tab-stop:none; |
---|
1272 | mso-level-number-position:left; |
---|
1273 | text-indent:-.25in;} |
---|
1274 | @list l2:level6 |
---|
1275 | {mso-level-number-format:roman-lower; |
---|
1276 | mso-level-tab-stop:none; |
---|
1277 | mso-level-number-position:right; |
---|
1278 | text-indent:-9.0pt;} |
---|
1279 | @list l2:level7 |
---|
1280 | {mso-level-tab-stop:none; |
---|
1281 | mso-level-number-position:left; |
---|
1282 | text-indent:-.25in;} |
---|
1283 | @list l2:level8 |
---|
1284 | {mso-level-number-format:alpha-lower; |
---|
1285 | mso-level-tab-stop:none; |
---|
1286 | mso-level-number-position:left; |
---|
1287 | text-indent:-.25in;} |
---|
1288 | @list l2:level9 |
---|
1289 | {mso-level-number-format:roman-lower; |
---|
1290 | mso-level-tab-stop:none; |
---|
1291 | mso-level-number-position:right; |
---|
1292 | text-indent:-9.0pt;} |
---|
1293 | @list l3 |
---|
1294 | {mso-list-id:608973138; |
---|
1295 | mso-list-type:hybrid; |
---|
1296 | mso-list-template-ids:-1449999034 67698703 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1297 | @list l3:level1 |
---|
1298 | {mso-level-tab-stop:none; |
---|
1299 | mso-level-number-position:left; |
---|
1300 | margin-left:.25in; |
---|
1301 | text-indent:-.25in;} |
---|
1302 | @list l3:level2 |
---|
1303 | {mso-level-number-format:alpha-lower; |
---|
1304 | mso-level-tab-stop:none; |
---|
1305 | mso-level-number-position:left; |
---|
1306 | margin-left:.75in; |
---|
1307 | text-indent:-.25in;} |
---|
1308 | @list l3:level3 |
---|
1309 | {mso-level-number-format:roman-lower; |
---|
1310 | mso-level-tab-stop:none; |
---|
1311 | mso-level-number-position:right; |
---|
1312 | margin-left:1.25in; |
---|
1313 | text-indent:-9.0pt;} |
---|
1314 | @list l3:level4 |
---|
1315 | {mso-level-tab-stop:none; |
---|
1316 | mso-level-number-position:left; |
---|
1317 | margin-left:1.75in; |
---|
1318 | text-indent:-.25in;} |
---|
1319 | @list l3:level5 |
---|
1320 | {mso-level-number-format:alpha-lower; |
---|
1321 | mso-level-tab-stop:none; |
---|
1322 | mso-level-number-position:left; |
---|
1323 | margin-left:2.25in; |
---|
1324 | text-indent:-.25in;} |
---|
1325 | @list l3:level6 |
---|
1326 | {mso-level-number-format:roman-lower; |
---|
1327 | mso-level-tab-stop:none; |
---|
1328 | mso-level-number-position:right; |
---|
1329 | margin-left:2.75in; |
---|
1330 | text-indent:-9.0pt;} |
---|
1331 | @list l3:level7 |
---|
1332 | {mso-level-tab-stop:none; |
---|
1333 | mso-level-number-position:left; |
---|
1334 | margin-left:3.25in; |
---|
1335 | text-indent:-.25in;} |
---|
1336 | @list l3:level8 |
---|
1337 | {mso-level-number-format:alpha-lower; |
---|
1338 | mso-level-tab-stop:none; |
---|
1339 | mso-level-number-position:left; |
---|
1340 | margin-left:3.75in; |
---|
1341 | text-indent:-.25in;} |
---|
1342 | @list l3:level9 |
---|
1343 | {mso-level-number-format:roman-lower; |
---|
1344 | mso-level-tab-stop:none; |
---|
1345 | mso-level-number-position:right; |
---|
1346 | margin-left:4.25in; |
---|
1347 | text-indent:-9.0pt;} |
---|
1348 | @list l4 |
---|
1349 | {mso-list-id:681592023; |
---|
1350 | mso-list-type:hybrid; |
---|
1351 | mso-list-template-ids:-1677018064 1906637506 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1352 | @list l4:level1 |
---|
1353 | {mso-level-tab-stop:none; |
---|
1354 | mso-level-number-position:left; |
---|
1355 | text-indent:-.25in;} |
---|
1356 | @list l4:level2 |
---|
1357 | {mso-level-number-format:alpha-lower; |
---|
1358 | mso-level-tab-stop:none; |
---|
1359 | mso-level-number-position:left; |
---|
1360 | text-indent:-.25in;} |
---|
1361 | @list l4:level3 |
---|
1362 | {mso-level-number-format:roman-lower; |
---|
1363 | mso-level-tab-stop:none; |
---|
1364 | mso-level-number-position:right; |
---|
1365 | text-indent:-9.0pt;} |
---|
1366 | @list l4:level4 |
---|
1367 | {mso-level-tab-stop:none; |
---|
1368 | mso-level-number-position:left; |
---|
1369 | text-indent:-.25in;} |
---|
1370 | @list l4:level5 |
---|
1371 | {mso-level-number-format:alpha-lower; |
---|
1372 | mso-level-tab-stop:none; |
---|
1373 | mso-level-number-position:left; |
---|
1374 | text-indent:-.25in;} |
---|
1375 | @list l4:level6 |
---|
1376 | {mso-level-number-format:roman-lower; |
---|
1377 | mso-level-tab-stop:none; |
---|
1378 | mso-level-number-position:right; |
---|
1379 | text-indent:-9.0pt;} |
---|
1380 | @list l4:level7 |
---|
1381 | {mso-level-tab-stop:none; |
---|
1382 | mso-level-number-position:left; |
---|
1383 | text-indent:-.25in;} |
---|
1384 | @list l4:level8 |
---|
1385 | {mso-level-number-format:alpha-lower; |
---|
1386 | mso-level-tab-stop:none; |
---|
1387 | mso-level-number-position:left; |
---|
1388 | text-indent:-.25in;} |
---|
1389 | @list l4:level9 |
---|
1390 | {mso-level-number-format:roman-lower; |
---|
1391 | mso-level-tab-stop:none; |
---|
1392 | mso-level-number-position:right; |
---|
1393 | text-indent:-9.0pt;} |
---|
1394 | @list l5 |
---|
1395 | {mso-list-id:961418051; |
---|
1396 | mso-list-type:hybrid; |
---|
1397 | mso-list-template-ids:-1150113346 -757201862 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1398 | @list l5:level1 |
---|
1399 | {mso-level-tab-stop:none; |
---|
1400 | mso-level-number-position:left; |
---|
1401 | margin-left:.25in; |
---|
1402 | text-indent:-.25in;} |
---|
1403 | @list l5:level2 |
---|
1404 | {mso-level-number-format:alpha-lower; |
---|
1405 | mso-level-tab-stop:none; |
---|
1406 | mso-level-number-position:left; |
---|
1407 | margin-left:45.0pt; |
---|
1408 | text-indent:-.25in;} |
---|
1409 | @list l5:level3 |
---|
1410 | {mso-level-number-format:roman-lower; |
---|
1411 | mso-level-tab-stop:none; |
---|
1412 | mso-level-number-position:right; |
---|
1413 | margin-left:81.0pt; |
---|
1414 | text-indent:-9.0pt;} |
---|
1415 | @list l5:level4 |
---|
1416 | {mso-level-tab-stop:none; |
---|
1417 | mso-level-number-position:left; |
---|
1418 | margin-left:117.0pt; |
---|
1419 | text-indent:-.25in;} |
---|
1420 | @list l5:level5 |
---|
1421 | {mso-level-number-format:alpha-lower; |
---|
1422 | mso-level-tab-stop:none; |
---|
1423 | mso-level-number-position:left; |
---|
1424 | margin-left:153.0pt; |
---|
1425 | text-indent:-.25in;} |
---|
1426 | @list l5:level6 |
---|
1427 | {mso-level-number-format:roman-lower; |
---|
1428 | mso-level-tab-stop:none; |
---|
1429 | mso-level-number-position:right; |
---|
1430 | margin-left:189.0pt; |
---|
1431 | text-indent:-9.0pt;} |
---|
1432 | @list l5:level7 |
---|
1433 | {mso-level-tab-stop:none; |
---|
1434 | mso-level-number-position:left; |
---|
1435 | margin-left:225.0pt; |
---|
1436 | text-indent:-.25in;} |
---|
1437 | @list l5:level8 |
---|
1438 | {mso-level-number-format:alpha-lower; |
---|
1439 | mso-level-tab-stop:none; |
---|
1440 | mso-level-number-position:left; |
---|
1441 | margin-left:261.0pt; |
---|
1442 | text-indent:-.25in;} |
---|
1443 | @list l5:level9 |
---|
1444 | {mso-level-number-format:roman-lower; |
---|
1445 | mso-level-tab-stop:none; |
---|
1446 | mso-level-number-position:right; |
---|
1447 | margin-left:297.0pt; |
---|
1448 | text-indent:-9.0pt;} |
---|
1449 | @list l6 |
---|
1450 | {mso-list-id:963118815; |
---|
1451 | mso-list-type:hybrid; |
---|
1452 | mso-list-template-ids:-1617130662 67698703 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1453 | @list l6:level1 |
---|
1454 | {mso-level-tab-stop:none; |
---|
1455 | mso-level-number-position:left; |
---|
1456 | text-indent:-.25in;} |
---|
1457 | @list l6:level2 |
---|
1458 | {mso-level-number-format:alpha-lower; |
---|
1459 | mso-level-tab-stop:none; |
---|
1460 | mso-level-number-position:left; |
---|
1461 | text-indent:-.25in;} |
---|
1462 | @list l6:level3 |
---|
1463 | {mso-level-number-format:roman-lower; |
---|
1464 | mso-level-tab-stop:none; |
---|
1465 | mso-level-number-position:right; |
---|
1466 | text-indent:-9.0pt;} |
---|
1467 | @list l6:level4 |
---|
1468 | {mso-level-tab-stop:none; |
---|
1469 | mso-level-number-position:left; |
---|
1470 | text-indent:-.25in;} |
---|
1471 | @list l6:level5 |
---|
1472 | {mso-level-number-format:alpha-lower; |
---|
1473 | mso-level-tab-stop:none; |
---|
1474 | mso-level-number-position:left; |
---|
1475 | text-indent:-.25in;} |
---|
1476 | @list l6:level6 |
---|
1477 | {mso-level-number-format:roman-lower; |
---|
1478 | mso-level-tab-stop:none; |
---|
1479 | mso-level-number-position:right; |
---|
1480 | text-indent:-9.0pt;} |
---|
1481 | @list l6:level7 |
---|
1482 | {mso-level-tab-stop:none; |
---|
1483 | mso-level-number-position:left; |
---|
1484 | text-indent:-.25in;} |
---|
1485 | @list l6:level8 |
---|
1486 | {mso-level-number-format:alpha-lower; |
---|
1487 | mso-level-tab-stop:none; |
---|
1488 | mso-level-number-position:left; |
---|
1489 | text-indent:-.25in;} |
---|
1490 | @list l6:level9 |
---|
1491 | {mso-level-number-format:roman-lower; |
---|
1492 | mso-level-tab-stop:none; |
---|
1493 | mso-level-number-position:right; |
---|
1494 | text-indent:-9.0pt;} |
---|
1495 | @list l7 |
---|
1496 | {mso-list-id:974749577; |
---|
1497 | mso-list-type:hybrid; |
---|
1498 | mso-list-template-ids:-1150113346 -757201862 67698713 67698715 67698703 67698713 67698715 67698703 67698713 67698715;} |
---|
1499 | @list l7:level1 |
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1680 | |
---|
1681 | <div class=WordSection1> |
---|
1682 | |
---|
1683 | <h1>Magnetic Structures in GSAS-II - IV</h1> |
---|
1684 | |
---|
1685 | <h2>Introduction</h2> |
---|
1686 | |
---|
1687 | <p class=MsoNormal>In this tutorial, we will show how GSAS-II makes use of the |
---|
1688 | Bilbao crystallographic server (<a href="http://www.cryst.ehu.es/">www.cryst.ehu.es/</a>) |
---|
1689 | <i style='mso-bidi-font-style:normal'>Magnetic Symmetry and Applications</i> routine |
---|
1690 | k-SUBGROUPSMAG (<a href="http://iopscience.iop.org/0953-8984/28/28/286001"><span |
---|
1691 | style='font-size:10.0pt;font-family:"Arial",sans-serif'>Perez-Mato, JM; <span |
---|
1692 | class=SpellE>Gallego</span>, SV; <span class=SpellE>Elcoro</span>, L; <span |
---|
1693 | class=SpellE>Tasci</span>, E and <span class=SpellE>Aroyo</span>, MI, <i>J. of |
---|
1694 | Phys.: <span class=SpellE>Condens</span> Matter</i> (2016), <b>28</b>:28601</span></a>) |
---|
1695 | to determine a magnetic crystal structure with two non-zero propagation |
---|
1696 | vectors. If you have not done so already, you may wish to do the Simple |
---|
1697 | Magnetic Structures tutorial first as it contains some background information |
---|
1698 | that will not be covered here. It is also helpful to do parts I - IV of the |
---|
1699 | series of Magnetic Structures tutorials. To make this work, your computer must |
---|
1700 | have an internet connection for GSAS-II to access this site. (We will supply |
---|
1701 | the project file that results after k-SUBGROUPSMAG is called in case you lack |
---|
1702 | internet access).</p> |
---|
1703 | |
---|
1704 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shapetype |
---|
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1721 | </v:formulas> |
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---|
1725 | style='width:358.5pt;height:477.75pt;visibility:visible;mso-wrap-style:square'> |
---|
1726 | <v:imagedata src="Magnetic-V_files/image001.png" o:title=""/> |
---|
1727 | </v:shape><![endif]--><![if !vml]><img border=0 width=478 height=637 |
---|
1728 | src="Magnetic-V_files/image038.gif" v:shapes="Picture_x0020_1"><![endif]></span></p> |
---|
1729 | |
---|
1730 | <p class=MsoNormal>In this tutorial we will be examining Mn<sub>3</sub>O<sub>4</sub> |
---|
1731 | (<span class=SpellE>hausmannite</span>), which shows two apparent magnetic |
---|
1732 | phase transitions between the paramagnetic phase above T<sub>N</sub> = 41K and |
---|
1733 | the lowest temperature explored (4.7K). The paramagnetic phase of Mn<sub>3</sub>O<sub>4</sub> |
---|
1734 | is a tetragonal distortion of the cubic spinel structure (drawing above) with |
---|
1735 | space group I4<sub>1</sub>/<span class=SpellE>amd</span>, a=5.765 and c=9.442 Å |
---|
1736 | at room temperature.<span style='mso-spacerun:yes'> </span>Time-of-flight |
---|
1737 | (TOF) neutron powder diffraction data of the paramagnetic phase was collected |
---|
1738 | on POWGEN (SNS, Oak Ridge National Laboratory) at 60K and the magnetic phase at |
---|
1739 | 10K with 2 frames of data for each. The magnetic structure was originally |
---|
1740 | determined by <span style='font-size:11.5pt'>Boucher, et al. (Boucher, B., |
---|
1741 | Buhl, R. & Perrin, M. (1971), J. Phys. Chem. Solids, 32, 2429-2437) and |
---|
1742 | reexamined by Jensen & Nielsen (Jensen, J.B. & Nielsen, O.V. J. Phys. |
---|
1743 | C: Solid State Phys. (1974), 7, 409-424). We will first refine the paramagnetic |
---|
1744 | phase and use that as the starting point for the magnetic structure determination. |
---|
1745 | As we will see the magnetic space group is a subgroup of I4<sub>1</sub>/<span |
---|
1746 | class=SpellE>amd</span> by both a loss the body centering symmetry and a unit |
---|
1747 | cell doubling along one of the equivalent tetragonal <span class=SpellE>a<span |
---|
1748 | class=GramE>,b</span></span>-axes. </span>We will use k-SUBGROUPSMAG to help |
---|
1749 | sort this out. NB: the <span class=SpellE>Bilboa</span> MAGNDATA data base |
---|
1750 | contains an entry for Mn<sub>3</sub>O<sub>4</sub> (#1.1), but it is for a |
---|
1751 | different phase of this material and is thus unrelated to this tutorial.</p> |
---|
1752 | |
---|
1753 | <p class=MsoNormal><o:p> </o:p></p> |
---|
1754 | |
---|
1755 | <p class=MsoNormal>If you have not done so already, start GSAS-II (make sure |
---|
1756 | about the internet connection!).</p> |
---|
1757 | |
---|
1758 | <h1>Refinement of paramagnetic Mn<sub>3</sub>O<sub>4</sub></h1> |
---|
1759 | |
---|
1760 | <h2><span style='mso-spacerun:yes'> </span>Step 1. Read in the data files</h2> |
---|
1761 | |
---|
1762 | <p class=MsoListParagraphCxSpFirst style='margin-left:.25in;mso-add-space:auto; |
---|
1763 | text-indent:-.25in;mso-list:l3 level1 lfo2'><![if !supportLists]><span |
---|
1764 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
1765 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Use |
---|
1766 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1767 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1768 | minor-latin'>Import/Powder Data/from TOPAS <span class=SpellE>xye</span> or |
---|
1769 | Fit2D chi file</span></b> menu item to read the data file into the current |
---|
1770 | GSAS-II project. This read option is set to read the <span class=SpellE><b |
---|
1771 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1772 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1773 | minor-latin'>xye</span></b></span> format (angles in degrees) used by <span |
---|
1774 | class=SpellE>Topas</span>, etc.<span style='mso-spacerun:yes'> </span>Because |
---|
1775 | you used <span style='mso-fareast-font-family:Calibri;mso-fareast-theme-font: |
---|
1776 | minor-latin'>the </span><b style='mso-bidi-font-weight:normal'><span |
---|
1777 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1778 | mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1779 | minor-latin'>Help/Download tutorial</span></b><span style='mso-fareast-font-family: |
---|
1780 | Calibri;mso-fareast-theme-font:minor-latin'> menu entry to open this page and |
---|
1781 | downloaded the exercise files (recommended), then the </span><b |
---|
1782 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1783 | mso-ascii-theme-font:minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font: |
---|
1784 | minor-latin;mso-hansi-theme-font:minor-latin'>Magnetic-V/data/...</span></b><span |
---|
1785 | style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'> |
---|
1786 | entry will bring you to the location where the files have been downloaded. (It is |
---|
1787 | also possible to download them manually from <a |
---|
1788 | href="https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-V/data/">https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-V/data/</a>. |
---|
1789 | In this case you will need to navigate to the download location manually.)<br> |
---|
1790 | For this tutorial you will see the data file in the file browser, because the |
---|
1791 | extensions on data files are the expected ones.</span></p> |
---|
1792 | |
---|
1793 | <p class=MsoListParagraphCxSpLast style='margin-left:.25in;mso-add-space:auto; |
---|
1794 | text-indent:-.25in;mso-list:l3 level1 lfo2'><![if !supportLists]><span |
---|
1795 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>2.<span |
---|
1796 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Select |
---|
1797 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1798 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1799 | minor-latin'>PG3_20256-2_60K.xye </span></b><span style='font-family:"Calibri",sans-serif; |
---|
1800 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1801 | minor-latin'>data</span> file in the first dialog and press <b |
---|
1802 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1803 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1804 | minor-latin'>Open</span></b>. There will be a Dialog box asking <span |
---|
1805 | class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1806 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1807 | minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
1808 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1809 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1810 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
1811 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1812 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1813 | minor-latin'>Yes</span></b></span> button to proceed. <b style='mso-bidi-font-weight: |
---|
1814 | normal'>NB:</b> Dont be tempted to read both data sets at once. The problem |
---|
1815 | with the <span class=SpellE>xye</span> format is that it has no provision for |
---|
1816 | identifying the instrument parameter file or the frame (Bank) number of the data. |
---|
1817 | If you did read both, then GSAS-II would use the <span class=SpellE>instprm</span> |
---|
1818 | file read in the next step and apply it inappropriately to both data sets. One |
---|
1819 | can recover from this error by selecting Instrument parameters and doing |
---|
1820 | Operations/Load parameters with the correct file. Since this data file does not |
---|
1821 | define an instrument parameter file, a file dialog will appear for you to |
---|
1822 | select the correct instrument parameter file. Select <b style='mso-bidi-font-weight: |
---|
1823 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1824 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Bank |
---|
1825 | 2.instprm</span></b>; you may have to change the file type in the file |
---|
1826 | selection Dialog box to <b style='mso-bidi-font-weight:normal'><span |
---|
1827 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1828 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>GSAS-II <span |
---|
1829 | class=SpellE>instprm</span> file</span></b> to see it. At this point the <b |
---|
1830 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1831 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1832 | minor-latin'>GSAS-II data tree</span></b> window will have several entries </p> |
---|
1833 | |
---|
1834 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1835 | id="Picture_x0020_2" o:spid="_x0000_i1077" type="#_x0000_t75" style='width:339pt; |
---|
1836 | height:214.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1837 | <v:imagedata src="Magnetic-V_files/image003.png" o:title=""/> |
---|
1838 | </v:shape><![endif]--><![if !vml]><img border=0 width=452 height=286 |
---|
1839 | src="Magnetic-V_files/image039.gif" v:shapes="Picture_x0020_2"><![endif]></span></p> |
---|
1840 | |
---|
1841 | <p class=MsoNormal style='margin-left:.25in'><span class=GramE>and</span> the |
---|
1842 | plot window will show the powder pattern</p> |
---|
1843 | |
---|
1844 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1845 | id="Picture_x0020_3" o:spid="_x0000_i1076" type="#_x0000_t75" style='width:341.25pt; |
---|
1846 | height:303pt;visibility:visible;mso-wrap-style:square'> |
---|
1847 | <v:imagedata src="Magnetic-V_files/image005.png" o:title=""/> |
---|
1848 | </v:shape><![endif]--><![if !vml]><img border=0 width=455 height=404 |
---|
1849 | src="Magnetic-V_files/image040.gif" v:shapes="Picture_x0020_3"><![endif]></span></p> |
---|
1850 | |
---|
1851 | <p class=MsoNormal style='margin-left:.25in'><span class=GramE>which</span> |
---|
1852 | covers the d-spacing range 0.4-4.545 Å. This is the high resolution frame for |
---|
1853 | POWGEN and is collected by a selected setting of the beam choppers. Go to <b |
---|
1854 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1855 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1856 | minor-latin'>Limits</span></b></p> |
---|
1857 | |
---|
1858 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1859 | id="Picture_x0020_4" o:spid="_x0000_i1075" type="#_x0000_t75" style='width:340.5pt; |
---|
1860 | height:189pt;visibility:visible;mso-wrap-style:square'> |
---|
1861 | <v:imagedata src="Magnetic-V_files/image007.png" o:title=""/> |
---|
1862 | </v:shape><![endif]--><![if !vml]><img border=0 width=454 height=252 |
---|
1863 | src="Magnetic-V_files/image041.gif" v:shapes="Picture_x0020_4"><![endif]></span></p> |
---|
1864 | |
---|
1865 | <p class=MsoNormal style='margin-left:.25in'>We want to remove the |
---|
1866 | uninteresting high TOF part and limit the low TOF to something reasonable. I |
---|
1867 | used <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1868 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1869 | minor-latin'>12500</span></b> and <b style='mso-bidi-font-weight:normal'><span |
---|
1870 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1871 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>75000</span></b>; |
---|
1872 | the lower one corresponds to d<sub>min</sub>~0.55 Å and the upper one is just |
---|
1873 | beyond the last visible peak. Now we have to read the other frame.</p> |
---|
1874 | |
---|
1875 | <p class=MsoListParagraphCxSpFirst style='margin-left:.25in;mso-add-space:auto; |
---|
1876 | text-indent:-.25in;mso-list:l3 level1 lfo2'><![if !supportLists]><span |
---|
1877 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>3.<span |
---|
1878 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Do |
---|
1879 | <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1880 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1881 | minor-latin'>Import/Powder Data/from TOPAS <span class=SpellE>xye</span> or |
---|
1882 | Fit2D chi file</span></b> and select the <b style='mso-bidi-font-weight:normal'><span |
---|
1883 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1884 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>PG3_20269-4_60K.xye |
---|
1885 | </span></b><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1886 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>data</span> |
---|
1887 | file in the first dialog and press <b style='mso-bidi-font-weight:normal'><span |
---|
1888 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1889 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Open</span></b>. |
---|
1890 | There will be a Dialog box asking <span class=GramE><b style='mso-bidi-font-weight: |
---|
1891 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1892 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
1893 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1894 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1895 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
1896 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1897 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1898 | minor-latin'>Yes</span></b></span> button to proceed.</p> |
---|
1899 | |
---|
1900 | <p class=MsoListParagraphCxSpLast style='margin-left:.25in;mso-add-space:auto; |
---|
1901 | text-indent:-.25in;mso-list:l3 level1 lfo2'><![if !supportLists]><span |
---|
1902 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>4.<span |
---|
1903 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Since |
---|
1904 | this data file does not define an instrument parameter file, a file dialog will |
---|
1905 | appear for you to select the correct instrument parameter file. Select <b |
---|
1906 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1907 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1908 | minor-latin'>Bank 4.instprm</span></b>; you may have to change the file type in |
---|
1909 | the file selection Dialog box to <b style='mso-bidi-font-weight:normal'><span |
---|
1910 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1911 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>GSAS-II <span |
---|
1912 | class=SpellE>instprm</span> file</span></b> to see it. At this point the <b |
---|
1913 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1914 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1915 | minor-latin'>GSAS-II data tree</span></b> window will have more entries </p> |
---|
1916 | |
---|
1917 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1918 | id="Picture_x0020_5" o:spid="_x0000_i1074" type="#_x0000_t75" style='width:341.25pt; |
---|
1919 | height:352.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1920 | <v:imagedata src="Magnetic-V_files/image009.png" o:title=""/> |
---|
1921 | </v:shape><![endif]--><![if !vml]><img border=0 width=455 height=470 |
---|
1922 | src="Magnetic-V_files/image042.gif" v:shapes="Picture_x0020_5"><![endif]></span></p> |
---|
1923 | |
---|
1924 | <p class=MsoNormal style='margin-left:.25in'>And the plot will show this larger |
---|
1925 | d-spacing (1.15-9.0 Å) frame collected with a different set of chopper |
---|
1926 | settings. Notice that there is now a peak (d=4.94 Å) which was beyond the range |
---|
1927 | of the other frame. Go to <b style='mso-bidi-font-weight:normal'><span |
---|
1928 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1929 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Limits</span></b> |
---|
1930 | for this data set and set the upper limit to 125000; leave the lower limit as |
---|
1931 | it is.</p> |
---|
1932 | |
---|
1933 | <h2>Step 2. Read in the chemical structure for Mn<sub>3</sub>O<sub>4</sub> (<span |
---|
1934 | class=SpellE>hausmannite</span>)</h2> |
---|
1935 | |
---|
1936 | <p class=MsoListParagraphCxSpFirst style='margin-left:.25in;mso-add-space:auto; |
---|
1937 | text-indent:-.25in;mso-list:l7 level1 lfo4'><![if !supportLists]><span |
---|
1938 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
1939 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Use |
---|
1940 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1941 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1942 | minor-latin'>Import/Phase/from CIF file</span></b> menu item to read the phase |
---|
1943 | information for Mn<sub>3</sub>O<sub>4</sub> into the current GSAS-II project. |
---|
1944 | This read option is set to read Crystallographic Information Files (CIF). Other |
---|
1945 | submenu items will read phase information in other formats.<span |
---|
1946 | style='mso-spacerun:yes'> </span>Because you used <span style='mso-fareast-font-family: |
---|
1947 | Calibri;mso-fareast-theme-font:minor-latin'>the </span><b style='mso-bidi-font-weight: |
---|
1948 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1949 | minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin; |
---|
1950 | mso-hansi-theme-font:minor-latin'>Help/Download tutorial</span></b><span |
---|
1951 | style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'> |
---|
1952 | menu entry to open this page and downloaded the exercise files (recommended), |
---|
1953 | then the </span><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1954 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-fareast-font-family: |
---|
1955 | Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin'>Magnetic-V/data/...</span></b><span |
---|
1956 | style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'> |
---|
1957 | entry will bring you to the location where the files have been downloaded. (It |
---|
1958 | is also possible to download them manually from <a |
---|
1959 | href="https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-V/data/">https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-V/data/</a>. |
---|
1960 | In this case you will need to navigate to the download location manually.)</span></p> |
---|
1961 | |
---|
1962 | <p class=MsoListParagraphCxSpLast style='margin-left:.25in;mso-add-space:auto; |
---|
1963 | text-indent:-.25in;mso-list:l7 level1 lfo4'><![if !supportLists]><span |
---|
1964 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>2.<span |
---|
1965 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Select |
---|
1966 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1967 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1968 | minor-latin'>Mn3O4-Hausmannite.cif</span></b><span style='font-family:"Calibri",sans-serif; |
---|
1969 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1970 | minor-latin'> data</span> file in the first dialog and press <b |
---|
1971 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1972 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1973 | minor-latin'>Open</span></b>. There will be a Dialog box asking <span |
---|
1974 | class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1975 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1976 | minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
1977 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1978 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1979 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
1980 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1981 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1982 | minor-latin'>Yes</span></b></span> button to proceed. You will get the |
---|
1983 | opportunity to change the phase name next (I took out the space!); press <b |
---|
1984 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1985 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1986 | minor-latin'>OK</span></b> to continue.</p> |
---|
1987 | |
---|
1988 | <p class=MsoNormal>Next is the histogram selection window; this connects the |
---|
1989 | phase to the data so it can be used in subsequent calculations.<span |
---|
1990 | style='mso-no-proof:yes'> </span>Select the histograms (or press <b |
---|
1991 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1992 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1993 | minor-latin'>Set All</span></b>) and press <b style='mso-bidi-font-weight:normal'><span |
---|
1994 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1995 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
1996 | The General tab for the phase is shown next<br> |
---|
1997 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_6" |
---|
1998 | o:spid="_x0000_i1073" type="#_x0000_t75" style='width:362.25pt;height:201pt; |
---|
1999 | visibility:visible;mso-wrap-style:square'> |
---|
2000 | <v:imagedata src="Magnetic-V_files/image011.png" o:title=""/> |
---|
2001 | </v:shape><![endif]--><![if !vml]><img border=0 width=483 height=268 |
---|
2002 | src="Magnetic-V_files/image043.gif" v:shapes="Picture_x0020_6"><![endif]></span></p> |
---|
2003 | |
---|
2004 | <h3>Step 3. Structure refinement</h3> |
---|
2005 | |
---|
2006 | <p class=MsoNormal>We are now ready for initial refinement of scale and |
---|
2007 | background. Do <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2008 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2009 | minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> from the |
---|
2010 | main menu; a File Selection dialog will appear wanting a file name for your |
---|
2011 | project. I used <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2012 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2013 | minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 60K</span></b>; the |
---|
2014 | refinement proceeded quickly. The fit is ok for a start (<span class=SpellE>wR</span> |
---|
2015 | ~23%), mostly from poorly fitting background; select <b style='mso-bidi-font-weight: |
---|
2016 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2017 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Background</span></b> |
---|
2018 | for both PWDR data sets and change the number of terms to 6. Then go to the <b |
---|
2019 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2020 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2021 | minor-latin'>Mn3O4</span></b> phase and set the lattice parameter refinement. |
---|
2022 | Do <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2023 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2024 | minor-latin'>Calculate/Refine</span></b>; the residual will be much improved (<span |
---|
2025 | class=SpellE>wR</span>=13.4%). Finally, go to the <b style='mso-bidi-font-weight: |
---|
2026 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2027 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Atoms</span></b> |
---|
2028 | tab and set refinement flags <b style='mso-bidi-font-weight:normal'><span |
---|
2029 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2030 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>XU</span></b> |
---|
2031 | for all atoms. Do <b style='mso-bidi-font-weight:normal'><span |
---|
2032 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2033 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b>; |
---|
2034 | the residual will be a bit better (<span class=SpellE>wR</span> = 10.16%). This |
---|
2035 | is a pretty good fit; we should be able to get as good a fit with the magnetic |
---|
2036 | structure. We are done with this step; <span class=GramE><b style='mso-bidi-font-weight: |
---|
2037 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2038 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Save</span></b></span> |
---|
2039 | the project & close GSAS-II; we will use this phase information for the |
---|
2040 | magnetic structure study.</p> |
---|
2041 | |
---|
2042 | <h1>The magnetic structure of Mn<sub>3</sub>O<sub>4</sub> at 10K</h1> |
---|
2043 | |
---|
2044 | <h2>Step 1. Read in the data files</h2> |
---|
2045 | |
---|
2046 | <p class=MsoNormal>If you have not done so already, start GSAS-II (make sure |
---|
2047 | about the internet connection!).</p> |
---|
2048 | |
---|
2049 | <p class=MsoListParagraphCxSpFirst style='margin-left:.25in;mso-add-space:auto; |
---|
2050 | text-indent:-.25in;mso-list:l5 level1 lfo6'><![if !supportLists]><span |
---|
2051 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
2052 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Use |
---|
2053 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2054 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2055 | minor-latin'>Import/Powder Data/from TOPAS <span class=SpellE>xye</span> or |
---|
2056 | Fit2D chi file</span></b> menu item to read the data file into the current |
---|
2057 | GSAS-II project. This read option is set to read the <span class=SpellE><b |
---|
2058 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2059 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2060 | minor-latin'>xye</span></b></span> format (angles in degrees) used by <span |
---|
2061 | class=SpellE>Topas</span>, etc.<span style='mso-spacerun:yes'> </span>Because |
---|
2062 | you used <span style='mso-fareast-font-family:Calibri;mso-fareast-theme-font: |
---|
2063 | minor-latin'>the </span><b style='mso-bidi-font-weight:normal'><span |
---|
2064 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2065 | mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2066 | minor-latin'>Help/Download tutorial</span></b><span style='mso-fareast-font-family: |
---|
2067 | Calibri;mso-fareast-theme-font:minor-latin'> menu entry to open this page and |
---|
2068 | downloaded the exercise files (recommended), then the </span><b |
---|
2069 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2070 | mso-ascii-theme-font:minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font: |
---|
2071 | minor-latin;mso-hansi-theme-font:minor-latin'>Magnetic-V/data/...</span></b><span |
---|
2072 | style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'> |
---|
2073 | entry will bring you to the location where the files have been downloaded. (It |
---|
2074 | is also possible to download them manually from <a |
---|
2075 | href="https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-V/data/">https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-V/data/</a>. |
---|
2076 | In this case you will need to navigate to the download location manually.)<br> |
---|
2077 | For this tutorial you will see the data file in the file browser, because the |
---|
2078 | extensions on data files are the expected ones.</span></p> |
---|
2079 | |
---|
2080 | <p class=MsoListParagraphCxSpMiddle style='margin-left:.25in;mso-add-space: |
---|
2081 | auto;text-indent:-.25in;mso-list:l5 level1 lfo6'><![if !supportLists]><span |
---|
2082 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>2.<span |
---|
2083 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Select |
---|
2084 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2085 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2086 | minor-latin'>PG3_20254-2_10K.xye </span></b><span style='font-family:"Calibri",sans-serif; |
---|
2087 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2088 | minor-latin'>data</span> file in the first dialog and press <b |
---|
2089 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2090 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2091 | minor-latin'>Open</span></b>. There will be a Dialog box asking <span |
---|
2092 | class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2093 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2094 | minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
2095 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2096 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2097 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
2098 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2099 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2100 | minor-latin'>Yes</span></b></span> button to proceed. <b style='mso-bidi-font-weight: |
---|
2101 | normal'>NB:</b> Dont be tempted to read both data sets at once. The problem |
---|
2102 | with the <span class=SpellE>xye</span> format is that it has no provision for |
---|
2103 | identifying the instrument parameter file or the frame (Bank) number of the |
---|
2104 | data. If you did read both, then GSAS-II would use the <span class=SpellE>instprm</span> |
---|
2105 | file read in the next step and apply it inappropriately to both data sets. One |
---|
2106 | can recover from this error by selecting Instrument parameters and doing |
---|
2107 | Operations/Load parameters with the correct file.</p> |
---|
2108 | |
---|
2109 | <p class=MsoListParagraphCxSpLast style='margin-left:.25in;mso-add-space:auto; |
---|
2110 | text-indent:-.25in;mso-list:l5 level1 lfo6'><![if !supportLists]><span |
---|
2111 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>3.<span |
---|
2112 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Since |
---|
2113 | this data file does not define an instrument parameter file, a file dialog will |
---|
2114 | appear for you to select the correct instrument parameter file. Select <b |
---|
2115 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2116 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2117 | minor-latin'>Bank 2.instprm</span></b>; you may have to change the file type in |
---|
2118 | the file selection Dialog box to <b style='mso-bidi-font-weight:normal'><span |
---|
2119 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2120 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>GSAS-II <span |
---|
2121 | class=SpellE>instprm</span> file</span></b> to see it. At this point the <b |
---|
2122 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2123 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2124 | minor-latin'>GSAS-II data tree</span></b> window will have several entries </p> |
---|
2125 | |
---|
2126 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2127 | id="Picture_x0020_7" o:spid="_x0000_i1072" type="#_x0000_t75" style='width:343.5pt; |
---|
2128 | height:217.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2129 | <v:imagedata src="Magnetic-V_files/image013.png" o:title=""/> |
---|
2130 | </v:shape><![endif]--><![if !vml]><img border=0 width=458 height=290 |
---|
2131 | src="Magnetic-V_files/image044.gif" v:shapes="Picture_x0020_7"><![endif]></span></p> |
---|
2132 | |
---|
2133 | <p class=MsoNormal style='margin-left:.25in'><span class=GramE>and</span> the |
---|
2134 | plot window will show the powder pattern</p> |
---|
2135 | |
---|
2136 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2137 | id="Picture_x0020_12" o:spid="_x0000_i1071" type="#_x0000_t75" style='width:344.25pt; |
---|
2138 | height:305.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2139 | <v:imagedata src="Magnetic-V_files/image015.png" o:title=""/> |
---|
2140 | </v:shape><![endif]--><![if !vml]><img border=0 width=459 height=407 |
---|
2141 | src="Magnetic-V_files/image045.gif" v:shapes="Picture_x0020_12"><![endif]></span></p> |
---|
2142 | |
---|
2143 | <p class=MsoNormal style='margin-left:.25in'><span class=GramE>which</span> |
---|
2144 | covers the d-spacing range 0.4-4.545 Å. This is the high resolution frame for |
---|
2145 | POWGEN and is collected by a selected setting of the beam choppers. Go to <b |
---|
2146 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2147 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2148 | minor-latin'>Limits</span></b></p> |
---|
2149 | |
---|
2150 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2151 | id="Picture_x0020_9" o:spid="_x0000_i1070" type="#_x0000_t75" style='width:340.5pt; |
---|
2152 | height:189pt;visibility:visible;mso-wrap-style:square'> |
---|
2153 | <v:imagedata src="Magnetic-V_files/image007.png" o:title=""/> |
---|
2154 | </v:shape><![endif]--><![if !vml]><img border=0 width=454 height=252 |
---|
2155 | src="Magnetic-V_files/image046.gif" v:shapes="Picture_x0020_9"><![endif]></span></p> |
---|
2156 | |
---|
2157 | <p class=MsoNormal style='margin-left:.25in'>We want to remove the partial peak |
---|
2158 | at high TOF and limit the low TOF to something reasonable. I used <b |
---|
2159 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2160 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2161 | minor-latin'>12500</span></b> and <b style='mso-bidi-font-weight:normal'><span |
---|
2162 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2163 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>100000</span></b>; |
---|
2164 | the lower one corresponds to d<sub>min</sub>~0.55 Å and the upper one is just |
---|
2165 | excludes the last visible peak. Now we have to read the other frame.</p> |
---|
2166 | |
---|
2167 | <p class=MsoListParagraphCxSpFirst style='margin-left:.25in;mso-add-space:auto; |
---|
2168 | text-indent:-.25in;mso-list:l5 level1 lfo6'><![if !supportLists]><span |
---|
2169 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>4.<span |
---|
2170 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Do |
---|
2171 | <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2172 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2173 | minor-latin'>Import/Powder Data/from TOPAS <span class=SpellE>xye</span> or |
---|
2174 | Fit2D chi file</span></b> and select the <b style='mso-bidi-font-weight:normal'><span |
---|
2175 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2176 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>PG3_20255-4_10K.xye |
---|
2177 | </span></b><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2178 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>data</span> |
---|
2179 | file in the first dialog and press <b style='mso-bidi-font-weight:normal'><span |
---|
2180 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2181 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Open</span></b>. |
---|
2182 | There will be a Dialog box asking <span class=GramE><b style='mso-bidi-font-weight: |
---|
2183 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2184 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
2185 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2186 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2187 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
2188 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2189 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2190 | minor-latin'>Yes</span></b></span> button to proceed.</p> |
---|
2191 | |
---|
2192 | <p class=MsoListParagraphCxSpLast style='margin-left:.25in;mso-add-space:auto; |
---|
2193 | text-indent:-.25in;mso-list:l5 level1 lfo6'><![if !supportLists]><span |
---|
2194 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>5.<span |
---|
2195 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Since |
---|
2196 | this data file does not define an instrument parameter file, a file dialog will |
---|
2197 | appear for you to select the correct instrument parameter file. Select <b |
---|
2198 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2199 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2200 | minor-latin'>Bank 4.instprm</span></b>; you may have to change the file type in |
---|
2201 | the file selection Dialog box to <b style='mso-bidi-font-weight:normal'><span |
---|
2202 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2203 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>GSAS-II <span |
---|
2204 | class=SpellE>instprm</span> file</span></b> to see it. At this point the <b |
---|
2205 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2206 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2207 | minor-latin'>GSAS-II data tree</span></b> window will have more entries </p> |
---|
2208 | |
---|
2209 | <p class=MsoNormal style='margin-left:.25in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2210 | id="Picture_x0020_13" o:spid="_x0000_i1069" type="#_x0000_t75" style='width:342pt; |
---|
2211 | height:5in;visibility:visible;mso-wrap-style:square'> |
---|
2212 | <v:imagedata src="Magnetic-V_files/image018.png" o:title=""/> |
---|
2213 | </v:shape><![endif]--><![if !vml]><img border=0 width=456 height=480 |
---|
2214 | src="Magnetic-V_files/image047.gif" v:shapes="Picture_x0020_13"><![endif]></span></p> |
---|
2215 | |
---|
2216 | <p class=MsoNormal style='margin-left:.25in'>And the plot will show this larger |
---|
2217 | d-spacing (1.15-9.0 Å) frame collected with a different set of chopper |
---|
2218 | settings. Notice that there is now a peak (d=4.94 Å) which was beyond the range |
---|
2219 | of the other frame. Go to Limits for this data set and set the upper limit to |
---|
2220 | 125000; leave the lower limit as it is.</p> |
---|
2221 | |
---|
2222 | <h3>Step 2. Read in the chemical structure for Mn<sub>3</sub>O<sub>4</sub> at |
---|
2223 | 60K</h3> |
---|
2224 | |
---|
2225 | <p class=MsoListParagraphCxSpFirst style='margin-left:.25in;mso-add-space:auto; |
---|
2226 | text-indent:-.25in;mso-list:l0 level1 lfo8'><![if !supportLists]><span |
---|
2227 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
2228 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Use |
---|
2229 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2230 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2231 | minor-latin'>Import/Phase/from GSAS-II <span class=SpellE>gpx</span> file</span></b> |
---|
2232 | menu item to read the phase information for Mn<sub>3</sub>O<sub>4</sub> into |
---|
2233 | the current GSAS-II project. The file you want is the one from the 1<sup>st</sup> |
---|
2234 | part of this tutorial and should be in your current directory. This read option |
---|
2235 | is set to read from other GSAS-II project files. Other submenu items can read |
---|
2236 | phase information in other formats.<span style='mso-spacerun:yes'> </span></p> |
---|
2237 | |
---|
2238 | <p class=MsoListParagraphCxSpLast style='margin-left:.25in;mso-add-space:auto; |
---|
2239 | text-indent:-.25in;mso-list:l0 level1 lfo8'><![if !supportLists]><span |
---|
2240 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>2.<span |
---|
2241 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Select |
---|
2242 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2243 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2244 | minor-latin'>Mn3O4 60K.gpx</span></b><span style='font-family:"Calibri",sans-serif; |
---|
2245 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2246 | minor-latin'> data</span> file in the first dialog and press <b |
---|
2247 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2248 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2249 | minor-latin'>Open</span></b>. There will be a Dialog box asking <span |
---|
2250 | class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2251 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2252 | minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
2253 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2254 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2255 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
2256 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2257 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2258 | minor-latin'>Yes</span></b></span> button to proceed. You will get the |
---|
2259 | opportunity to change the phase name next; press <b style='mso-bidi-font-weight: |
---|
2260 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2261 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> |
---|
2262 | to continue.</p> |
---|
2263 | |
---|
2264 | <p class=MsoNormal style='margin-left:.25in'>Next is the histogram selection |
---|
2265 | window; this connects the phase to the data so it can be used in subsequent calculations.<span |
---|
2266 | style='mso-no-proof:yes'> </span>Select the histograms (or press <b |
---|
2267 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2268 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2269 | minor-latin'>Set All</span></b>) and press <b style='mso-bidi-font-weight:normal'><span |
---|
2270 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2271 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
2272 | The General tab for the phase is shown next<br> |
---|
2273 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_11" |
---|
2274 | o:spid="_x0000_i1068" type="#_x0000_t75" style='width:342.75pt;height:183pt; |
---|
2275 | visibility:visible;mso-wrap-style:square'> |
---|
2276 | <v:imagedata src="Magnetic-V_files/image020.png" o:title=""/> |
---|
2277 | </v:shape><![endif]--><![if !vml]><img border=0 width=457 height=244 |
---|
2278 | src="Magnetic-V_files/image048.gif" v:shapes="Picture_x0020_11"><![endif]></span></p> |
---|
2279 | |
---|
2280 | <h3>Step 3. Check powder pattern indexing</h3> |
---|
2281 | |
---|
2282 | <p class=MsoNormal>Here the objective is to determine how the reflection |
---|
2283 | positions generated from the chemical (nuclear) crystal structure lattice |
---|
2284 | match up with the peaks observed for this magnetic phase. </p> |
---|
2285 | |
---|
2286 | <p class=MsoListParagraph style='margin-left:.25in;mso-add-space:auto; |
---|
2287 | text-indent:-.25in;mso-list:l1 level1 lfo10'><![if !supportLists]><span |
---|
2288 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
2289 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Select |
---|
2290 | <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2291 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2292 | minor-latin'>Unit Cells List</span></b> from the tree entries under the 2<sup>nd</sup> |
---|
2293 | histogram (<b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2294 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2295 | minor-latin;mso-bidi-theme-font:minor-latin'>PWDR PG3_20255-4_10k.xye</span></b> |
---|
2296 | & has the largest d-spacing peaks); the Indexing controls will be shown<br> |
---|
2297 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_15" |
---|
2298 | o:spid="_x0000_i1067" type="#_x0000_t75" style='width:340.5pt;height:116.25pt; |
---|
2299 | visibility:visible;mso-wrap-style:square'> |
---|
2300 | <v:imagedata src="Magnetic-V_files/image022.png" o:title=""/> |
---|
2301 | </v:shape><![endif]--><![if !vml]><img border=0 width=454 height=155 |
---|
2302 | src="Magnetic-V_files/image049.gif" v:shapes="Picture_x0020_15"><![endif]></span><span |
---|
2303 | style='mso-spacerun:yes'> </span><br> |
---|
2304 | This can be use lattice parameters & space groups to generate expected |
---|
2305 | reflection positions to check against the peaks in the powder pattern. </p> |
---|
2306 | |
---|
2307 | <p class=MsoNormal style='margin-left:.25in'>One could then enter <span |
---|
2308 | class=SpellE>Bravais</span> lattice, choose space group & enter lattice |
---|
2309 | parameters by hand, but the easy way is to use the chemical lattice directly. |
---|
2310 | Do <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2311 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2312 | minor-latin'>Cell Index/Refine/Load Cell</span></b> from the menu; a Phase |
---|
2313 | selection box will appear with only one choice (<b style='mso-bidi-font-weight: |
---|
2314 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2315 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4</span></b>). |
---|
2316 | This was taken from the Phases present in this project; there could be more |
---|
2317 | than one depending on what you loaded/created earlier. The <b style='mso-bidi-font-weight: |
---|
2318 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2319 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Import</span></b> |
---|
2320 | menu item allows you to get lattice information from any one of the other phase |
---|
2321 | containing files known to GSAS-II.<br> |
---|
2322 | Press <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2323 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2324 | minor-latin'>OK</span></b> and the Indexing controls will be change<br> |
---|
2325 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="_x0000_i1066" |
---|
2326 | type="#_x0000_t75" style='width:339.75pt;height:115.5pt;visibility:visible; |
---|
2327 | mso-wrap-style:square'> |
---|
2328 | <v:imagedata src="Magnetic-V_files/image024.png" o:title=""/> |
---|
2329 | </v:shape><![endif]--><![if !vml]><img border=0 width=453 height=154 |
---|
2330 | src="Magnetic-V_files/image050.gif" v:shapes="_x0000_i1066"><![endif]></span><br> |
---|
2331 | showing the lattice constants for Mn<sub>3</sub>O<sub>4</sub> you had obtained |
---|
2332 | from the <span class=SpellE>gpx</span> file and the powder pattern will change |
---|
2333 | showing the lines for I 41/<span class=SpellE>amd</span> and the Mn<sub>3</sub>O<sub>4</sub> |
---|
2334 | lattice parameters. Change the space group to <b style='mso-bidi-font-weight: |
---|
2335 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2336 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>I |
---|
2337 | 4/m <span class=SpellE>m</span> <span class=SpellE>m</span></span></b>; the |
---|
2338 | plot will change showing the new lines.<br> |
---|
2339 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_17" |
---|
2340 | o:spid="_x0000_i1065" type="#_x0000_t75" style='width:341.25pt;height:303pt; |
---|
2341 | visibility:visible;mso-wrap-style:square'> |
---|
2342 | <v:imagedata src="Magnetic-V_files/image026.png" o:title=""/> |
---|
2343 | </v:shape><![endif]--><![if !vml]><img border=0 width=455 height=404 |
---|
2344 | src="Magnetic-V_files/image051.gif" v:shapes="Picture_x0020_17"><![endif]></span><br> |
---|
2345 | Notice that some lines are not indexed; perhaps we need to double one of the |
---|
2346 | axes to generate reflections for these. Add <b style='mso-bidi-font-weight: |
---|
2347 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2348 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>*2</span></b> |
---|
2349 | at the end of the a-axis; this will index some lines but remove it from others. |
---|
2350 | Try doing the same for the c-axis; doesnt appear to help either. Bring both |
---|
2351 | back to the original values (add <b style='mso-bidi-font-weight:normal'><span |
---|
2352 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2353 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>/2</span></b> |
---|
2354 | as needed to each, or else just do <b style='mso-bidi-font-weight:normal'><span |
---|
2355 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2356 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Load unit |
---|
2357 | cell</span></b> again). Recall that the chemical unit cell is I-centered; maybe |
---|
2358 | the centering is lost in forming the magnetic space group. Set the <span |
---|
2359 | class=SpellE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2360 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2361 | minor-latin;mso-bidi-theme-font:minor-latin'>Bravais</span></b></span><b |
---|
2362 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2363 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2364 | minor-latin'> lattice</span></b> to <b style='mso-bidi-font-weight:normal'><span |
---|
2365 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2366 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>P4/mmm</span></b> |
---|
2367 | and the space group to match. Then try doubling the a-axis; that indexes every |
---|
2368 | line. So we need two parts to the propagation vector; one to double a (or b) |
---|
2369 | and one to remove the centering. This makes sense considering the report that |
---|
2370 | there are two low temperature phase transitions for this material. They would |
---|
2371 | be (1/2<span class=GramE>,0,0</span>) or (0,1/2,0) and (0,0,1). Im going to |
---|
2372 | pick (0<span class=GramE>,1</span>/2,0) for the 1<sup>st</sup> one as that will |
---|
2373 | match what was originally used.</p> |
---|
2374 | |
---|
2375 | <h2>Step 4. Run k-SUBGROUPSMAG</h2> |
---|
2376 | |
---|
2377 | <p class=MsoNormal>In this next step, you will be accessing the Bilbao |
---|
2378 | crystallographic server so you must be connected to the internet. In the Cell |
---|
2379 | Index/Refine menu select <b style='mso-bidi-font-weight:normal'><span |
---|
2380 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2381 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Run |
---|
2382 | k-SUBGROUPSMAG</span></b>; a small popup dialog will appear</p> |
---|
2383 | |
---|
2384 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2385 | id="Picture_x0020_14" o:spid="_x0000_i1064" type="#_x0000_t75" style='width:166.5pt; |
---|
2386 | height:278.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2387 | <v:imagedata src="Magnetic-V_files/image028.png" o:title=""/> |
---|
2388 | </v:shape><![endif]--><![if !vml]><img border=0 width=222 height=371 |
---|
2389 | src="Magnetic-V_files/image052.gif" v:shapes="Picture_x0020_14"><![endif]></span></p> |
---|
2390 | |
---|
2391 | <p class=MsoNormal>To set the propagation vectors, set <b style='mso-bidi-font-weight: |
---|
2392 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2393 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>ky1=1/2</span></b> |
---|
2394 | and <span class=GramE><b style='mso-bidi-font-weight:normal'><span |
---|
2395 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2396 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>kx2 ,</span></b></span><b |
---|
2397 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2398 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2399 | minor-latin'> ky2 & kz2</span></b> to <b style='mso-bidi-font-weight:normal'><span |
---|
2400 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2401 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>0, 0, 1</span></b> |
---|
2402 | (NB: dont leave any blank not the same as zero; k-SUBGROUPSMAG will fail if |
---|
2403 | you do). Select <span class=SpellE><b style='mso-bidi-font-weight:normal'><span |
---|
2404 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2405 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn</span></b></span> |
---|
2406 | for the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2407 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2408 | minor-latin'>mag atoms test</span></b> and check the last box so we see |
---|
2409 | solutions with all magnetic <span class=SpellE>Mn</span> atoms marked as |
---|
2410 | Keep. Press <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2411 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2412 | minor-latin;mso-bidi-theme-font:minor-latin'>Ok</span></b>; a popup dialog will |
---|
2413 | appear reminding you how to cite the Bilbao routine in any paper you write |
---|
2414 | using this facility.</p> |
---|
2415 | |
---|
2416 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2417 | id="Picture_x0020_16" o:spid="_x0000_i1063" type="#_x0000_t75" style='width:357.75pt; |
---|
2418 | height:123.75pt;visibility:visible;mso-wrap-style:square'> |
---|
2419 | <v:imagedata src="Magnetic-V_files/image030.png" o:title=""/> |
---|
2420 | </v:shape><![endif]--><![if !vml]><img border=0 width=477 height=165 |
---|
2421 | src="Magnetic-V_files/image053.gif" v:shapes="Picture_x0020_16"><![endif]></span></p> |
---|
2422 | |
---|
2423 | <p class=MsoNormal>Press <b style='mso-bidi-font-weight:normal'><span |
---|
2424 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2425 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ok</span></b>, |
---|
2426 | the nag note will also appear on the console and after a pause, the console |
---|
2427 | will show request OK indicating that the Bilbao site has responded with some |
---|
2428 | results. GSAS-II will next display a File Dialog asking for a project name to |
---|
2429 | save this project; change the directory to a useful place for your work on this |
---|
2430 | tutorial and give the project a name; I used <b style='mso-bidi-font-weight: |
---|
2431 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2432 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 |
---|
2433 | 10K.<o:p></o:p></span></b></p> |
---|
2434 | |
---|
2435 | <p class=MsoNormal>The GSAS-II data window will display the 184(!) results from |
---|
2436 | k-SUBGROUPSMAG. (If k-SUBGROUPSMAG failed because you lack internet access, |
---|
2437 | this file is located in the same location as the powder data and <span |
---|
2438 | class=SpellE>cif</span> files used above were found. Do <b style='mso-bidi-font-weight: |
---|
2439 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2440 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>File/Open |
---|
2441 | Project</span></b> from the main menu to access it as <b style='mso-bidi-font-weight: |
---|
2442 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2443 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 |
---|
2444 | 10K.gpx</span></b>, then do <b style='mso-bidi-font-weight:normal'><span |
---|
2445 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2446 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Save as</span></b> |
---|
2447 | to save it immediately in your working directory.). The Unit Cells List window |
---|
2448 | will show the results<br> |
---|
2449 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_20" |
---|
2450 | o:spid="_x0000_i1062" type="#_x0000_t75" style='width:359.25pt;height:241.5pt; |
---|
2451 | visibility:visible;mso-wrap-style:square'> |
---|
2452 | <v:imagedata src="Magnetic-V_files/image054.png" o:title=""/> |
---|
2453 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=322 |
---|
2454 | src="Magnetic-V_files/image055.gif" v:shapes="Picture_x0020_20"><![endif]></span></p> |
---|
2455 | |
---|
2456 | <p class=MsoNormal>There are a lot of possible solutions; the lowest number of |
---|
2457 | unique positions is 4. Lets change the filters to <span class=GramE>Keep</span> |
---|
2458 | only those. Double click the Keep column heading; a popup will appear</p> |
---|
2459 | |
---|
2460 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2461 | id="Picture_x0020_21" o:spid="_x0000_i1061" type="#_x0000_t75" style='width:168pt; |
---|
2462 | height:110.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2463 | <v:imagedata src="Magnetic-V_files/image056.png" o:title=""/> |
---|
2464 | </v:shape><![endif]--><![if !vml]><img border=0 width=224 height=147 |
---|
2465 | src="Magnetic-V_files/image057.gif" v:shapes="Picture_x0020_21"><![endif]></span></p> |
---|
2466 | |
---|
2467 | <p class=MsoNormal>Set <b style='mso-bidi-font-weight:normal'><span |
---|
2468 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2469 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>max unique</span></b> |
---|
2470 | to <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2471 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2472 | minor-latin'>4</span></b>, the <b style='mso-bidi-font-weight:normal'><span |
---|
2473 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2474 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>test for mag |
---|
2475 | atoms</span></b> to <span class=SpellE><b style='mso-bidi-font-weight:normal'><span |
---|
2476 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2477 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn</span></b></span>, |
---|
2478 | and press <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2479 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2480 | minor-latin'>OK</span></b>. That cleared away a lot of solutions</p> |
---|
2481 | |
---|
2482 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2483 | id="Picture_x0020_22" o:spid="_x0000_i1060" type="#_x0000_t75" style='width:357.75pt; |
---|
2484 | height:240pt;visibility:visible;mso-wrap-style:square'> |
---|
2485 | <v:imagedata src="Magnetic-V_files/image058.png" o:title=""/> |
---|
2486 | </v:shape><![endif]--><![if !vml]><img border=0 width=477 height=320 |
---|
2487 | src="Magnetic-V_files/image059.gif" v:shapes="Picture_x0020_22"><![endif]></span></p> |
---|
2488 | |
---|
2489 | <p class=MsoNormal>In fact there are only 4 left from the initial 184 possible |
---|
2490 | space groups; well have to look at each in turn. If you do <span class=GramE><b |
---|
2491 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2492 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2493 | minor-latin'>Try</span></b></span> on each, unfortunately there are no |
---|
2494 | reflections within our TOF frames that systematically change so we can |
---|
2495 | discriminate between them. If you then click on the number in the <span |
---|
2496 | class=SpellE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2497 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2498 | minor-latin;mso-bidi-theme-font:minor-latin'>Uniq</span></b></span> column (<b |
---|
2499 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2500 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2501 | minor-latin'>4</span></b> in each case), GSAS-II will show the unique magnetic |
---|
2502 | atom positions and their magnetic moment components. For #2 (<span |
---|
2503 | class=SpellE>Pbna</span>) we see</p> |
---|
2504 | |
---|
2505 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2506 | id="Picture_x0020_23" o:spid="_x0000_i1059" type="#_x0000_t75" style='width:265.5pt; |
---|
2507 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2508 | <v:imagedata src="Magnetic-V_files/image060.png" o:title=""/> |
---|
2509 | </v:shape><![endif]--><![if !vml]><img border=0 width=354 height=186 |
---|
2510 | src="Magnetic-V_files/image061.gif" v:shapes="Picture_x0020_23"><![endif]></span></p> |
---|
2511 | |
---|
2512 | <p class=MsoNormal>Press <b style='mso-bidi-font-weight:normal'><span |
---|
2513 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2514 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> |
---|
2515 | & try the next one (#3 <span class=SpellE>Pbna</span>)</p> |
---|
2516 | |
---|
2517 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2518 | id="Picture_x0020_24" o:spid="_x0000_i1058" type="#_x0000_t75" style='width:269.25pt; |
---|
2519 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2520 | <v:imagedata src="Magnetic-V_files/image062.png" o:title=""/> |
---|
2521 | </v:shape><![endif]--><![if !vml]><img border=0 width=359 height=186 |
---|
2522 | src="Magnetic-V_files/image063.gif" v:shapes="Picture_x0020_24"><![endif]></span></p> |
---|
2523 | |
---|
2524 | <p class=MsoNormal>Again press <b style='mso-bidi-font-weight:normal'><span |
---|
2525 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2526 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> |
---|
2527 | & try the next (#4 <span class=SpellE>Pbna</span>)</p> |
---|
2528 | |
---|
2529 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2530 | id="Picture_x0020_25" o:spid="_x0000_i1057" type="#_x0000_t75" style='width:269.25pt; |
---|
2531 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2532 | <v:imagedata src="Magnetic-V_files/image062.png" o:title=""/> |
---|
2533 | </v:shape><![endif]--><![if !vml]><img border=0 width=359 height=186 |
---|
2534 | src="Magnetic-V_files/image063.gif" v:shapes="Picture_x0020_25"><![endif]></span></p> |
---|
2535 | |
---|
2536 | <p class=MsoNormal>Press <b style='mso-bidi-font-weight:normal'><span |
---|
2537 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2538 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> |
---|
2539 | and finally the last one (#8 <span class=SpellE>Pbna</span>)</p> |
---|
2540 | |
---|
2541 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2542 | id="Picture_x0020_26" o:spid="_x0000_i1056" type="#_x0000_t75" style='width:265.5pt; |
---|
2543 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2544 | <v:imagedata src="Magnetic-V_files/image064.png" o:title=""/> |
---|
2545 | </v:shape><![endif]--><![if !vml]><img border=0 width=354 height=186 |
---|
2546 | src="Magnetic-V_files/image065.gif" v:shapes="Picture_x0020_26"><![endif]></span>.</p> |
---|
2547 | |
---|
2548 | <p class=MsoNormal>These seem to be in pairs two (#2 & #8) with no <span |
---|
2549 | class=SpellE>My</span>, <span class=SpellE>Mz</span> component on one atom and the |
---|
2550 | other two (#3 & #4) with no <span class=SpellE>Mx</span> component on one |
---|
2551 | atom; the other atoms are in general positions and have all three components |
---|
2552 | allowed. One other point for consideration is that the <span class=SpellE>Mn</span> |
---|
2553 | oxidation states are in the + 2 to +4 range so the high spin magnetic moments could |
---|
2554 | be large (4-5<span style='font-family:Symbol'>m</span><sub>B</sub>). We will |
---|
2555 | still have to try each in turn. Before we start we should go to the <b |
---|
2556 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2557 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2558 | minor-latin'>Mn3O4</span></b> phase, clear the <b style='mso-bidi-font-weight: |
---|
2559 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2560 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Unit |
---|
2561 | cell refine</span></b> flag and then select <b style='mso-bidi-font-weight: |
---|
2562 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2563 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Atoms</span></b> |
---|
2564 | and clear the refine flags there; this will avoid problems for our first |
---|
2565 | refinements. <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2566 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2567 | minor-latin;mso-bidi-theme-font:minor-latin'>Save</span></b> the project.</p> |
---|
2568 | |
---|
2569 | <h2>Step 5. Trial magnetic structures for Mn<sub>3</sub>O<sub>4<o:p></o:p></sub></h2> |
---|
2570 | |
---|
2571 | <h3><span class=SpellE>Intoduction</span></h3> |
---|
2572 | |
---|
2573 | <p class=MsoNormal>In this section we will be doing the same thing using each |
---|
2574 | of the 4 possible magnetic solutions with the minimum number (4) of magnetic |
---|
2575 | atoms. For each one we have opened the initial one phase project containing the |
---|
2576 | k-SUBGROUPSMAG table of possible magnetic space groups. We then select one, |
---|
2577 | assign values to the magnetic components and then do sufficient refinements to |
---|
2578 | be able to compare them.</p> |
---|
2579 | |
---|
2580 | <h3 style='margin-left:.5in;text-indent:-.25in;mso-list:l8 level1 lfo12'><![if !supportLists]><span |
---|
2581 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
2582 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Try |
---|
2583 | <span class=SpellE>Pbna</span> (#2)</h3> |
---|
2584 | |
---|
2585 | <p class=MsoNormal>To begin, be sure <b style='mso-bidi-font-weight:normal'><span |
---|
2586 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2587 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 10K.gpx</span></b> |
---|
2588 | is opened in your GSAS-II. Select the <b style='mso-bidi-font-weight:normal'><span |
---|
2589 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2590 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4</span></b> |
---|
2591 | phase and do <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2592 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2593 | minor-latin;mso-bidi-theme-font:minor-latin'>Compute/Select magnetic phase</span></b>; |
---|
2594 | a popup selection will appear</p> |
---|
2595 | |
---|
2596 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2597 | id="Picture_x0020_40" o:spid="_x0000_i1055" type="#_x0000_t75" style='width:187.5pt; |
---|
2598 | height:155.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2599 | <v:imagedata src="Magnetic-V_files/image066.png" o:title=""/> |
---|
2600 | </v:shape><![endif]--><![if !vml]><img border=0 width=250 height=207 |
---|
2601 | src="Magnetic-V_files/image067.gif" v:shapes="Picture_x0020_40"><![endif]></span></p> |
---|
2602 | |
---|
2603 | <p class=MsoNormal>Select the <b style='mso-bidi-font-weight:normal'><span |
---|
2604 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2605 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1<sup>st</sup></span></b> |
---|
2606 | one and press <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2607 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2608 | minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>; a new popup will |
---|
2609 | appear</p> |
---|
2610 | |
---|
2611 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2612 | id="Picture_x0020_27" o:spid="_x0000_i1054" type="#_x0000_t75" style='width:265.5pt; |
---|
2613 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2614 | <v:imagedata src="Magnetic-V_files/image068.png" o:title=""/> |
---|
2615 | </v:shape><![endif]--><![if !vml]><img border=0 width=354 height=186 |
---|
2616 | src="Magnetic-V_files/image069.gif" v:shapes="Picture_x0020_27"><![endif]></span></p> |
---|
2617 | |
---|
2618 | <p class=MsoNormal>Press <span class=GramE><b style='mso-bidi-font-weight:normal'><span |
---|
2619 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2620 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Yes</span></b></span>; |
---|
2621 | a new project will be created <b style='mso-bidi-font-weight:normal'><span |
---|
2622 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2623 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 |
---|
2624 | mag_2.gpx</span></b> and you will be at the General tab for the new magnetic |
---|
2625 | phase</p> |
---|
2626 | |
---|
2627 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2628 | id="Picture_x0020_28" o:spid="_x0000_i1053" type="#_x0000_t75" style='width:359.25pt; |
---|
2629 | height:201pt;visibility:visible;mso-wrap-style:square'> |
---|
2630 | <v:imagedata src="Magnetic-V_files/image070.png" o:title=""/> |
---|
2631 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=268 |
---|
2632 | src="Magnetic-V_files/image071.gif" v:shapes="Picture_x0020_28"><![endif]></span></p> |
---|
2633 | |
---|
2634 | <p class=MsoNormal>Select <b style='mso-bidi-font-weight:normal'><span |
---|
2635 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2636 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Atoms</span></b> |
---|
2637 | and enter <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2638 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2639 | minor-latin'>2.0</span></b> for every <span class=SpellE><b style='mso-bidi-font-weight: |
---|
2640 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2641 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mx</span></b></span><b |
---|
2642 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2643 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2644 | minor-latin'> My <span class=SpellE>Mz</span></span></b> allowed for all 4 |
---|
2645 | atoms; it should look like</p> |
---|
2646 | |
---|
2647 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2648 | id="Picture_x0020_29" o:spid="_x0000_i1052" type="#_x0000_t75" style='width:5in; |
---|
2649 | height:111pt;visibility:visible;mso-wrap-style:square'> |
---|
2650 | <v:imagedata src="Magnetic-V_files/image072.png" o:title=""/> |
---|
2651 | </v:shape><![endif]--><![if !vml]><img border=0 width=480 height=148 |
---|
2652 | src="Magnetic-V_files/image073.gif" v:shapes="Picture_x0020_29"><![endif]></span></p> |
---|
2653 | |
---|
2654 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
2655 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2656 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
2657 | for Scale & Background for 2 data sets (<span class=SpellE>wR</span> = |
---|
2658 | 27.6%). Set refine for all <span class=SpellE>Mn</span> atoms to <b |
---|
2659 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2660 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2661 | minor-latin'>M</span></b> and do <b style='mso-bidi-font-weight:normal'><span |
---|
2662 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2663 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
2664 | 2-3 times to convergence (<span class=SpellE>wR</span>=20.6%).</p> |
---|
2665 | |
---|
2666 | <p class=MsoNormal>Next select the <b style='mso-bidi-font-weight:normal'><span |
---|
2667 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2668 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>General</span></b> |
---|
2669 | tab for each phase and check the <b style='mso-bidi-font-weight:normal'><span |
---|
2670 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2671 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Refine unit |
---|
2672 | cell</span></b> box for each. Then select <b style='mso-bidi-font-weight:normal'><span |
---|
2673 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2674 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Constraints</span></b> |
---|
2675 | (there will be a popup about a conflict; press <b style='mso-bidi-font-weight: |
---|
2676 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2677 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>)</p> |
---|
2678 | |
---|
2679 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2680 | id="Picture_x0020_30" o:spid="_x0000_i1051" type="#_x0000_t75" style='width:360.75pt; |
---|
2681 | height:351.75pt;visibility:visible;mso-wrap-style:square'> |
---|
2682 | <v:imagedata src="Magnetic-V_files/image074.png" o:title=""/> |
---|
2683 | </v:shape><![endif]--><![if !vml]><img border=0 width=481 height=469 |
---|
2684 | src="Magnetic-V_files/image075.gif" v:shapes="Picture_x0020_30"><![endif]></span></p> |
---|
2685 | |
---|
2686 | <p class=MsoNormal>The problem here is similar to what we saw in the Magnetic |
---|
2687 | Structures-III tutorial. Here we want this constraint to be on the orthorhombic |
---|
2688 | lattice parameters; e.g. that b = 2*a (or A0= 4*A1). <b style='mso-bidi-font-weight: |
---|
2689 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2690 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Delete</span></b> |
---|
2691 | the one marked in yellow. Then do <span class=GramE><b style='mso-bidi-font-weight: |
---|
2692 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2693 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Edit</span></b></span><b |
---|
2694 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2695 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2696 | minor-latin'> <span class=SpellE>constr</span>/Add equivalence</span></b>; a |
---|
2697 | popup will appear</p> |
---|
2698 | |
---|
2699 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2700 | id="Picture_x0020_31" o:spid="_x0000_i1050" type="#_x0000_t75" style='width:358.5pt; |
---|
2701 | height:229.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2702 | <v:imagedata src="Magnetic-V_files/image076.png" o:title=""/> |
---|
2703 | </v:shape><![endif]--><![if !vml]><img border=0 width=478 height=306 |
---|
2704 | src="Magnetic-V_files/image077.gif" v:shapes="Picture_x0020_31"><![endif]></span></p> |
---|
2705 | |
---|
2706 | <p class=MsoNormal>Select the <b style='mso-bidi-font-weight:normal'><span |
---|
2707 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2708 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1::A0</span></b> |
---|
2709 | line and press <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2710 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2711 | minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> a new popup will |
---|
2712 | appear. Select <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2713 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2714 | minor-latin;mso-bidi-theme-font:minor-latin'>1::A1</span></b><br> |
---|
2715 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_33" |
---|
2716 | o:spid="_x0000_i1049" type="#_x0000_t75" style='width:356.25pt;height:208.5pt; |
---|
2717 | visibility:visible;mso-wrap-style:square'> |
---|
2718 | <v:imagedata src="Magnetic-V_files/image078.png" o:title=""/> |
---|
2719 | </v:shape><![endif]--><![if !vml]><img border=0 width=475 height=278 |
---|
2720 | src="Magnetic-V_files/image079.gif" v:shapes="Picture_x0020_33"><![endif]></span></p> |
---|
2721 | |
---|
2722 | <p class=MsoNormal><span class=GramE>and</span> press <b style='mso-bidi-font-weight: |
---|
2723 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2724 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
2725 | A new line will be added to the list of constraints; press <b style='mso-bidi-font-weight: |
---|
2726 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2727 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Edit</span></b> |
---|
2728 | for it and a popup will appear</p> |
---|
2729 | |
---|
2730 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2731 | id="Picture_x0020_34" o:spid="_x0000_i1048" type="#_x0000_t75" style='width:358.5pt; |
---|
2732 | height:116.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2733 | <v:imagedata src="Magnetic-V_files/image080.png" o:title=""/> |
---|
2734 | </v:shape><![endif]--><![if !vml]><img border=0 width=478 height=155 |
---|
2735 | src="Magnetic-V_files/image081.gif" v:shapes="Picture_x0020_34"><![endif]></span></p> |
---|
2736 | |
---|
2737 | <p class=MsoNormal>Since A0 is the reciprocal metric tensor element = a*2 and |
---|
2738 | A1 is that = b*2, we want A0 = A1/4. So enter <b style='mso-bidi-font-weight: |
---|
2739 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2740 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>4</span></b> |
---|
2741 | in the box for <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2742 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2743 | minor-latin;mso-bidi-theme-font:minor-latin'>1::A1</span></b> to give</p> |
---|
2744 | |
---|
2745 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2746 | id="Picture_x0020_55" o:spid="_x0000_i1047" type="#_x0000_t75" style='width:357pt; |
---|
2747 | height:115.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2748 | <v:imagedata src="Magnetic-V_files/image082.png" o:title=""/> |
---|
2749 | </v:shape><![endif]--><![if !vml]><img border=0 width=476 height=154 |
---|
2750 | src="Magnetic-V_files/image083.gif" v:shapes="Picture_x0020_55"><![endif]></span></p> |
---|
2751 | |
---|
2752 | <p class=MsoNormal>Press <b style='mso-bidi-font-weight:normal'><span |
---|
2753 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2754 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>; |
---|
2755 | the constraints should read</p> |
---|
2756 | |
---|
2757 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2758 | id="Picture_x0020_56" o:spid="_x0000_i1046" type="#_x0000_t75" style='width:358.5pt; |
---|
2759 | height:242.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2760 | <v:imagedata src="Magnetic-V_files/image084.png" o:title=""/> |
---|
2761 | </v:shape><![endif]--><![if !vml]><img border=0 width=478 height=323 |
---|
2762 | src="Magnetic-V_files/image085.gif" v:shapes="Picture_x0020_56"><![endif]></span></p> |
---|
2763 | |
---|
2764 | <p class=MsoNormal>Now do <b style='mso-bidi-font-weight:normal'><span |
---|
2765 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2766 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
2767 | until convergence (my <span class=SpellE>wR</span>=16.4% after several |
---|
2768 | refinements).</p> |
---|
2769 | |
---|
2770 | <p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span |
---|
2771 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2772 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Save</span></b> |
---|
2773 | the project; we may look at it later for more refinement.</p> |
---|
2774 | |
---|
2775 | <p class=MsoListParagraph style='mso-margin-top-alt:auto;mso-margin-bottom-alt: |
---|
2776 | auto;text-indent:-.25in;mso-outline-level:3;mso-list:l9 level1 lfo13; |
---|
2777 | display:none'><![if !supportLists]><b><span style='font-size:13.5pt;mso-fareast-font-family: |
---|
2778 | "Times New Roman";display:none;mso-hide:all'><span style='mso-list:Ignore'>1.<span |
---|
2779 | style='font:7.0pt "Times New Roman"'> </span></span></span></b><![endif]><b><span |
---|
2780 | style='font-size:13.5pt;display:none;mso-hide:all'><o:p> </o:p></span></b></p> |
---|
2781 | |
---|
2782 | <h3 style='margin-left:.5in;text-indent:-.25in;mso-list:l9 level1 lfo13'><![if !supportLists]><span |
---|
2783 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>2.<span |
---|
2784 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Try |
---|
2785 | <span class=SpellE>Pbna</span> (#3)</h3> |
---|
2786 | |
---|
2787 | <p class=MsoNormal>To begin, be sure <b style='mso-bidi-font-weight:normal'><span |
---|
2788 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2789 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 10K.gpx</span></b> |
---|
2790 | is opened in your GSAS-II; we are going to repeat the above steps. Select the <b |
---|
2791 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2792 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2793 | minor-latin'>Mn3O4</span></b> phase and do <b style='mso-bidi-font-weight:normal'><span |
---|
2794 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2795 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Compute/Select |
---|
2796 | magnetic phase</span></b>; a popup selection will appear</p> |
---|
2797 | |
---|
2798 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2799 | id="Picture_x0020_41" o:spid="_x0000_i1045" type="#_x0000_t75" style='width:187.5pt; |
---|
2800 | height:155.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2801 | <v:imagedata src="Magnetic-V_files/image066.png" o:title=""/> |
---|
2802 | </v:shape><![endif]--><![if !vml]><img border=0 width=250 height=207 |
---|
2803 | src="Magnetic-V_files/image086.gif" v:shapes="Picture_x0020_41"><![endif]></span><o:p></o:p></p> |
---|
2804 | |
---|
2805 | <p class=MsoNormal>Weve done the 1<sup>st</sup> one; now pick the <b |
---|
2806 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2807 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2808 | minor-latin'>2<sup>nd</sup></span></b> and press <b style='mso-bidi-font-weight: |
---|
2809 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2810 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
2811 | A new popup will appear<o:p></o:p></p> |
---|
2812 | |
---|
2813 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2814 | id="Picture_x0020_42" o:spid="_x0000_i1044" type="#_x0000_t75" style='width:269.25pt; |
---|
2815 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2816 | <v:imagedata src="Magnetic-V_files/image087.png" o:title=""/> |
---|
2817 | </v:shape><![endif]--><![if !vml]><img border=0 width=359 height=186 |
---|
2818 | src="Magnetic-V_files/image088.gif" v:shapes="Picture_x0020_42"><![endif]></span><o:p></o:p></p> |
---|
2819 | |
---|
2820 | <p class=MsoNormal>Press <span class=GramE><b style='mso-bidi-font-weight:normal'><span |
---|
2821 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2822 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Yes</span></b></span>; |
---|
2823 | a new project will be created <b style='mso-bidi-font-weight:normal'><span |
---|
2824 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2825 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 mag_3.gpx</span></b> |
---|
2826 | and you will be at the General tab for the new magnetic phase<o:p></o:p></p> |
---|
2827 | |
---|
2828 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2829 | id="Picture_x0020_43" o:spid="_x0000_i1043" type="#_x0000_t75" style='width:366.75pt; |
---|
2830 | height:207pt;visibility:visible;mso-wrap-style:square'> |
---|
2831 | <v:imagedata src="Magnetic-V_files/image089.png" o:title=""/> |
---|
2832 | </v:shape><![endif]--><![if !vml]><img border=0 width=489 height=276 |
---|
2833 | src="Magnetic-V_files/image090.gif" v:shapes="Picture_x0020_43"><![endif]></span><o:p></o:p></p> |
---|
2834 | |
---|
2835 | <p class=MsoNormal>Select <b style='mso-bidi-font-weight:normal'><span |
---|
2836 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2837 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Atoms</span></b> |
---|
2838 | and enter <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2839 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2840 | minor-latin'>2</span></b> for every <span class=SpellE><b style='mso-bidi-font-weight: |
---|
2841 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2842 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mx</span></b></span><b |
---|
2843 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2844 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2845 | minor-latin'> My <span class=SpellE>Mz</span></span></b> allowed for all 4 |
---|
2846 | atoms; it should look like<o:p></o:p></p> |
---|
2847 | |
---|
2848 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2849 | id="Picture_x0020_44" o:spid="_x0000_i1042" type="#_x0000_t75" style='width:365.25pt; |
---|
2850 | height:91.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2851 | <v:imagedata src="Magnetic-V_files/image091.png" o:title=""/> |
---|
2852 | </v:shape><![endif]--><![if !vml]><img border=0 width=487 height=122 |
---|
2853 | src="Magnetic-V_files/image092.gif" v:shapes="Picture_x0020_44"><![endif]></span><o:p></o:p></p> |
---|
2854 | |
---|
2855 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
2856 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2857 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
2858 | for Scale & Background for 2 data sets (<span class=SpellE>wR</span> = 25.1%). |
---|
2859 | Set refine for all <span class=SpellE>Mn</span> atoms to <b style='mso-bidi-font-weight: |
---|
2860 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2861 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>M</span></b> |
---|
2862 | and do <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2863 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2864 | minor-latin'>Calculate/Refine</span></b> 2-3 times to convergence (<span |
---|
2865 | class=SpellE>wR</span>=20.9%).<o:p></o:p></p> |
---|
2866 | |
---|
2867 | <p class=MsoNormal>Next select the <b style='mso-bidi-font-weight:normal'><span |
---|
2868 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2869 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>General</span></b> |
---|
2870 | tab for each phase and check the <b style='mso-bidi-font-weight:normal'><span |
---|
2871 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2872 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Refine unit |
---|
2873 | cell</span></b> box for each. Then select <b style='mso-bidi-font-weight:normal'><span |
---|
2874 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2875 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Constraints</span></b> |
---|
2876 | (there will be a popup about a conflict; press <b style='mso-bidi-font-weight: |
---|
2877 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2878 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>).</p> |
---|
2879 | |
---|
2880 | <p class=MsoNormal>Fix the constraints as above: 1) delete the one in error, 2) |
---|
2881 | add an equivalence for <b style='mso-bidi-font-weight:normal'><span |
---|
2882 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2883 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1::A0</span></b> |
---|
2884 | = <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2885 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2886 | minor-latin'>1::A1</span></b> and 3) edit the constraint so <b |
---|
2887 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2888 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2889 | minor-latin'>1::A1 = 0.250*1::A0</span></b> to give</p> |
---|
2890 | |
---|
2891 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2892 | id="Picture_x0020_57" o:spid="_x0000_i1041" type="#_x0000_t75" style='width:5in; |
---|
2893 | height:243pt;visibility:visible;mso-wrap-style:square'> |
---|
2894 | <v:imagedata src="Magnetic-V_files/image093.png" o:title=""/> |
---|
2895 | </v:shape><![endif]--><![if !vml]><img border=0 width=480 height=324 |
---|
2896 | src="Magnetic-V_files/image094.gif" v:shapes="Picture_x0020_57"><![endif]></span><o:p></o:p></p> |
---|
2897 | |
---|
2898 | <p class=MsoNormal>Now do <b style='mso-bidi-font-weight:normal'><span |
---|
2899 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2900 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
2901 | until convergence (my <span class=SpellE>wR</span>=16.9% after several |
---|
2902 | refinements).<o:p></o:p></p> |
---|
2903 | |
---|
2904 | <p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span |
---|
2905 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2906 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Save</span></b> |
---|
2907 | the project; we may look at it later for more refinement.<o:p></o:p></p> |
---|
2908 | |
---|
2909 | <h3 style='margin-left:.5in;text-indent:-.25in;mso-list:l9 level1 lfo13'><![if !supportLists]><span |
---|
2910 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>3.<span |
---|
2911 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Try |
---|
2912 | <span class=SpellE>Pbna</span> (#4)<o:p></o:p></h3> |
---|
2913 | |
---|
2914 | <p class=MsoNormal>To begin, be sure <b style='mso-bidi-font-weight:normal'><span |
---|
2915 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2916 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 10K.gpx</span></b> |
---|
2917 | is opened in your GSAS-II; we are going to repeat the above steps. Select the <b |
---|
2918 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2919 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2920 | minor-latin'>Mn3O4</span></b> phase and do <b style='mso-bidi-font-weight:normal'><span |
---|
2921 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2922 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Compute/Select |
---|
2923 | magnetic phase</span></b>; a popup selection will appear<o:p></o:p></p> |
---|
2924 | |
---|
2925 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2926 | id="Picture_x0020_46" o:spid="_x0000_i1040" type="#_x0000_t75" style='width:187.5pt; |
---|
2927 | height:155.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2928 | <v:imagedata src="Magnetic-V_files/image066.png" o:title=""/> |
---|
2929 | </v:shape><![endif]--><![if !vml]><img border=0 width=250 height=207 |
---|
2930 | src="Magnetic-V_files/image086.gif" v:shapes="Picture_x0020_46"><![endif]></span><o:p></o:p></p> |
---|
2931 | |
---|
2932 | <p class=MsoNormal>Weve done the 1<sup>st</sup> two; now pick the <b |
---|
2933 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2934 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2935 | minor-latin'>3rd</span></b> and press <b style='mso-bidi-font-weight:normal'><span |
---|
2936 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2937 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
2938 | A new popup will appear<o:p></o:p></p> |
---|
2939 | |
---|
2940 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2941 | id="Picture_x0020_51" o:spid="_x0000_i1039" type="#_x0000_t75" style='width:269.25pt; |
---|
2942 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2943 | <v:imagedata src="Magnetic-V_files/image095.png" o:title=""/> |
---|
2944 | </v:shape><![endif]--><![if !vml]><img border=0 width=359 height=186 |
---|
2945 | src="Magnetic-V_files/image096.gif" v:shapes="Picture_x0020_51"><![endif]></span><o:p></o:p></p> |
---|
2946 | |
---|
2947 | <p class=MsoNormal>Press <span class=GramE><b style='mso-bidi-font-weight:normal'><span |
---|
2948 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2949 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Yes</span></b></span>; |
---|
2950 | a new project will be created <b style='mso-bidi-font-weight:normal'><span |
---|
2951 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2952 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 mag_4.gpx</span></b> |
---|
2953 | and you will be at the General tab for the new magnetic phase<o:p></o:p></p> |
---|
2954 | |
---|
2955 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2956 | id="Picture_x0020_52" o:spid="_x0000_i1038" type="#_x0000_t75" style='width:358.5pt; |
---|
2957 | height:206.25pt;visibility:visible;mso-wrap-style:square'> |
---|
2958 | <v:imagedata src="Magnetic-V_files/image097.png" o:title=""/> |
---|
2959 | </v:shape><![endif]--><![if !vml]><img border=0 width=478 height=275 |
---|
2960 | src="Magnetic-V_files/image098.gif" v:shapes="Picture_x0020_52"><![endif]></span><o:p></o:p></p> |
---|
2961 | |
---|
2962 | <p class=MsoNormal>Select <b style='mso-bidi-font-weight:normal'><span |
---|
2963 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2964 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Atoms</span></b> |
---|
2965 | and enter <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2966 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2967 | minor-latin'>2</span></b> for every <span class=SpellE><b style='mso-bidi-font-weight: |
---|
2968 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2969 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mx</span></b></span><b |
---|
2970 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2971 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2972 | minor-latin'> My <span class=SpellE>Mz</span></span></b> allowed for all 4 |
---|
2973 | atoms; it should look like<o:p></o:p></p> |
---|
2974 | |
---|
2975 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2976 | id="Picture_x0020_53" o:spid="_x0000_i1037" type="#_x0000_t75" style='width:355.5pt; |
---|
2977 | height:94.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2978 | <v:imagedata src="Magnetic-V_files/image099.png" o:title=""/> |
---|
2979 | </v:shape><![endif]--><![if !vml]><img border=0 width=474 height=126 |
---|
2980 | src="Magnetic-V_files/image100.gif" v:shapes="Picture_x0020_53"><![endif]></span><o:p></o:p></p> |
---|
2981 | |
---|
2982 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
2983 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2984 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
2985 | for Scale & Background for 2 data sets (<span class=SpellE>wR</span> = 25.9%). |
---|
2986 | Set refine for all <span class=SpellE>Mn</span> atoms to <b style='mso-bidi-font-weight: |
---|
2987 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2988 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>M</span></b> |
---|
2989 | and do <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2990 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2991 | minor-latin'>Calculate/Refine</span></b> 2-3 times to convergence (<span |
---|
2992 | class=SpellE>wR</span>=19.9%).<o:p></o:p></p> |
---|
2993 | |
---|
2994 | <p class=MsoNormal>Next select the <b style='mso-bidi-font-weight:normal'><span |
---|
2995 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2996 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>General</span></b> |
---|
2997 | tab for each phase and check the <b style='mso-bidi-font-weight:normal'><span |
---|
2998 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2999 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Refine unit |
---|
3000 | cell</span></b> box for each. Then select <b style='mso-bidi-font-weight:normal'><span |
---|
3001 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3002 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Constraints</span></b> |
---|
3003 | (there will be a popup about a conflict; press <b style='mso-bidi-font-weight: |
---|
3004 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3005 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>).<o:p></o:p></p> |
---|
3006 | |
---|
3007 | <p class=MsoNormal>Fix the constraints as above: 1) delete the one in error, 2) |
---|
3008 | add an equivalence for <span style='font-family:"Calibri",sans-serif; |
---|
3009 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3010 | minor-latin'>1::A0 = 1::A1</span> and 3) edit the constraint so <b |
---|
3011 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3012 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3013 | minor-latin'>1::A0 = 0.250*1::A1</span></b> to give<o:p></o:p></p> |
---|
3014 | |
---|
3015 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3016 | id="Picture_x0020_58" o:spid="_x0000_i1036" type="#_x0000_t75" style='width:354pt; |
---|
3017 | height:239.25pt;visibility:visible;mso-wrap-style:square'> |
---|
3018 | <v:imagedata src="Magnetic-V_files/image101.png" o:title=""/> |
---|
3019 | </v:shape><![endif]--><![if !vml]><img border=0 width=472 height=319 |
---|
3020 | src="Magnetic-V_files/image102.gif" v:shapes="Picture_x0020_58"><![endif]></span><o:p></o:p></p> |
---|
3021 | |
---|
3022 | <p class=MsoNormal>Now do <b style='mso-bidi-font-weight:normal'><span |
---|
3023 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3024 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
3025 | until convergence (my <span class=SpellE>wR</span>=15.8% after several |
---|
3026 | refinements).<o:p></o:p></p> |
---|
3027 | |
---|
3028 | <p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span |
---|
3029 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3030 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Save</span></b> |
---|
3031 | the project; we may look at it later for more refinement.<o:p></o:p></p> |
---|
3032 | |
---|
3033 | <h3 style='margin-left:.5in;text-indent:-.25in;mso-list:l9 level1 lfo13'><![if !supportLists]><span |
---|
3034 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>4.<span |
---|
3035 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Try |
---|
3036 | <span class=SpellE>Pbna</span> (#8)<o:p></o:p></h3> |
---|
3037 | |
---|
3038 | <p class=MsoNormal>To begin, be sure <b style='mso-bidi-font-weight:normal'><span |
---|
3039 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3040 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 10K.gpx</span></b> |
---|
3041 | is opened in your GSAS-II; we are going to repeat the above steps. Select the <b |
---|
3042 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3043 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3044 | minor-latin'>Mn3O4</span></b> phase and do <b style='mso-bidi-font-weight:normal'><span |
---|
3045 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3046 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Compute/Select |
---|
3047 | magnetic phase</span></b>; a popup selection will appear<o:p></o:p></p> |
---|
3048 | |
---|
3049 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3050 | id="Picture_x0020_59" o:spid="_x0000_i1035" type="#_x0000_t75" style='width:187.5pt; |
---|
3051 | height:155.25pt;visibility:visible;mso-wrap-style:square'> |
---|
3052 | <v:imagedata src="Magnetic-V_files/image066.png" o:title=""/> |
---|
3053 | </v:shape><![endif]--><![if !vml]><img border=0 width=250 height=207 |
---|
3054 | src="Magnetic-V_files/image086.gif" v:shapes="Picture_x0020_59"><![endif]></span><o:p></o:p></p> |
---|
3055 | |
---|
3056 | <p class=MsoNormal>Weve done the 1<sup>st</sup> three; now pick the <b |
---|
3057 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3058 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3059 | minor-latin'>last</span></b> one (#8) and press <b style='mso-bidi-font-weight: |
---|
3060 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3061 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
3062 | A new popup will appear<o:p></o:p></p> |
---|
3063 | |
---|
3064 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3065 | id="Picture_x0020_64" o:spid="_x0000_i1034" type="#_x0000_t75" style='width:265.5pt; |
---|
3066 | height:139.5pt;visibility:visible;mso-wrap-style:square'> |
---|
3067 | <v:imagedata src="Magnetic-V_files/image103.png" o:title=""/> |
---|
3068 | </v:shape><![endif]--><![if !vml]><img border=0 width=354 height=186 |
---|
3069 | src="Magnetic-V_files/image104.gif" v:shapes="Picture_x0020_64"><![endif]></span><o:p></o:p></p> |
---|
3070 | |
---|
3071 | <p class=MsoNormal>Press <span class=GramE><b style='mso-bidi-font-weight:normal'><span |
---|
3072 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3073 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Yes</span></b></span>; |
---|
3074 | a new project will be created <b style='mso-bidi-font-weight:normal'><span |
---|
3075 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3076 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mn3O4 mag_4.gpx</span></b> |
---|
3077 | and you will be at the General tab for the new magnetic phase<o:p></o:p></p> |
---|
3078 | |
---|
3079 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3080 | id="Picture_x0020_65" o:spid="_x0000_i1033" type="#_x0000_t75" style='width:359.25pt; |
---|
3081 | height:203.25pt;visibility:visible;mso-wrap-style:square'> |
---|
3082 | <v:imagedata src="Magnetic-V_files/image105.png" o:title=""/> |
---|
3083 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=271 |
---|
3084 | src="Magnetic-V_files/image106.gif" v:shapes="Picture_x0020_65"><![endif]></span><o:p></o:p></p> |
---|
3085 | |
---|
3086 | <p class=MsoNormal>Select <b style='mso-bidi-font-weight:normal'><span |
---|
3087 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3088 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Atoms</span></b> |
---|
3089 | and enter <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3090 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3091 | minor-latin'>2</span></b> for every <span class=SpellE><b style='mso-bidi-font-weight: |
---|
3092 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3093 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mx</span></b></span><b |
---|
3094 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3095 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3096 | minor-latin'> My <span class=SpellE>Mz</span></span></b> allowed for all 4 |
---|
3097 | atoms; it should look like<o:p></o:p></p> |
---|
3098 | |
---|
3099 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3100 | id="Picture_x0020_67" o:spid="_x0000_i1032" type="#_x0000_t75" style='width:356.25pt; |
---|
3101 | height:90pt;visibility:visible;mso-wrap-style:square'> |
---|
3102 | <v:imagedata src="Magnetic-V_files/image107.png" o:title=""/> |
---|
3103 | </v:shape><![endif]--><![if !vml]><img border=0 width=475 height=120 |
---|
3104 | src="Magnetic-V_files/image108.gif" v:shapes="Picture_x0020_67"><![endif]></span><o:p></o:p></p> |
---|
3105 | |
---|
3106 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
3107 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3108 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
3109 | for Scale & Background for 2 data sets (<span class=SpellE>wR</span> = 28.8%). |
---|
3110 | Set refine for all <span class=SpellE>Mn</span> atoms to <b style='mso-bidi-font-weight: |
---|
3111 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3112 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>M</span></b> |
---|
3113 | and do <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3114 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3115 | minor-latin'>Calculate/Refine</span></b> 2-3 times to convergence (<span |
---|
3116 | class=SpellE>wR</span>=22.7%).<o:p></o:p></p> |
---|
3117 | |
---|
3118 | <p class=MsoNormal>Next select the <b style='mso-bidi-font-weight:normal'><span |
---|
3119 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3120 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>General</span></b> |
---|
3121 | tab for each phase and check the <b style='mso-bidi-font-weight:normal'><span |
---|
3122 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3123 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Refine unit |
---|
3124 | cell</span></b> box for each. Then select <b style='mso-bidi-font-weight:normal'><span |
---|
3125 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3126 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Constraints</span></b> |
---|
3127 | (there will be a popup about a conflict; press <b style='mso-bidi-font-weight: |
---|
3128 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3129 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>).<o:p></o:p></p> |
---|
3130 | |
---|
3131 | <p class=MsoNormal>Fix the constraints as above: 1) delete the one in error, 2) |
---|
3132 | add an equivalence for <b style='mso-bidi-font-weight:normal'><span |
---|
3133 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3134 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1::A0 = 1::A1</span></b> |
---|
3135 | and 3) edit the constraint so <b style='mso-bidi-font-weight:normal'><span |
---|
3136 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3137 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1::A0 = 0.250*1::A1</span></b> |
---|
3138 | to give<o:p></o:p></p> |
---|
3139 | |
---|
3140 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3141 | id="Picture_x0020_66" o:spid="_x0000_i1031" type="#_x0000_t75" style='width:357pt; |
---|
3142 | height:233.25pt;visibility:visible;mso-wrap-style:square'> |
---|
3143 | <v:imagedata src="Magnetic-V_files/image109.png" o:title=""/> |
---|
3144 | </v:shape><![endif]--><![if !vml]><img border=0 width=476 height=311 |
---|
3145 | src="Magnetic-V_files/image110.gif" v:shapes="Picture_x0020_66"><![endif]></span><o:p></o:p></p> |
---|
3146 | |
---|
3147 | <p class=MsoNormal>Now do <b style='mso-bidi-font-weight:normal'><span |
---|
3148 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3149 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
3150 | until convergence (my <span class=SpellE>wR</span>=19.4% after several |
---|
3151 | refinements).<o:p></o:p></p> |
---|
3152 | |
---|
3153 | <p class=MsoNormal>Save the project; we may look at it later for more |
---|
3154 | refinement.</p> |
---|
3155 | |
---|
3156 | <h3>Review results and complete refinement</h3> |
---|
3157 | |
---|
3158 | <p class=MsoNormal>Comparing the final <span class=SpellE>wR</span> values for |
---|
3159 | the 4 structures gives the following order: 1) <span class=SpellE>Pbna</span> |
---|
3160 | (#4) <span class=SpellE>wR</span>=15.8%, 2) <span class=SpellE>Pbna</span> |
---|
3161 | (#2) <span class=SpellE>wR</span>= 16.4%, 3) <span class=SpellE>Pbna</span> |
---|
3162 | (#3) <span class=SpellE>wR</span>=16.9% and 4) <span class=SpellE>Pbna</span> |
---|
3163 | (#8) <span class=SpellE>wR</span>=19.4%. Clearly, #8 is poorest and #4 is best |
---|
3164 | in terms of residuals. The pattern for the higher d-spacing frame shows the fit</p> |
---|
3165 | |
---|
3166 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3167 | id="Picture_x0020_68" o:spid="_x0000_i1030" type="#_x0000_t75" style='width:5in; |
---|
3168 | height:319.5pt;visibility:visible;mso-wrap-style:square'> |
---|
3169 | <v:imagedata src="Magnetic-V_files/image134.png" o:title=""/> |
---|
3170 | </v:shape><![endif]--><![if !vml]><img border=0 width=480 height=426 |
---|
3171 | src="Magnetic-V_files/image135.gif" v:shapes="Picture_x0020_68"><![endif]></span></p> |
---|
3172 | |
---|
3173 | <p class=MsoNormal>The principal problem seems to be peak positions; the |
---|
3174 | magnitudes seem ok which indicates that the magnetic structure is correct.</p> |
---|
3175 | |
---|
3176 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3177 | id="Picture_x0020_69" o:spid="_x0000_i1029" type="#_x0000_t75" style='width:5in; |
---|
3178 | height:94.5pt;visibility:visible;mso-wrap-style:square'> |
---|
3179 | <v:imagedata src="Magnetic-V_files/image136.png" o:title=""/> |
---|
3180 | </v:shape><![endif]--><![if !vml]><img border=0 width=480 height=126 |
---|
3181 | src="Magnetic-V_files/image137.gif" v:shapes="Picture_x0020_69"><![endif]></span><o:p></o:p></p> |
---|
3182 | |
---|
3183 | <p class=MsoNormal>Looking at the magnetic moment components, it appears that <span |
---|
3184 | class=SpellE>Mx</span> could be zero for all atoms. Lets try this; set all <span |
---|
3185 | class=SpellE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
3186 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
3187 | minor-latin;mso-bidi-theme-font:minor-latin'>Mx</span></b></span><b |
---|
3188 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3189 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3190 | minor-latin'> = 0</span></b>. Now we have to add holds on these in Constraints |
---|
3191 | to keep them at zero (and avoid possible least-squares singularities). Go to <b |
---|
3192 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3193 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3194 | minor-latin'>Constraints</span></b> and do <b style='mso-bidi-font-weight:normal'><span |
---|
3195 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3196 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Edit Constr<span |
---|
3197 | class=GramE>./</span>Add hold</span></b>; a popup will appear</p> |
---|
3198 | |
---|
3199 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3200 | id="Picture_x0020_70" o:spid="_x0000_i1028" type="#_x0000_t75" style='width:7in; |
---|
3201 | height:252.75pt;visibility:visible;mso-wrap-style:square'> |
---|
3202 | <v:imagedata src="Magnetic-V_files/image138.png" o:title=""/> |
---|
3203 | </v:shape><![endif]--><![if !vml]><img border=0 width=672 height=337 |
---|
3204 | src="Magnetic-V_files/image139.gif" v:shapes="Picture_x0020_70"><![endif]></span></p> |
---|
3205 | |
---|
3206 | <p class=MsoNormal>Use <span class=SpellE><b style='mso-bidi-font-weight:normal'><span |
---|
3207 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3208 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mx</span></b></span> |
---|
3209 | for the filter and select all that shows (it doesnt matter that one is fixed |
---|
3210 | by symmetry). The Constraints list will show the holds at the bottom</p> |
---|
3211 | |
---|
3212 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3213 | id="Picture_x0020_71" o:spid="_x0000_i1027" type="#_x0000_t75" style='width:444pt; |
---|
3214 | height:438pt;visibility:visible;mso-wrap-style:square'> |
---|
3215 | <v:imagedata src="Magnetic-V_files/image140.png" o:title=""/> |
---|
3216 | </v:shape><![endif]--><![if !vml]><img border=0 width=592 height=584 |
---|
3217 | src="Magnetic-V_files/image141.gif" v:shapes="Picture_x0020_71"><![endif]></span></p> |
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3218 | |
---|
3219 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
3220 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3221 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
3222 | until convergence (<span class=SpellE>wR</span>=15.8%); it is essentially |
---|
3223 | unchanged showing that <span class=SpellE>Mx</span>=0 is a valid assumption. In |
---|
3224 | addition it appears that <span class=SpellE>Mz</span>=0 for the 1<sup>st</sup> <span |
---|
3225 | class=SpellE>Mn</span> atom. Set <span class=SpellE><b style='mso-bidi-font-weight: |
---|
3226 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3227 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Mz</span></b></span><b |
---|
3228 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3229 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3230 | minor-latin'>=0</span></b> for it and add the appropriate hold for it to the |
---|
3231 | constraints list. Finally we can refine the remaining atom parameters; set <b |
---|
3232 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3233 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3234 | minor-latin'>U</span></b> for all atoms and <b style='mso-bidi-font-weight: |
---|
3235 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3236 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>XU</span></b> |
---|
3237 | for the O-atom in the chemical cell, and <b style='mso-bidi-font-weight:normal'><span |
---|
3238 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3239 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>UM</span></b> |
---|
3240 | for all <span class=SpellE>Mn</span> atoms in the magnetic cell. Whatever |
---|
3241 | constraints are needed to tie these together have already been entered in the |
---|
3242 | Constraints list. Do <b style='mso-bidi-font-weight:normal'><span |
---|
3243 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3244 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
3245 | until convergence (<span class=SpellE>wR</span>=15.9%); the residual is |
---|
3246 | essentially unchanged. These parameters were already well determined from the |
---|
3247 | 60K data. We still see peak position errors especially for the magnetic peaks |
---|
3248 | at high d-spacing. This probably arises from a bit of magnetically induced |
---|
3249 | strain on the lattice. We can explore this by refining the <span class=SpellE>Dij</span> |
---|
3250 | coefficients for the magnetic phase. Go to the <b style='mso-bidi-font-weight: |
---|
3251 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3252 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Data</span></b> |
---|
3253 | tab for the magnetic phase</p> |
---|
3254 | |
---|
3255 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3256 | id="Picture_x0020_72" o:spid="_x0000_i1026" type="#_x0000_t75" style='width:445.5pt; |
---|
3257 | height:335.25pt;visibility:visible;mso-wrap-style:square'> |
---|
3258 | <v:imagedata src="Magnetic-V_files/image142.png" o:title=""/> |
---|
3259 | </v:shape><![endif]--><![if !vml]><img border=0 width=594 height=447 |
---|
3260 | src="Magnetic-V_files/image143.gif" v:shapes="Picture_x0020_72"><![endif]></span><br> |
---|
3261 | <span class=GramE>and</span> set the refine boxes for <b style='mso-bidi-font-weight: |
---|
3262 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3263 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>D11 |
---|
3264 | D22</span></b> & <b style='mso-bidi-font-weight:normal'><span |
---|
3265 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3266 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>D33</span></b> |
---|
3267 | for both histograms. (<span class=GramE>do</span> not be tempted to do the same |
---|
3268 | for the chemical phase that will result in a singular matrix error because of |
---|
3269 | the coupling with the lattice parameters). Do <b style='mso-bidi-font-weight: |
---|
3270 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
3271 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
3272 | until convergence; my <span class=SpellE>wR</span>=15.2% is significantly |
---|
3273 | better showing that magnetic strain is a possibility. Since D11 & D33 are |
---|
3274 | < than D22, they could be reset to zero & not refined. In that case <span |
---|
3275 | class=SpellE>wR</span>=15.2% again indicating that all the magnetic strain is |
---|
3276 | along the b-axis (the one that was doubled). This analysis is not strictly |
---|
3277 | correct because it does not allow the chemical cell to show the magnetic |
---|
3278 | strain. To do this one has to describe the chemical structure in the doubled |
---|
3279 | magnetic cell with the space group <span class=SpellE>Pbna</span> (probably |
---|
3280 | doubling or more the number of atom positions and having a very unstable |
---|
3281 | refinement to deal with). Next we examine our result.</p> |
---|
3282 | |
---|
3283 | <p class=MsoNormal>Go to the <b style='mso-bidi-font-weight:normal'><span |
---|
3284 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3285 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Draw Atoms</span></b> |
---|
3286 | tab for the magnetic phase. Then select all the atoms and do <span class=GramE><b |
---|
3287 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3288 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3289 | minor-latin'>Edit</span></b></span><b style='mso-bidi-font-weight:normal'><span |
---|
3290 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3291 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'> Figure/Fill |
---|
3292 | unit cell</span></b>. The structure will be redrawn showing the complex |
---|
3293 | magnetic structure.</p> |
---|
3294 | |
---|
3295 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
3296 | id="Picture_x0020_73" o:spid="_x0000_i1025" type="#_x0000_t75" style='width:361.5pt; |
---|
3297 | height:321pt;visibility:visible;mso-wrap-style:square'> |
---|
3298 | <v:imagedata src="Magnetic-V_files/image144.png" o:title=""/> |
---|
3299 | </v:shape><![endif]--><![if !vml]><img border=0 width=482 height=428 |
---|
3300 | src="Magnetic-V_files/image145.gif" v:shapes="Picture_x0020_73"><![endif]></span></p> |
---|
3301 | |
---|
3302 | <p class=MsoNormal>Ive colored the tetrahedral <span class=SpellE>Mn</span> |
---|
3303 | atoms as orange to distinguish them from the octahedral ones; you can do that |
---|
3304 | by selecting <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
3305 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
3306 | minor-latin;mso-bidi-theme-font:minor-latin'>Mn1_0</span></b> from the <b |
---|
3307 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
3308 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
3309 | minor-latin'>Name</span></b> column (double click the heading and select from |
---|
3310 | the popup). Then do <b style='mso-bidi-font-weight:normal'><span |
---|
3311 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
3312 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Edit Figure/Atom |
---|
3313 | color</span></b>; select the color from the pallet. The tetrahedral ones are |
---|
3314 | ordered aligned <span class=SpellE>ferromagnetically</span> along the doubled |
---|
3315 | b-axis while the rest are in two intersecting ferromagnetic layers to give an overall |
---|
3316 | antiferromagnetic structure. This arrangement is essentially that of Jensen |
---|
3317 | & Nielsen but with a properly selected magnetic space group, <span |
---|
3318 | class=SpellE>Pbna</span>, as a subgroup of I4<sub>1</sub>/<span class=SpellE>amd</span>, |
---|
3319 | and associated set of unique magnetic <span class=SpellE>Mn</span> atoms. This |
---|
3320 | completes this tutorial, you can save the project if you wish.</p> |
---|
3321 | |
---|
3322 | </div> |
---|
3323 | |
---|
3324 | </body> |
---|
3325 | |
---|
3326 | </html> |
---|