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23 | <o:Author>Von Dreele</o:Author> |
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24 | <o:LastAuthor>vondreele</o:LastAuthor> |
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25 | <o:Revision>16</o:Revision> |
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26 | <o:TotalTime>554</o:TotalTime> |
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27 | <o:Created>2012-05-05T14:50:00Z</o:Created> |
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28 | <o:LastSaved>2018-09-30T13:28:00Z</o:LastSaved> |
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29 | <o:Pages>19</o:Pages> |
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186 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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188 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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204 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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219 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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220 | Name="Body Text Indent"/> |
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221 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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223 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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225 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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227 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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229 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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230 | Name="List Continue 5"/> |
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231 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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233 | <w:LsdException Locked="false" Priority="11" QFormat="true" Name="Subtitle"/> |
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234 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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235 | Name="Salutation"/> |
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236 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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237 | Name="Date"/> |
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238 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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240 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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241 | Name="Body Text First Indent 2"/> |
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242 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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243 | Name="Note Heading"/> |
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244 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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246 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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247 | Name="Body Text 3"/> |
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248 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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250 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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251 | Name="Body Text Indent 3"/> |
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252 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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253 | Name="Block Text"/> |
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254 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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256 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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258 | <w:LsdException Locked="false" Priority="22" QFormat="true" Name="Strong"/> |
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259 | <w:LsdException Locked="false" Priority="20" QFormat="true" Name="Emphasis"/> |
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260 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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262 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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263 | Name="Plain Text"/> |
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264 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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265 | Name="E-mail Signature"/> |
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266 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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268 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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271 | Name="Normal (Web)"/> |
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272 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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274 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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275 | Name="HTML Address"/> |
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276 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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278 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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279 | Name="HTML Code"/> |
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280 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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281 | Name="HTML Definition"/> |
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282 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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283 | Name="HTML Keyboard"/> |
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284 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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285 | Name="HTML Preformatted"/> |
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286 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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287 | Name="HTML Sample"/> |
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288 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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289 | Name="HTML Typewriter"/> |
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290 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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291 | Name="HTML Variable"/> |
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292 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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293 | Name="Normal Table"/> |
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294 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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295 | Name="annotation subject"/> |
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296 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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298 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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300 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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301 | Name="Outline List 2"/> |
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302 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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303 | Name="Outline List 3"/> |
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304 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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306 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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307 | Name="Table Simple 2"/> |
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308 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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309 | Name="Table Simple 3"/> |
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310 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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312 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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313 | Name="Table Classic 2"/> |
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314 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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315 | Name="Table Classic 3"/> |
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316 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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317 | Name="Table Classic 4"/> |
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318 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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319 | Name="Table Colorful 1"/> |
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320 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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321 | Name="Table Colorful 2"/> |
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322 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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323 | Name="Table Colorful 3"/> |
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324 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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325 | Name="Table Columns 1"/> |
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326 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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327 | Name="Table Columns 2"/> |
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328 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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329 | Name="Table Columns 3"/> |
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330 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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331 | Name="Table Columns 4"/> |
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332 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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333 | Name="Table Columns 5"/> |
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334 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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335 | Name="Table Grid 1"/> |
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336 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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337 | Name="Table Grid 2"/> |
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338 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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339 | Name="Table Grid 3"/> |
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340 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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341 | Name="Table Grid 4"/> |
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342 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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343 | Name="Table Grid 5"/> |
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344 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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345 | Name="Table Grid 6"/> |
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346 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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347 | Name="Table Grid 7"/> |
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348 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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349 | Name="Table Grid 8"/> |
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350 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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351 | Name="Table List 1"/> |
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352 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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353 | Name="Table List 2"/> |
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354 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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355 | Name="Table List 3"/> |
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356 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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357 | Name="Table List 4"/> |
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358 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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359 | Name="Table List 5"/> |
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360 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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361 | Name="Table List 6"/> |
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362 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
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363 | Name="Table List 7"/> |
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364 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
365 | Name="Table List 8"/> |
---|
366 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
367 | Name="Table 3D effects 1"/> |
---|
368 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
369 | Name="Table 3D effects 2"/> |
---|
370 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
371 | Name="Table 3D effects 3"/> |
---|
372 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
373 | Name="Table Contemporary"/> |
---|
374 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
375 | Name="Table Elegant"/> |
---|
376 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
377 | Name="Table Professional"/> |
---|
378 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
379 | Name="Table Subtle 1"/> |
---|
380 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
381 | Name="Table Subtle 2"/> |
---|
382 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
383 | Name="Table Web 1"/> |
---|
384 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
385 | Name="Table Web 2"/> |
---|
386 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
387 | Name="Table Web 3"/> |
---|
388 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
389 | Name="Balloon Text"/> |
---|
390 | <w:LsdException Locked="false" Priority="59" Name="Table Grid"/> |
---|
391 | <w:LsdException Locked="false" SemiHidden="true" UnhideWhenUsed="true" |
---|
392 | Name="Table Theme"/> |
---|
393 | <w:LsdException Locked="false" SemiHidden="true" Name="Placeholder Text"/> |
---|
394 | <w:LsdException Locked="false" Priority="1" QFormat="true" Name="No Spacing"/> |
---|
395 | <w:LsdException Locked="false" Priority="60" Name="Light Shading"/> |
---|
396 | <w:LsdException Locked="false" Priority="61" Name="Light List"/> |
---|
397 | <w:LsdException Locked="false" Priority="62" Name="Light Grid"/> |
---|
398 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1"/> |
---|
399 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2"/> |
---|
400 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1"/> |
---|
401 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2"/> |
---|
402 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1"/> |
---|
403 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2"/> |
---|
404 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3"/> |
---|
405 | <w:LsdException Locked="false" Priority="70" Name="Dark List"/> |
---|
406 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading"/> |
---|
407 | <w:LsdException Locked="false" Priority="72" Name="Colorful List"/> |
---|
408 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid"/> |
---|
409 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 1"/> |
---|
410 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 1"/> |
---|
411 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 1"/> |
---|
412 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 1"/> |
---|
413 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 1"/> |
---|
414 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 1"/> |
---|
415 | <w:LsdException Locked="false" SemiHidden="true" Name="Revision"/> |
---|
416 | <w:LsdException Locked="false" Priority="34" QFormat="true" |
---|
417 | Name="List Paragraph"/> |
---|
418 | <w:LsdException Locked="false" Priority="29" QFormat="true" Name="Quote"/> |
---|
419 | <w:LsdException Locked="false" Priority="30" QFormat="true" |
---|
420 | Name="Intense Quote"/> |
---|
421 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 1"/> |
---|
422 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 1"/> |
---|
423 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 1"/> |
---|
424 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 1"/> |
---|
425 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 1"/> |
---|
426 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 1"/> |
---|
427 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 1"/> |
---|
428 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 1"/> |
---|
429 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 2"/> |
---|
430 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 2"/> |
---|
431 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 2"/> |
---|
432 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 2"/> |
---|
433 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 2"/> |
---|
434 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 2"/> |
---|
435 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 2"/> |
---|
436 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 2"/> |
---|
437 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 2"/> |
---|
438 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 2"/> |
---|
439 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 2"/> |
---|
440 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 2"/> |
---|
441 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 2"/> |
---|
442 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 2"/> |
---|
443 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 3"/> |
---|
444 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 3"/> |
---|
445 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 3"/> |
---|
446 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 3"/> |
---|
447 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 3"/> |
---|
448 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 3"/> |
---|
449 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 3"/> |
---|
450 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 3"/> |
---|
451 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 3"/> |
---|
452 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 3"/> |
---|
453 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 3"/> |
---|
454 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 3"/> |
---|
455 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 3"/> |
---|
456 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 3"/> |
---|
457 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 4"/> |
---|
458 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 4"/> |
---|
459 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 4"/> |
---|
460 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 4"/> |
---|
461 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 4"/> |
---|
462 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 4"/> |
---|
463 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 4"/> |
---|
464 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 4"/> |
---|
465 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 4"/> |
---|
466 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 4"/> |
---|
467 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 4"/> |
---|
468 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 4"/> |
---|
469 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 4"/> |
---|
470 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 4"/> |
---|
471 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 5"/> |
---|
472 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 5"/> |
---|
473 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 5"/> |
---|
474 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 5"/> |
---|
475 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 5"/> |
---|
476 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 5"/> |
---|
477 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 5"/> |
---|
478 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 5"/> |
---|
479 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 5"/> |
---|
480 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 5"/> |
---|
481 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 5"/> |
---|
482 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 5"/> |
---|
483 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 5"/> |
---|
484 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 5"/> |
---|
485 | <w:LsdException Locked="false" Priority="60" Name="Light Shading Accent 6"/> |
---|
486 | <w:LsdException Locked="false" Priority="61" Name="Light List Accent 6"/> |
---|
487 | <w:LsdException Locked="false" Priority="62" Name="Light Grid Accent 6"/> |
---|
488 | <w:LsdException Locked="false" Priority="63" Name="Medium Shading 1 Accent 6"/> |
---|
489 | <w:LsdException Locked="false" Priority="64" Name="Medium Shading 2 Accent 6"/> |
---|
490 | <w:LsdException Locked="false" Priority="65" Name="Medium List 1 Accent 6"/> |
---|
491 | <w:LsdException Locked="false" Priority="66" Name="Medium List 2 Accent 6"/> |
---|
492 | <w:LsdException Locked="false" Priority="67" Name="Medium Grid 1 Accent 6"/> |
---|
493 | <w:LsdException Locked="false" Priority="68" Name="Medium Grid 2 Accent 6"/> |
---|
494 | <w:LsdException Locked="false" Priority="69" Name="Medium Grid 3 Accent 6"/> |
---|
495 | <w:LsdException Locked="false" Priority="70" Name="Dark List Accent 6"/> |
---|
496 | <w:LsdException Locked="false" Priority="71" Name="Colorful Shading Accent 6"/> |
---|
497 | <w:LsdException Locked="false" Priority="72" Name="Colorful List Accent 6"/> |
---|
498 | <w:LsdException Locked="false" Priority="73" Name="Colorful Grid Accent 6"/> |
---|
499 | <w:LsdException Locked="false" Priority="19" QFormat="true" |
---|
500 | Name="Subtle Emphasis"/> |
---|
501 | <w:LsdException Locked="false" Priority="21" QFormat="true" |
---|
502 | Name="Intense Emphasis"/> |
---|
503 | <w:LsdException Locked="false" Priority="31" QFormat="true" |
---|
504 | Name="Subtle Reference"/> |
---|
505 | <w:LsdException Locked="false" Priority="32" QFormat="true" |
---|
506 | Name="Intense Reference"/> |
---|
507 | <w:LsdException Locked="false" Priority="33" QFormat="true" Name="Book Title"/> |
---|
508 | <w:LsdException Locked="false" Priority="37" SemiHidden="true" |
---|
509 | UnhideWhenUsed="true" Name="Bibliography"/> |
---|
510 | <w:LsdException Locked="false" Priority="39" SemiHidden="true" |
---|
511 | UnhideWhenUsed="true" QFormat="true" Name="TOC Heading"/> |
---|
512 | <w:LsdException Locked="false" Priority="41" Name="Plain Table 1"/> |
---|
513 | <w:LsdException Locked="false" Priority="42" Name="Plain Table 2"/> |
---|
514 | <w:LsdException Locked="false" Priority="43" Name="Plain Table 3"/> |
---|
515 | <w:LsdException Locked="false" Priority="44" Name="Plain Table 4"/> |
---|
516 | <w:LsdException Locked="false" Priority="45" Name="Plain Table 5"/> |
---|
517 | <w:LsdException Locked="false" Priority="40" Name="Grid Table Light"/> |
---|
518 | <w:LsdException Locked="false" Priority="46" Name="Grid Table 1 Light"/> |
---|
519 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2"/> |
---|
520 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3"/> |
---|
521 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4"/> |
---|
522 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark"/> |
---|
523 | <w:LsdException Locked="false" Priority="51" Name="Grid Table 6 Colorful"/> |
---|
524 | <w:LsdException Locked="false" Priority="52" Name="Grid Table 7 Colorful"/> |
---|
525 | <w:LsdException Locked="false" Priority="46" |
---|
526 | Name="Grid Table 1 Light Accent 1"/> |
---|
527 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 1"/> |
---|
528 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 1"/> |
---|
529 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 1"/> |
---|
530 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 1"/> |
---|
531 | <w:LsdException Locked="false" Priority="51" |
---|
532 | Name="Grid Table 6 Colorful Accent 1"/> |
---|
533 | <w:LsdException Locked="false" Priority="52" |
---|
534 | Name="Grid Table 7 Colorful Accent 1"/> |
---|
535 | <w:LsdException Locked="false" Priority="46" |
---|
536 | Name="Grid Table 1 Light Accent 2"/> |
---|
537 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 2"/> |
---|
538 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 2"/> |
---|
539 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 2"/> |
---|
540 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 2"/> |
---|
541 | <w:LsdException Locked="false" Priority="51" |
---|
542 | Name="Grid Table 6 Colorful Accent 2"/> |
---|
543 | <w:LsdException Locked="false" Priority="52" |
---|
544 | Name="Grid Table 7 Colorful Accent 2"/> |
---|
545 | <w:LsdException Locked="false" Priority="46" |
---|
546 | Name="Grid Table 1 Light Accent 3"/> |
---|
547 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 3"/> |
---|
548 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 3"/> |
---|
549 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 3"/> |
---|
550 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 3"/> |
---|
551 | <w:LsdException Locked="false" Priority="51" |
---|
552 | Name="Grid Table 6 Colorful Accent 3"/> |
---|
553 | <w:LsdException Locked="false" Priority="52" |
---|
554 | Name="Grid Table 7 Colorful Accent 3"/> |
---|
555 | <w:LsdException Locked="false" Priority="46" |
---|
556 | Name="Grid Table 1 Light Accent 4"/> |
---|
557 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 4"/> |
---|
558 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 4"/> |
---|
559 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 4"/> |
---|
560 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 4"/> |
---|
561 | <w:LsdException Locked="false" Priority="51" |
---|
562 | Name="Grid Table 6 Colorful Accent 4"/> |
---|
563 | <w:LsdException Locked="false" Priority="52" |
---|
564 | Name="Grid Table 7 Colorful Accent 4"/> |
---|
565 | <w:LsdException Locked="false" Priority="46" |
---|
566 | Name="Grid Table 1 Light Accent 5"/> |
---|
567 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 5"/> |
---|
568 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 5"/> |
---|
569 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 5"/> |
---|
570 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 5"/> |
---|
571 | <w:LsdException Locked="false" Priority="51" |
---|
572 | Name="Grid Table 6 Colorful Accent 5"/> |
---|
573 | <w:LsdException Locked="false" Priority="52" |
---|
574 | Name="Grid Table 7 Colorful Accent 5"/> |
---|
575 | <w:LsdException Locked="false" Priority="46" |
---|
576 | Name="Grid Table 1 Light Accent 6"/> |
---|
577 | <w:LsdException Locked="false" Priority="47" Name="Grid Table 2 Accent 6"/> |
---|
578 | <w:LsdException Locked="false" Priority="48" Name="Grid Table 3 Accent 6"/> |
---|
579 | <w:LsdException Locked="false" Priority="49" Name="Grid Table 4 Accent 6"/> |
---|
580 | <w:LsdException Locked="false" Priority="50" Name="Grid Table 5 Dark Accent 6"/> |
---|
581 | <w:LsdException Locked="false" Priority="51" |
---|
582 | Name="Grid Table 6 Colorful Accent 6"/> |
---|
583 | <w:LsdException Locked="false" Priority="52" |
---|
584 | Name="Grid Table 7 Colorful Accent 6"/> |
---|
585 | <w:LsdException Locked="false" Priority="46" Name="List Table 1 Light"/> |
---|
586 | <w:LsdException Locked="false" Priority="47" Name="List Table 2"/> |
---|
587 | <w:LsdException Locked="false" Priority="48" Name="List Table 3"/> |
---|
588 | <w:LsdException Locked="false" Priority="49" Name="List Table 4"/> |
---|
589 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark"/> |
---|
590 | <w:LsdException Locked="false" Priority="51" Name="List Table 6 Colorful"/> |
---|
591 | <w:LsdException Locked="false" Priority="52" Name="List Table 7 Colorful"/> |
---|
592 | <w:LsdException Locked="false" Priority="46" |
---|
593 | Name="List Table 1 Light Accent 1"/> |
---|
594 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 1"/> |
---|
595 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 1"/> |
---|
596 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 1"/> |
---|
597 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 1"/> |
---|
598 | <w:LsdException Locked="false" Priority="51" |
---|
599 | Name="List Table 6 Colorful Accent 1"/> |
---|
600 | <w:LsdException Locked="false" Priority="52" |
---|
601 | Name="List Table 7 Colorful Accent 1"/> |
---|
602 | <w:LsdException Locked="false" Priority="46" |
---|
603 | Name="List Table 1 Light Accent 2"/> |
---|
604 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 2"/> |
---|
605 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 2"/> |
---|
606 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 2"/> |
---|
607 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 2"/> |
---|
608 | <w:LsdException Locked="false" Priority="51" |
---|
609 | Name="List Table 6 Colorful Accent 2"/> |
---|
610 | <w:LsdException Locked="false" Priority="52" |
---|
611 | Name="List Table 7 Colorful Accent 2"/> |
---|
612 | <w:LsdException Locked="false" Priority="46" |
---|
613 | Name="List Table 1 Light Accent 3"/> |
---|
614 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 3"/> |
---|
615 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 3"/> |
---|
616 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 3"/> |
---|
617 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 3"/> |
---|
618 | <w:LsdException Locked="false" Priority="51" |
---|
619 | Name="List Table 6 Colorful Accent 3"/> |
---|
620 | <w:LsdException Locked="false" Priority="52" |
---|
621 | Name="List Table 7 Colorful Accent 3"/> |
---|
622 | <w:LsdException Locked="false" Priority="46" |
---|
623 | Name="List Table 1 Light Accent 4"/> |
---|
624 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 4"/> |
---|
625 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 4"/> |
---|
626 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 4"/> |
---|
627 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 4"/> |
---|
628 | <w:LsdException Locked="false" Priority="51" |
---|
629 | Name="List Table 6 Colorful Accent 4"/> |
---|
630 | <w:LsdException Locked="false" Priority="52" |
---|
631 | Name="List Table 7 Colorful Accent 4"/> |
---|
632 | <w:LsdException Locked="false" Priority="46" |
---|
633 | Name="List Table 1 Light Accent 5"/> |
---|
634 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 5"/> |
---|
635 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 5"/> |
---|
636 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 5"/> |
---|
637 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 5"/> |
---|
638 | <w:LsdException Locked="false" Priority="51" |
---|
639 | Name="List Table 6 Colorful Accent 5"/> |
---|
640 | <w:LsdException Locked="false" Priority="52" |
---|
641 | Name="List Table 7 Colorful Accent 5"/> |
---|
642 | <w:LsdException Locked="false" Priority="46" |
---|
643 | Name="List Table 1 Light Accent 6"/> |
---|
644 | <w:LsdException Locked="false" Priority="47" Name="List Table 2 Accent 6"/> |
---|
645 | <w:LsdException Locked="false" Priority="48" Name="List Table 3 Accent 6"/> |
---|
646 | <w:LsdException Locked="false" Priority="49" Name="List Table 4 Accent 6"/> |
---|
647 | <w:LsdException Locked="false" Priority="50" Name="List Table 5 Dark Accent 6"/> |
---|
648 | <w:LsdException Locked="false" Priority="51" |
---|
649 | Name="List Table 6 Colorful Accent 6"/> |
---|
650 | <w:LsdException Locked="false" Priority="52" |
---|
651 | Name="List Table 7 Colorful Accent 6"/> |
---|
652 | </w:LatentStyles> |
---|
653 | </xml><![endif]--> |
---|
654 | <style> |
---|
655 | <!-- |
---|
656 | /* Font Definitions */ |
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657 | @font-face |
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658 | {font-family:"Cambria Math"; |
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659 | panose-1:2 4 5 3 5 4 6 3 2 4; |
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660 | mso-font-charset:0; |
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661 | mso-generic-font-family:roman; |
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662 | mso-font-pitch:variable; |
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663 | mso-font-signature:-536869121 1107305727 33554432 0 415 0;} |
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664 | @font-face |
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665 | {font-family:Calibri; |
---|
666 | panose-1:2 15 5 2 2 2 4 3 2 4; |
---|
667 | mso-font-charset:0; |
---|
668 | mso-generic-font-family:swiss; |
---|
669 | mso-font-pitch:variable; |
---|
670 | mso-font-signature:-536859905 -1073732485 9 0 511 0;} |
---|
671 | @font-face |
---|
672 | {font-family:Tahoma; |
---|
673 | panose-1:2 11 6 4 3 5 4 4 2 4; |
---|
674 | mso-font-charset:0; |
---|
675 | mso-generic-font-family:swiss; |
---|
676 | mso-font-pitch:variable; |
---|
677 | mso-font-signature:-520081665 -1073717157 41 0 66047 0;} |
---|
678 | /* Style Definitions */ |
---|
679 | p.MsoNormal, li.MsoNormal, div.MsoNormal |
---|
680 | {mso-style-unhide:no; |
---|
681 | mso-style-qformat:yes; |
---|
682 | mso-style-parent:""; |
---|
683 | margin:0in; |
---|
684 | margin-bottom:.0001pt; |
---|
685 | mso-pagination:widow-orphan; |
---|
686 | font-size:12.0pt; |
---|
687 | font-family:"Times New Roman",serif; |
---|
688 | mso-fareast-font-family:"Times New Roman"; |
---|
689 | mso-fareast-theme-font:minor-fareast;} |
---|
690 | h1 |
---|
691 | {mso-style-priority:9; |
---|
692 | mso-style-unhide:no; |
---|
693 | mso-style-qformat:yes; |
---|
694 | mso-style-link:"Heading 1 Char"; |
---|
695 | mso-margin-top-alt:auto; |
---|
696 | margin-right:0in; |
---|
697 | mso-margin-bottom-alt:auto; |
---|
698 | margin-left:0in; |
---|
699 | mso-pagination:widow-orphan; |
---|
700 | mso-outline-level:1; |
---|
701 | font-size:24.0pt; |
---|
702 | font-family:"Times New Roman",serif; |
---|
703 | mso-fareast-font-family:"Times New Roman"; |
---|
704 | mso-fareast-theme-font:minor-fareast; |
---|
705 | font-weight:bold;} |
---|
706 | h2 |
---|
707 | {mso-style-noshow:yes; |
---|
708 | mso-style-priority:9; |
---|
709 | mso-style-qformat:yes; |
---|
710 | mso-style-link:"Heading 2 Char"; |
---|
711 | mso-margin-top-alt:auto; |
---|
712 | margin-right:0in; |
---|
713 | mso-margin-bottom-alt:auto; |
---|
714 | margin-left:0in; |
---|
715 | mso-pagination:widow-orphan; |
---|
716 | mso-outline-level:2; |
---|
717 | font-size:18.0pt; |
---|
718 | font-family:"Times New Roman",serif; |
---|
719 | mso-fareast-font-family:"Times New Roman"; |
---|
720 | mso-fareast-theme-font:minor-fareast; |
---|
721 | font-weight:bold;} |
---|
722 | h3 |
---|
723 | {mso-style-noshow:yes; |
---|
724 | mso-style-priority:9; |
---|
725 | mso-style-qformat:yes; |
---|
726 | mso-style-link:"Heading 3 Char"; |
---|
727 | mso-margin-top-alt:auto; |
---|
728 | margin-right:0in; |
---|
729 | mso-margin-bottom-alt:auto; |
---|
730 | margin-left:0in; |
---|
731 | mso-pagination:widow-orphan; |
---|
732 | mso-outline-level:3; |
---|
733 | font-size:13.5pt; |
---|
734 | font-family:"Times New Roman",serif; |
---|
735 | mso-fareast-font-family:"Times New Roman"; |
---|
736 | mso-fareast-theme-font:minor-fareast; |
---|
737 | font-weight:bold;} |
---|
738 | h4 |
---|
739 | {mso-style-noshow:yes; |
---|
740 | mso-style-priority:9; |
---|
741 | mso-style-qformat:yes; |
---|
742 | mso-style-link:"Heading 4 Char"; |
---|
743 | mso-style-next:Normal; |
---|
744 | margin-top:10.0pt; |
---|
745 | margin-right:0in; |
---|
746 | margin-bottom:0in; |
---|
747 | margin-left:0in; |
---|
748 | margin-bottom:.0001pt; |
---|
749 | mso-pagination:widow-orphan lines-together; |
---|
750 | page-break-after:avoid; |
---|
751 | mso-outline-level:4; |
---|
752 | font-size:13.0pt; |
---|
753 | font-family:"Calibri Light",sans-serif; |
---|
754 | mso-ascii-font-family:"Calibri Light"; |
---|
755 | mso-ascii-theme-font:major-latin; |
---|
756 | mso-fareast-font-family:"Times New Roman"; |
---|
757 | mso-fareast-theme-font:major-fareast; |
---|
758 | mso-hansi-font-family:"Calibri Light"; |
---|
759 | mso-hansi-theme-font:major-latin; |
---|
760 | mso-bidi-font-family:"Times New Roman"; |
---|
761 | mso-bidi-theme-font:major-bidi; |
---|
762 | color:#5B9BD5; |
---|
763 | mso-themecolor:accent1; |
---|
764 | font-weight:bold; |
---|
765 | font-style:italic;} |
---|
766 | h5 |
---|
767 | {mso-style-noshow:yes; |
---|
768 | mso-style-priority:9; |
---|
769 | mso-style-qformat:yes; |
---|
770 | mso-style-link:"Heading 5 Char"; |
---|
771 | mso-margin-top-alt:auto; |
---|
772 | margin-right:0in; |
---|
773 | mso-margin-bottom-alt:auto; |
---|
774 | margin-left:0in; |
---|
775 | mso-pagination:widow-orphan; |
---|
776 | mso-outline-level:5; |
---|
777 | font-size:12.0pt; |
---|
778 | font-family:"Times New Roman",serif; |
---|
779 | mso-fareast-font-family:"Times New Roman"; |
---|
780 | mso-fareast-theme-font:minor-fareast; |
---|
781 | color:#4F4FFF; |
---|
782 | font-weight:bold;} |
---|
783 | a:link, span.MsoHyperlink |
---|
784 | {mso-style-noshow:yes; |
---|
785 | mso-style-priority:99; |
---|
786 | color:blue; |
---|
787 | text-decoration:underline; |
---|
788 | text-underline:single;} |
---|
789 | a:visited, span.MsoHyperlinkFollowed |
---|
790 | {mso-style-noshow:yes; |
---|
791 | mso-style-priority:99; |
---|
792 | color:purple; |
---|
793 | text-decoration:underline; |
---|
794 | text-underline:single;} |
---|
795 | p.MsoDocumentMap, li.MsoDocumentMap, div.MsoDocumentMap |
---|
796 | {mso-style-noshow:yes; |
---|
797 | mso-style-priority:99; |
---|
798 | mso-style-link:"Document Map Char"; |
---|
799 | margin:0in; |
---|
800 | margin-bottom:.0001pt; |
---|
801 | mso-pagination:widow-orphan; |
---|
802 | font-size:8.0pt; |
---|
803 | font-family:"Tahoma",sans-serif; |
---|
804 | mso-fareast-font-family:"Times New Roman"; |
---|
805 | mso-fareast-theme-font:minor-fareast;} |
---|
806 | p |
---|
807 | {mso-style-noshow:yes; |
---|
808 | mso-style-priority:99; |
---|
809 | mso-margin-top-alt:auto; |
---|
810 | margin-right:0in; |
---|
811 | mso-margin-bottom-alt:auto; |
---|
812 | margin-left:0in; |
---|
813 | mso-pagination:widow-orphan; |
---|
814 | font-size:12.0pt; |
---|
815 | font-family:"Times New Roman",serif; |
---|
816 | mso-fareast-font-family:"Times New Roman"; |
---|
817 | mso-fareast-theme-font:minor-fareast;} |
---|
818 | pre |
---|
819 | {mso-style-noshow:yes; |
---|
820 | mso-style-priority:99; |
---|
821 | mso-style-link:"HTML Preformatted Char"; |
---|
822 | margin:0in; |
---|
823 | margin-bottom:.0001pt; |
---|
824 | mso-pagination:widow-orphan; |
---|
825 | tab-stops:45.8pt 91.6pt 137.4pt 183.2pt 229.0pt 274.8pt 320.6pt 366.4pt 412.2pt 458.0pt 503.8pt 549.6pt 595.4pt 641.2pt 687.0pt 732.8pt; |
---|
826 | font-size:10.0pt; |
---|
827 | font-family:"Courier New"; |
---|
828 | mso-fareast-font-family:"Times New Roman";} |
---|
829 | p.MsoAcetate, li.MsoAcetate, div.MsoAcetate |
---|
830 | {mso-style-noshow:yes; |
---|
831 | mso-style-priority:99; |
---|
832 | mso-style-link:"Balloon Text Char"; |
---|
833 | margin:0in; |
---|
834 | margin-bottom:.0001pt; |
---|
835 | mso-pagination:widow-orphan; |
---|
836 | font-size:8.0pt; |
---|
837 | font-family:"Tahoma",sans-serif; |
---|
838 | mso-fareast-font-family:"Times New Roman"; |
---|
839 | mso-fareast-theme-font:minor-fareast;} |
---|
840 | span.MsoPlaceholderText |
---|
841 | {mso-style-noshow:yes; |
---|
842 | mso-style-priority:99; |
---|
843 | mso-style-unhide:no; |
---|
844 | color:gray;} |
---|
845 | p.MsoNoSpacing, li.MsoNoSpacing, div.MsoNoSpacing |
---|
846 | {mso-style-noshow:yes; |
---|
847 | mso-style-priority:1; |
---|
848 | mso-style-unhide:no; |
---|
849 | mso-style-qformat:yes; |
---|
850 | mso-style-parent:""; |
---|
851 | margin:0in; |
---|
852 | margin-bottom:.0001pt; |
---|
853 | mso-pagination:widow-orphan; |
---|
854 | font-size:12.0pt; |
---|
855 | font-family:"Times New Roman",serif; |
---|
856 | mso-fareast-font-family:"Times New Roman"; |
---|
857 | mso-fareast-theme-font:minor-fareast;} |
---|
858 | p.MsoListParagraph, li.MsoListParagraph, div.MsoListParagraph |
---|
859 | {mso-style-noshow:yes; |
---|
860 | mso-style-priority:34; |
---|
861 | mso-style-unhide:no; |
---|
862 | mso-style-qformat:yes; |
---|
863 | margin-top:0in; |
---|
864 | margin-right:0in; |
---|
865 | margin-bottom:0in; |
---|
866 | margin-left:.5in; |
---|
867 | margin-bottom:.0001pt; |
---|
868 | mso-add-space:auto; |
---|
869 | mso-pagination:widow-orphan; |
---|
870 | font-size:12.0pt; |
---|
871 | font-family:"Times New Roman",serif; |
---|
872 | mso-fareast-font-family:"Times New Roman"; |
---|
873 | mso-fareast-theme-font:minor-fareast;} |
---|
874 | p.MsoListParagraphCxSpFirst, li.MsoListParagraphCxSpFirst, div.MsoListParagraphCxSpFirst |
---|
875 | {mso-style-noshow:yes; |
---|
876 | mso-style-priority:34; |
---|
877 | mso-style-unhide:no; |
---|
878 | mso-style-qformat:yes; |
---|
879 | mso-style-type:export-only; |
---|
880 | margin-top:0in; |
---|
881 | margin-right:0in; |
---|
882 | margin-bottom:0in; |
---|
883 | margin-left:.5in; |
---|
884 | margin-bottom:.0001pt; |
---|
885 | mso-add-space:auto; |
---|
886 | mso-pagination:widow-orphan; |
---|
887 | font-size:12.0pt; |
---|
888 | font-family:"Times New Roman",serif; |
---|
889 | mso-fareast-font-family:"Times New Roman"; |
---|
890 | mso-fareast-theme-font:minor-fareast;} |
---|
891 | p.MsoListParagraphCxSpMiddle, li.MsoListParagraphCxSpMiddle, div.MsoListParagraphCxSpMiddle |
---|
892 | {mso-style-noshow:yes; |
---|
893 | mso-style-priority:34; |
---|
894 | mso-style-unhide:no; |
---|
895 | mso-style-qformat:yes; |
---|
896 | mso-style-type:export-only; |
---|
897 | margin-top:0in; |
---|
898 | margin-right:0in; |
---|
899 | margin-bottom:0in; |
---|
900 | margin-left:.5in; |
---|
901 | margin-bottom:.0001pt; |
---|
902 | mso-add-space:auto; |
---|
903 | mso-pagination:widow-orphan; |
---|
904 | font-size:12.0pt; |
---|
905 | font-family:"Times New Roman",serif; |
---|
906 | mso-fareast-font-family:"Times New Roman"; |
---|
907 | mso-fareast-theme-font:minor-fareast;} |
---|
908 | p.MsoListParagraphCxSpLast, li.MsoListParagraphCxSpLast, div.MsoListParagraphCxSpLast |
---|
909 | {mso-style-noshow:yes; |
---|
910 | mso-style-priority:34; |
---|
911 | mso-style-unhide:no; |
---|
912 | mso-style-qformat:yes; |
---|
913 | mso-style-type:export-only; |
---|
914 | margin-top:0in; |
---|
915 | margin-right:0in; |
---|
916 | margin-bottom:0in; |
---|
917 | margin-left:.5in; |
---|
918 | margin-bottom:.0001pt; |
---|
919 | mso-add-space:auto; |
---|
920 | mso-pagination:widow-orphan; |
---|
921 | font-size:12.0pt; |
---|
922 | font-family:"Times New Roman",serif; |
---|
923 | mso-fareast-font-family:"Times New Roman"; |
---|
924 | mso-fareast-theme-font:minor-fareast;} |
---|
925 | span.MsoIntenseReference |
---|
926 | {mso-style-priority:32; |
---|
927 | mso-style-unhide:no; |
---|
928 | mso-style-qformat:yes; |
---|
929 | font-variant:small-caps; |
---|
930 | color:#ED7D31; |
---|
931 | mso-themecolor:accent2; |
---|
932 | letter-spacing:.25pt; |
---|
933 | font-weight:bold; |
---|
934 | text-decoration:underline; |
---|
935 | text-underline:single;} |
---|
936 | span.Heading1Char |
---|
937 | {mso-style-name:"Heading 1 Char"; |
---|
938 | mso-style-priority:9; |
---|
939 | mso-style-unhide:no; |
---|
940 | mso-style-locked:yes; |
---|
941 | mso-style-link:"Heading 1"; |
---|
942 | mso-ansi-font-size:24.0pt; |
---|
943 | mso-bidi-font-size:24.0pt; |
---|
944 | font-family:"Times New Roman",serif; |
---|
945 | mso-ascii-font-family:"Times New Roman"; |
---|
946 | mso-fareast-font-family:"Times New Roman"; |
---|
947 | mso-fareast-theme-font:minor-fareast; |
---|
948 | mso-hansi-font-family:"Times New Roman"; |
---|
949 | mso-bidi-font-family:"Times New Roman"; |
---|
950 | mso-font-kerning:18.0pt; |
---|
951 | font-weight:bold;} |
---|
952 | span.Heading2Char |
---|
953 | {mso-style-name:"Heading 2 Char"; |
---|
954 | mso-style-noshow:yes; |
---|
955 | mso-style-priority:9; |
---|
956 | mso-style-unhide:no; |
---|
957 | mso-style-locked:yes; |
---|
958 | mso-style-link:"Heading 2"; |
---|
959 | mso-ansi-font-size:18.0pt; |
---|
960 | mso-bidi-font-size:18.0pt; |
---|
961 | font-family:"Times New Roman",serif; |
---|
962 | mso-ascii-font-family:"Times New Roman"; |
---|
963 | mso-fareast-font-family:"Times New Roman"; |
---|
964 | mso-fareast-theme-font:minor-fareast; |
---|
965 | mso-hansi-font-family:"Times New Roman"; |
---|
966 | mso-bidi-font-family:"Times New Roman"; |
---|
967 | font-weight:bold;} |
---|
968 | span.Heading3Char |
---|
969 | {mso-style-name:"Heading 3 Char"; |
---|
970 | mso-style-noshow:yes; |
---|
971 | mso-style-priority:9; |
---|
972 | mso-style-unhide:no; |
---|
973 | mso-style-locked:yes; |
---|
974 | mso-style-link:"Heading 3"; |
---|
975 | mso-ansi-font-size:13.5pt; |
---|
976 | mso-bidi-font-size:13.5pt; |
---|
977 | font-family:"Times New Roman",serif; |
---|
978 | mso-ascii-font-family:"Times New Roman"; |
---|
979 | mso-fareast-font-family:"Times New Roman"; |
---|
980 | mso-fareast-theme-font:minor-fareast; |
---|
981 | mso-hansi-font-family:"Times New Roman"; |
---|
982 | mso-bidi-font-family:"Times New Roman"; |
---|
983 | font-weight:bold;} |
---|
984 | span.Heading4Char |
---|
985 | {mso-style-name:"Heading 4 Char"; |
---|
986 | mso-style-noshow:yes; |
---|
987 | mso-style-priority:9; |
---|
988 | mso-style-unhide:no; |
---|
989 | mso-style-locked:yes; |
---|
990 | mso-style-link:"Heading 4"; |
---|
991 | mso-ansi-font-size:13.0pt; |
---|
992 | mso-bidi-font-size:13.0pt; |
---|
993 | font-family:"Calibri Light",sans-serif; |
---|
994 | mso-ascii-font-family:"Calibri Light"; |
---|
995 | mso-ascii-theme-font:major-latin; |
---|
996 | mso-fareast-font-family:"Times New Roman"; |
---|
997 | mso-fareast-theme-font:major-fareast; |
---|
998 | mso-hansi-font-family:"Calibri Light"; |
---|
999 | mso-hansi-theme-font:major-latin; |
---|
1000 | mso-bidi-font-family:"Times New Roman"; |
---|
1001 | mso-bidi-theme-font:major-bidi; |
---|
1002 | color:#5B9BD5; |
---|
1003 | mso-themecolor:accent1; |
---|
1004 | font-weight:bold; |
---|
1005 | font-style:italic;} |
---|
1006 | span.Heading5Char |
---|
1007 | {mso-style-name:"Heading 5 Char"; |
---|
1008 | mso-style-noshow:yes; |
---|
1009 | mso-style-priority:9; |
---|
1010 | mso-style-unhide:no; |
---|
1011 | mso-style-locked:yes; |
---|
1012 | mso-style-link:"Heading 5"; |
---|
1013 | mso-ansi-font-size:12.0pt; |
---|
1014 | mso-bidi-font-size:12.0pt; |
---|
1015 | font-family:"Times New Roman",serif; |
---|
1016 | mso-ascii-font-family:"Times New Roman"; |
---|
1017 | mso-fareast-font-family:"Times New Roman"; |
---|
1018 | mso-fareast-theme-font:minor-fareast; |
---|
1019 | mso-hansi-font-family:"Times New Roman"; |
---|
1020 | mso-bidi-font-family:"Times New Roman"; |
---|
1021 | color:#4F4FFF; |
---|
1022 | font-weight:bold;} |
---|
1023 | span.HTMLPreformattedChar |
---|
1024 | {mso-style-name:"HTML Preformatted Char"; |
---|
1025 | mso-style-noshow:yes; |
---|
1026 | mso-style-priority:99; |
---|
1027 | mso-style-unhide:no; |
---|
1028 | mso-style-locked:yes; |
---|
1029 | mso-style-link:"HTML Preformatted"; |
---|
1030 | mso-ansi-font-size:10.0pt; |
---|
1031 | mso-bidi-font-size:10.0pt; |
---|
1032 | font-family:"Courier New"; |
---|
1033 | mso-ascii-font-family:"Courier New"; |
---|
1034 | mso-fareast-font-family:"Times New Roman"; |
---|
1035 | mso-hansi-font-family:"Courier New"; |
---|
1036 | mso-bidi-font-family:"Courier New";} |
---|
1037 | p.msonormal0, li.msonormal0, div.msonormal0 |
---|
1038 | {mso-style-name:msonormal; |
---|
1039 | mso-style-noshow:yes; |
---|
1040 | mso-style-priority:99; |
---|
1041 | mso-style-unhide:no; |
---|
1042 | mso-margin-top-alt:auto; |
---|
1043 | margin-right:0in; |
---|
1044 | mso-margin-bottom-alt:auto; |
---|
1045 | margin-left:0in; |
---|
1046 | mso-pagination:widow-orphan; |
---|
1047 | font-size:12.0pt; |
---|
1048 | font-family:"Times New Roman",serif; |
---|
1049 | mso-fareast-font-family:"Times New Roman"; |
---|
1050 | mso-fareast-theme-font:minor-fareast;} |
---|
1051 | span.DocumentMapChar |
---|
1052 | {mso-style-name:"Document Map Char"; |
---|
1053 | mso-style-noshow:yes; |
---|
1054 | mso-style-priority:99; |
---|
1055 | mso-style-unhide:no; |
---|
1056 | mso-style-locked:yes; |
---|
1057 | mso-style-link:"Document Map"; |
---|
1058 | mso-ansi-font-size:8.0pt; |
---|
1059 | mso-bidi-font-size:8.0pt; |
---|
1060 | font-family:"Tahoma",sans-serif; |
---|
1061 | mso-ascii-font-family:Tahoma; |
---|
1062 | mso-fareast-font-family:"Times New Roman"; |
---|
1063 | mso-fareast-theme-font:minor-fareast; |
---|
1064 | mso-hansi-font-family:Tahoma; |
---|
1065 | mso-bidi-font-family:Tahoma;} |
---|
1066 | span.BalloonTextChar |
---|
1067 | {mso-style-name:"Balloon Text Char"; |
---|
1068 | mso-style-noshow:yes; |
---|
1069 | mso-style-priority:99; |
---|
1070 | mso-style-unhide:no; |
---|
1071 | mso-style-locked:yes; |
---|
1072 | mso-style-link:"Balloon Text"; |
---|
1073 | mso-ansi-font-size:8.0pt; |
---|
1074 | mso-bidi-font-size:8.0pt; |
---|
1075 | font-family:"Tahoma",sans-serif; |
---|
1076 | mso-ascii-font-family:Tahoma; |
---|
1077 | mso-fareast-font-family:"Times New Roman"; |
---|
1078 | mso-fareast-theme-font:minor-fareast; |
---|
1079 | mso-hansi-font-family:Tahoma; |
---|
1080 | mso-bidi-font-family:Tahoma;} |
---|
1081 | span.GSAS-IItextChar |
---|
1082 | {mso-style-name:"GSAS-II text Char"; |
---|
1083 | mso-style-unhide:no; |
---|
1084 | mso-style-locked:yes; |
---|
1085 | mso-style-link:"GSAS-II text"; |
---|
1086 | mso-ansi-font-size:12.0pt; |
---|
1087 | mso-bidi-font-size:12.0pt; |
---|
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---|
1280 | |
---|
1281 | <h1>Magnetic Structures in GSAS-II - III</h1> |
---|
1282 | |
---|
1283 | <h2>Introduction</h2> |
---|
1284 | |
---|
1285 | <p class=MsoNormal>In this and subsequent tutorials, we will show how GSAS-II |
---|
1286 | makes use of the Bilbao crystallographic server (<a |
---|
1287 | href="http://www.cryst.ehu.es/">www.cryst.ehu.es/</a>) <i style='mso-bidi-font-style: |
---|
1288 | normal'>Magnetic Symmetry and Applications</i> routine k-SUBGROUPSMAG (<a |
---|
1289 | href="http://iopscience.iop.org/0953-8984/28/28/286001"><span style='font-size: |
---|
1290 | 10.0pt;font-family:"Arial",sans-serif'>Perez-<span class=SpellE>Mato</span>, |
---|
1291 | JM; <span class=SpellE>Gallego</span>, SV; <span class=SpellE>Elcoro</span>, L; |
---|
1292 | <span class=SpellE>Tasci</span>, E and <span class=SpellE>Aroyo</span>, MI</span><span |
---|
1293 | style='font-size:10.0pt;font-family:"Arial",sans-serif;color:windowtext; |
---|
1294 | text-decoration:none;text-underline:none'><br> |
---|
1295 | </span><i><span style='font-size:10.0pt;font-family:"Arial",sans-serif'>J. of |
---|
1296 | Phys.: <span class=SpellE>Condens</span> Matter</span></i><span |
---|
1297 | style='font-size:10.0pt;font-family:"Arial",sans-serif'> (2016), <b>28</b>:28601</span></a>) |
---|
1298 | to determine a magnetic crystal structure with a non-zero propagation vector. |
---|
1299 | If you have not done so already, you may wish to do the Simple Magnetic |
---|
1300 | Structures tutorial first as it contains some background information that will |
---|
1301 | not be covered here. It is also helpful to do parts I and II of the series of |
---|
1302 | Magnetic Structures tutorials. To make this work, your computer must have an |
---|
1303 | internet connection for GSAS-II to access this site. (We will supply the |
---|
1304 | project file that results after k-SUBGROUPSMAG is called in case you lack |
---|
1305 | internet access).</p> |
---|
1306 | |
---|
1307 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shapetype |
---|
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---|
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---|
1310 | <v:stroke joinstyle="miter"/> |
---|
1311 | <v:formulas> |
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---|
1324 | </v:formulas> |
---|
1325 | <v:path o:extrusionok="f" gradientshapeok="t" o:connecttype="rect"/> |
---|
1326 | <o:lock v:ext="edit" aspectratio="t"/> |
---|
1327 | </v:shapetype><v:shape id="Picture_x0020_4" o:spid="_x0000_i1055" type="#_x0000_t75" |
---|
1328 | style='width:359.25pt;height:369.75pt;visibility:visible;mso-wrap-style:square'> |
---|
1329 | <v:imagedata src="Magnetic-III_files/image001.png" o:title=""/> |
---|
1330 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=493 |
---|
1331 | src="Magnetic-III_files/image002.gif" v:shapes="Picture_x0020_4"><![endif]></span></p> |
---|
1332 | |
---|
1333 | <p class=MsoNormal>In this example, we will determine the magnetic structure |
---|
1334 | for Ba<sub>6</sub>Co<sub>6</sub>ClO<sub>16</sub> from neutron data taken on the |
---|
1335 | D1b diffractometer (ILL, Grenoble, France) at 1.4K and λ=2.394 Å and is |
---|
1336 | based on Example 12.2 in the Jana2006 Cookbook (<span class=SpellE>Duek</span>, |
---|
1337 | et al., 2017).<span style='mso-spacerun:yes'> </span>Its magnetic structure |
---|
1338 | was originally determined by <span class=SpellE>Mentré</span>, et al. (<span |
---|
1339 | class=SpellE>Mentré</span>, O., Kauffmann, M., <span class=SpellE>Ehora</span>, |
---|
1340 | G., <span class=SpellE>Daviero-Minaud</span>, S., Abraham F. & <span |
---|
1341 | class=SpellE>Roussel</span>, P. (2008). <i>Solid State Sciences </i><b>10</b>, |
---|
1342 | 471-475). The chemical structure is P <!--[if gte msEquation 12]><m:oMath><m:acc><m:accPr><m:chr |
---|
1343 | m:val="̅"/><span style='font-family:"Cambria Math",serif;mso-ascii-font-family: |
---|
1344 | "Cambria Math";mso-hansi-font-family:"Cambria Math";font-style:italic; |
---|
1345 | mso-bidi-font-style:normal'><m:ctrlPr></m:ctrlPr></span></m:accPr><m:e><i |
---|
1346 | style='mso-bidi-font-style:normal'><span style='font-family:"Cambria Math",serif'><m:r>6</m:r></span></i></m:e></m:acc></m:oMath><![endif]--><![if !msEquation]><span |
---|
1347 | style='font-size:12.0pt;font-family:"Times New Roman",serif;mso-fareast-font-family: |
---|
1348 | "Times New Roman";mso-fareast-theme-font:minor-fareast;position:relative; |
---|
1349 | top:3.0pt;mso-text-raise:-3.0pt;mso-ansi-language:EN-US;mso-fareast-language: |
---|
1350 | EN-US;mso-bidi-language:AR-SA'><!--[if gte vml 1]><v:shape id="_x0000_i1025" |
---|
1351 | type="#_x0000_t75" style='width:6.75pt;height:14.25pt'> |
---|
1352 | <v:imagedata src="Magnetic-III_files/image036.png" o:title="" chromakey="white"/> |
---|
1353 | </v:shape><![endif]--><![if !vml]><img width=9 height=19 |
---|
1354 | src="Magnetic-III_files/image004.gif" v:shapes="_x0000_i1025"><![endif]></span><![endif]>m2 |
---|
1355 | with a= 5.64870 Å and c= 5.64870 Å. From the structure drawing above, you can |
---|
1356 | see a tetrameric string of face sharing CoO<sub>6</sub> <span class=SpellE>octahedra</span> |
---|
1357 | and a separate CoO<sub>4</sub> tetrahedron with one disordered oxygen position |
---|
1358 | and it appears to order <span class=SpellE>antiferromagnetically</span> at low |
---|
1359 | temperature. Of interest is whether both tetrahedral and octahedral Co atoms |
---|
1360 | carry magnetic moments and how the moments are arranged. As we will see, in |
---|
1361 | this case the magnetic space group is a subgroup of the parent chemical one |
---|
1362 | after a doubling of the c-axis. We will use k-SUBGROUPSMAG to help sort this |
---|
1363 | out.</p> |
---|
1364 | |
---|
1365 | <p class=MsoNormal><o:p> </o:p></p> |
---|
1366 | |
---|
1367 | <p class=MsoNormal>If you have not done so already, start GSAS-II (make sure |
---|
1368 | about the internet connection!).</p> |
---|
1369 | |
---|
1370 | <h3>Step 1. Read in the data file</h3> |
---|
1371 | |
---|
1372 | <p class=MsoListParagraphCxSpFirst style='text-indent:-.25in;mso-list:l1 level1 lfo2'><![if !supportLists]><span |
---|
1373 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
1374 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Use |
---|
1375 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1376 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1377 | minor-latin'>Import/Powder Data/from TOPAS <span class=SpellE>xye</span> or |
---|
1378 | Fit2D chi file</span></b> menu item to read the data file into the current |
---|
1379 | GSAS-II project. Because you used <span style='mso-fareast-font-family:Calibri; |
---|
1380 | mso-fareast-theme-font:minor-latin'>the </span><b style='mso-bidi-font-weight: |
---|
1381 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1382 | minor-latin;mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin; |
---|
1383 | mso-hansi-theme-font:minor-latin'>Help/Download tutorial</span></b><span |
---|
1384 | style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'> |
---|
1385 | menu entry to open this page and downloaded the exercise files (recommended), |
---|
1386 | then the </span><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1387 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-fareast-font-family: |
---|
1388 | Calibri;mso-fareast-theme-font:minor-latin;mso-hansi-theme-font:minor-latin'>Magnetic-III/data/...</span></b><span |
---|
1389 | style='mso-fareast-font-family:Calibri;mso-fareast-theme-font:minor-latin'> |
---|
1390 | entry will bring you to the location where the files have been downloaded. (It |
---|
1391 | is also possible to download them manually from <a |
---|
1392 | href="https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-III/data/">https://subversion.xray.aps.anl.gov/pyGSAS/Tutorials/Magnetic-III/data/</a>. |
---|
1393 | In this case you will need to navigate to the download location manually.)<br> |
---|
1394 | For this tutorial the extension on the data file is the expected one, so it |
---|
1395 | should be immediately visible.</span></p> |
---|
1396 | |
---|
1397 | <p class=MsoListParagraphCxSpMiddle style='text-indent:-.25in;mso-list:l1 level1 lfo2'><![if !supportLists]><span |
---|
1398 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>2.<span |
---|
1399 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Select |
---|
1400 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1401 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1402 | minor-latin'>Ba6Co6.xye</span></b><span style='font-family:"Calibri",sans-serif; |
---|
1403 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1404 | minor-latin'> data</span> file in the first dialog and press <b |
---|
1405 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1406 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1407 | minor-latin'>Open</span></b>. There will be a Dialog box asking <span |
---|
1408 | class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1409 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1410 | minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
1411 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1412 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1413 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
1414 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1415 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1416 | minor-latin'>Yes</span></b></span> button to proceed.</p> |
---|
1417 | |
---|
1418 | <p class=MsoListParagraphCxSpMiddle style='text-indent:-.25in;mso-list:l1 level1 lfo2'><![if !supportLists]><span |
---|
1419 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>3.<span |
---|
1420 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Since |
---|
1421 | this data file does not define an instrument parameter file, a file dialog will |
---|
1422 | appear for you to select the correct instrument parameter file. Select <b |
---|
1423 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1424 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1425 | minor-latin'>D1B.PRM</span></b>; you may have to change the file type in the |
---|
1426 | file selection Dialog box to <b style='mso-bidi-font-weight:normal'><span |
---|
1427 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1428 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>GSAS <span |
---|
1429 | class=SpellE>iparm</span> file</span></b> to see it. At this point the <b |
---|
1430 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1431 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1432 | minor-latin'>GSAS-II data tree</span></b> window will have several entries</p> |
---|
1433 | |
---|
1434 | <p class=MsoListParagraphCxSpLast><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1435 | id="Picture_x0020_5" o:spid="_x0000_i1054" type="#_x0000_t75" style='width:324.75pt; |
---|
1436 | height:199.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1437 | <v:imagedata src="Magnetic-III_files/image003.png" o:title=""/> |
---|
1438 | </v:shape><![endif]--><![if !vml]><img border=0 width=433 height=266 |
---|
1439 | src="Magnetic-III_files/image006.gif" v:shapes="Picture_x0020_5"><![endif]></span></p> |
---|
1440 | |
---|
1441 | <p class=MsoNormal style='margin-left:.5in'><span class=GramE>and</span> the |
---|
1442 | plot window will show the powder pattern</p> |
---|
1443 | |
---|
1444 | <p class=MsoNormal style='margin-left:.5in'><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1445 | id="Picture_x0020_6" o:spid="_x0000_i1053" type="#_x0000_t75" style='width:324.75pt; |
---|
1446 | height:334.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1447 | <v:imagedata src="Magnetic-III_files/image005.png" o:title=""/> |
---|
1448 | </v:shape><![endif]--><![if !vml]><img border=0 width=433 height=446 |
---|
1449 | src="Magnetic-III_files/image008.gif" v:shapes="Picture_x0020_6"><![endif]></span></p> |
---|
1450 | |
---|
1451 | <p class=MsoNormal style='margin-left:.5in'>We will use the default limits.</p> |
---|
1452 | |
---|
1453 | <h3>Step 2. Read in the chemical structure for Ba<sub>6</sub>Co<sub>6</sub>ClO<sub>16</sub></h3> |
---|
1454 | |
---|
1455 | <p class=MsoListParagraphCxSpFirst style='text-indent:-.25in;mso-list:l0 level1 lfo4'><![if !supportLists]><span |
---|
1456 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>1.<span |
---|
1457 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Use |
---|
1458 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1459 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1460 | minor-latin'>Import/Phase/from CIF file</span></b> menu item to read the phase |
---|
1461 | information for Ba<sub>6</sub>Co<sub>6</sub>ClO<sub>16</sub> into the current |
---|
1462 | GSAS-II project. The file you want is <b style='mso-bidi-font-weight:normal'><span |
---|
1463 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1464 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6.cif</span></b> |
---|
1465 | and should be in your current directory. Other submenu items can read phase |
---|
1466 | information in other formats.<span style='mso-spacerun:yes'> </span></p> |
---|
1467 | |
---|
1468 | <p class=MsoListParagraphCxSpMiddle style='text-indent:-.25in;mso-list:l0 level1 lfo4'><![if !supportLists]><span |
---|
1469 | style='mso-fareast-font-family:"Times New Roman"'><span style='mso-list:Ignore'>2.<span |
---|
1470 | style='font:7.0pt "Times New Roman"'> </span></span></span><![endif]>Select |
---|
1471 | the <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1472 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1473 | minor-latin'>Ba6Co6.cif </span></b><span style='font-family:"Calibri",sans-serif; |
---|
1474 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1475 | minor-latin'>data</span> file in the first dialog and press <b |
---|
1476 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1477 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1478 | minor-latin'>Open</span></b>. There will be a Dialog box asking <span |
---|
1479 | class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1480 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1481 | minor-latin;mso-bidi-theme-font:minor-latin'>Is</span></b></span><b |
---|
1482 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1483 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1484 | minor-latin'> this the file you want?</span></b> Press <span class=GramE><b |
---|
1485 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1486 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1487 | minor-latin'>Yes</span></b></span> button to proceed. You will get the |
---|
1488 | opportunity to change the phase name next (I changed it to <b style='mso-bidi-font-weight: |
---|
1489 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1490 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6</span></b>); |
---|
1491 | press <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1492 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1493 | minor-latin'>OK</span></b> to continue.</p> |
---|
1494 | |
---|
1495 | <p class=MsoListParagraphCxSpLast>Next is the histogram selection window; this |
---|
1496 | connects the phase to the data so it can be used in subsequent calculations.<span |
---|
1497 | style='mso-no-proof:yes'> </span>Select the histogram (or press <b |
---|
1498 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1499 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1500 | minor-latin'>Set All</span></b>) and press <b style='mso-bidi-font-weight:normal'><span |
---|
1501 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1502 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
1503 | The General tab for the phase is shown next<br> |
---|
1504 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_7" |
---|
1505 | o:spid="_x0000_i1052" type="#_x0000_t75" style='width:322.5pt;height:176.25pt; |
---|
1506 | visibility:visible;mso-wrap-style:square'> |
---|
1507 | <v:imagedata src="Magnetic-III_files/image007.png" o:title=""/> |
---|
1508 | </v:shape><![endif]--><![if !vml]><img border=0 width=430 height=235 |
---|
1509 | src="Magnetic-III_files/image010.gif" v:shapes="Picture_x0020_7"><![endif]></span></p> |
---|
1510 | |
---|
1511 | <h3>Step 3. Check powder pattern indexing</h3> |
---|
1512 | |
---|
1513 | <p class=MsoNormal>Here the objective is to determine how the reflection positions |
---|
1514 | generated from the chemical (nuclear) crystal structure lattice match up with |
---|
1515 | the peaks observed for this antiferromagnet. </p> |
---|
1516 | |
---|
1517 | <p class=MsoNormal>Select <b style='mso-bidi-font-weight:normal'><span |
---|
1518 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1519 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Unit Cells |
---|
1520 | List</span></b> from the tree entries under the histogram (begins with PWDR); |
---|
1521 | the Indexing controls will be shown<br> |
---|
1522 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_8" |
---|
1523 | o:spid="_x0000_i1051" type="#_x0000_t75" style='width:359.25pt;height:121.5pt; |
---|
1524 | visibility:visible;mso-wrap-style:square'> |
---|
1525 | <v:imagedata src="Magnetic-III_files/image009.png" o:title=""/> |
---|
1526 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=162 |
---|
1527 | src="Magnetic-III_files/image012.gif" v:shapes="Picture_x0020_8"><![endif]></span></p> |
---|
1528 | |
---|
1529 | <p class=MsoNormal>This can use lattice parameters & space groups to |
---|
1530 | generate expected reflection positions to check against the peaks in the powder |
---|
1531 | pattern. One could then enter <span class=SpellE>Bravais</span> lattice, choose |
---|
1532 | space group & enter lattice parameters by hand, but the easy way is to use |
---|
1533 | the chemical lattice directly. Do <b style='mso-bidi-font-weight:normal'><span |
---|
1534 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1535 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Cell |
---|
1536 | Index/Refine/Load Cell</span></b> from the menu; a Phase selection box will |
---|
1537 | appear with only one choice (<b style='mso-bidi-font-weight:normal'><span |
---|
1538 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1539 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6</span></b>). |
---|
1540 | This was taken from the Phases present in this project; there could be more |
---|
1541 | than one depending on what you loaded/created earlier. The <b style='mso-bidi-font-weight: |
---|
1542 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1543 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Import</span></b> |
---|
1544 | menu item allows you to get lattice information from any one of the other phase |
---|
1545 | containing files known to GSAS-II. Press <b style='mso-bidi-font-weight:normal'><span |
---|
1546 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1547 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> |
---|
1548 | and the Indexing controls will be change<br> |
---|
1549 | <span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_9" |
---|
1550 | o:spid="_x0000_i1050" type="#_x0000_t75" style='width:358.5pt;height:114pt; |
---|
1551 | visibility:visible;mso-wrap-style:square'> |
---|
1552 | <v:imagedata src="Magnetic-III_files/image011.png" o:title=""/> |
---|
1553 | </v:shape><![endif]--><![if !vml]><img border=0 width=478 height=152 |
---|
1554 | src="Magnetic-III_files/image014.gif" v:shapes="Picture_x0020_9"><![endif]></span></p> |
---|
1555 | |
---|
1556 | <p class=MsoNormal><span class=GramE>showing</span> the lattice constants for |
---|
1557 | Ba<sub>6</sub>Co<sub>6</sub>ClO<sub>16</sub> you had obtained from the <span |
---|
1558 | class=SpellE>cif</span> file and the powder pattern will change showing the |
---|
1559 | lines for P <!--[if gte msEquation 12]><m:oMath><m:acc><m:accPr><m:chr m:val="̅"/><span |
---|
1560 | style='font-family:"Cambria Math",serif;mso-ascii-font-family:"Cambria Math"; |
---|
1561 | mso-hansi-font-family:"Cambria Math";font-style:italic;mso-bidi-font-style: |
---|
1562 | normal'><m:ctrlPr></m:ctrlPr></span></m:accPr><m:e><i style='mso-bidi-font-style: |
---|
1563 | normal'><span style='font-family:"Cambria Math",serif'><m:r>6</m:r></span></i></m:e></m:acc></m:oMath><![endif]--><![if !msEquation]><span |
---|
1564 | style='font-size:12.0pt;font-family:"Times New Roman",serif;mso-fareast-font-family: |
---|
1565 | "Times New Roman";mso-fareast-theme-font:minor-fareast;position:relative; |
---|
1566 | top:3.0pt;mso-text-raise:-3.0pt;mso-ansi-language:EN-US;mso-fareast-language: |
---|
1567 | EN-US;mso-bidi-language:AR-SA'><!--[if gte vml 1]><v:shape id="_x0000_i1025" |
---|
1568 | type="#_x0000_t75" style='width:6.75pt;height:14.25pt'> |
---|
1569 | <v:imagedata src="Magnetic-III_files/image036.png" o:title="" chromakey="white"/> |
---|
1570 | </v:shape><![endif]--><![if !vml]><img width=9 height=19 |
---|
1571 | src="Magnetic-III_files/image004.gif" v:shapes="_x0000_i1025"><![endif]></span><![endif]>m2 |
---|
1572 | and those lattice parameters. </p> |
---|
1573 | |
---|
1574 | <p class=MsoNormal><b style='mso-bidi-font-weight:normal'><span |
---|
1575 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1576 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin;mso-no-proof: |
---|
1577 | yes'><!--[if gte vml 1]><v:shape id="Picture_x0020_10" o:spid="_x0000_i1049" |
---|
1578 | type="#_x0000_t75" style='width:355.5pt;height:366pt;visibility:visible; |
---|
1579 | mso-wrap-style:square'> |
---|
1580 | <v:imagedata src="Magnetic-III_files/image013.png" o:title=""/> |
---|
1581 | </v:shape><![endif]--><![if !vml]><img border=0 width=474 height=488 |
---|
1582 | src="Magnetic-III_files/image016.gif" v:shapes="Picture_x0020_10"><![endif]></span></b></p> |
---|
1583 | |
---|
1584 | <p class=MsoNormal>Ive expanded & shifted the plot slightly to see that a |
---|
1585 | number of peaks are not indexed by this space group (NB: P <!--[if gte msEquation 12]><m:oMath><m:acc><m:accPr><m:chr |
---|
1586 | m:val="̅"/><span style='font-family:"Cambria Math",serif;mso-ascii-font-family: |
---|
1587 | "Cambria Math";mso-hansi-font-family:"Cambria Math";font-style:italic; |
---|
1588 | mso-bidi-font-style:normal'><m:ctrlPr></m:ctrlPr></span></m:accPr><m:e><i |
---|
1589 | style='mso-bidi-font-style:normal'><span style='font-family:"Cambria Math",serif'><m:r>6</m:r></span></i></m:e></m:acc></m:oMath><![endif]--><![if !msEquation]><span |
---|
1590 | style='font-size:12.0pt;font-family:"Times New Roman",serif;mso-fareast-font-family: |
---|
1591 | "Times New Roman";mso-fareast-theme-font:minor-fareast;position:relative; |
---|
1592 | top:3.0pt;mso-text-raise:-3.0pt;mso-ansi-language:EN-US;mso-fareast-language: |
---|
1593 | EN-US;mso-bidi-language:AR-SA'><!--[if gte vml 1]><v:shape id="_x0000_i1025" |
---|
1594 | type="#_x0000_t75" style='width:6.75pt;height:14.25pt'> |
---|
1595 | <v:imagedata src="Magnetic-III_files/image036.png" o:title="" chromakey="white"/> |
---|
1596 | </v:shape><![endif]--><![if !vml]><img width=9 height=19 |
---|
1597 | src="Magnetic-III_files/image004.gif" v:shapes="_x0000_i1025"><![endif]></span><![endif]>m2 |
---|
1598 | lacks space group extinctions so there is no need to change it as in previous |
---|
1599 | tutorials) and lattice. Antiferromagnetic ordering may force an increase in the |
---|
1600 | unit cell dimensions (usually a doubling or tripling of one or more cell |
---|
1601 | dimensions) or by removing a space group centering. The effect on reciprocal |
---|
1602 | space of this is the appearance of extra reflections at positions that are half |
---|
1603 | (or third) way between those expected from the parent lattice; they are |
---|
1604 | described by a propagation vector (<span class=SpellE>kx<span class=GramE>,ky,kz</span></span>) |
---|
1605 | consisting of fractions (1/2, 1/3, etc.). To explore this possibility here, we |
---|
1606 | need to try doubling either <span class=GramE>a or</span> c axis and see the |
---|
1607 | effect on the powder pattern indexing. To try a-axis doubling add <b |
---|
1608 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1609 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1610 | minor-latin'>*2</span></b> to the end of the a-axis value; it will quickly |
---|
1611 | change to</p> |
---|
1612 | |
---|
1613 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1614 | id="Picture_x0020_11" o:spid="_x0000_i1048" type="#_x0000_t75" style='width:357.75pt; |
---|
1615 | height:114pt;visibility:visible;mso-wrap-style:square'> |
---|
1616 | <v:imagedata src="Magnetic-III_files/image015.png" o:title=""/> |
---|
1617 | </v:shape><![endif]--><![if !vml]><img border=0 width=477 height=152 |
---|
1618 | src="Magnetic-III_files/image018.gif" v:shapes="Picture_x0020_11"><![endif]></span></p> |
---|
1619 | |
---|
1620 | <p class=MsoNormal>Notice that the a-axis (11.2974) is now twice the original |
---|
1621 | value (5.6487) and the plot shows the new indexing</p> |
---|
1622 | |
---|
1623 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1624 | id="Picture_x0020_12" o:spid="_x0000_i1047" type="#_x0000_t75" style='width:357pt; |
---|
1625 | height:367.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1626 | <v:imagedata src="Magnetic-III_files/image017.png" o:title=""/> |
---|
1627 | </v:shape><![endif]--><![if !vml]><img border=0 width=476 height=490 |
---|
1628 | src="Magnetic-III_files/image020.gif" v:shapes="Picture_x0020_12"><![endif]></span></p> |
---|
1629 | |
---|
1630 | <p class=MsoNormal>Clearly that did not index all the observed peaks, so we |
---|
1631 | want to try doubling the c-axis next. First add <b style='mso-bidi-font-weight: |
---|
1632 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1633 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>/2</span></b> |
---|
1634 | to the end of the a-axis value; it will quickly change back to the old value |
---|
1635 | (and redraw the plot). Then add <b style='mso-bidi-font-weight:normal'><span |
---|
1636 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1637 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>*2</span></b> |
---|
1638 | to the end of the c-axis value; it will change to 28.9316 and the plot shows</p> |
---|
1639 | |
---|
1640 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1641 | id="Picture_x0020_13" o:spid="_x0000_i1046" type="#_x0000_t75" style='width:5in; |
---|
1642 | height:370.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1643 | <v:imagedata src="Magnetic-III_files/image019.png" o:title=""/> |
---|
1644 | </v:shape><![endif]--><![if !vml]><img border=0 width=480 height=494 |
---|
1645 | src="Magnetic-III_files/image022.gif" v:shapes="Picture_x0020_13"><![endif]></span></p> |
---|
1646 | |
---|
1647 | <p class=MsoNormal>In this case every powder peak is indexed so a doubling of |
---|
1648 | the c-axis is required and thus the propagation vector is (0<span class=GramE>,0,1</span>/2); |
---|
1649 | just the reciprocal of the required axis operation. Add a<span |
---|
1650 | style='mso-spacerun:yes'> </span><b style='mso-bidi-font-weight:normal'><span |
---|
1651 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1652 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>/2</span></b> |
---|
1653 | to the c-axis entry or else redo the <b style='mso-bidi-font-weight:normal'><span |
---|
1654 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1655 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Load cell</span></b> |
---|
1656 | operation, because the next step requires the chemical cell and space group to |
---|
1657 | be entered here (<b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1658 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1659 | minor-latin;mso-bidi-theme-font:minor-latin'>VERY IMPORTANT!</span></b>)</p> |
---|
1660 | |
---|
1661 | <h3>Step 4. Run k-SUBGROUPSMAG</h3> |
---|
1662 | |
---|
1663 | <p class=MsoNormal>In this next step, you will be accessing the Bilbao |
---|
1664 | crystallographic server so you must be connected to the internet. In the Cell |
---|
1665 | Index/Refine menu select <b style='mso-bidi-font-weight:normal'><span |
---|
1666 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1667 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Run |
---|
1668 | k-SUBGROUPSMAG</span></b>; a small popup dialog will appear</p> |
---|
1669 | |
---|
1670 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1671 | id="Picture_x0020_14" o:spid="_x0000_i1045" type="#_x0000_t75" style='width:166.5pt; |
---|
1672 | height:278.25pt;visibility:visible;mso-wrap-style:square'> |
---|
1673 | <v:imagedata src="Magnetic-III_files/image021.png" o:title=""/> |
---|
1674 | </v:shape><![endif]--><![if !vml]><img border=0 width=222 height=371 |
---|
1675 | src="Magnetic-III_files/image024.gif" v:shapes="Picture_x0020_14"><![endif]></span></p> |
---|
1676 | |
---|
1677 | <p class=MsoNormal>These are the controls for running the Bilbao routine. The |
---|
1678 | space group (P <!--[if gte msEquation 12]><m:oMath><m:acc><m:accPr><m:chr m:val="̅"/><span |
---|
1679 | style='font-family:"Cambria Math",serif;mso-ascii-font-family:"Cambria Math"; |
---|
1680 | mso-hansi-font-family:"Cambria Math";font-style:italic;mso-bidi-font-style: |
---|
1681 | normal'><m:ctrlPr></m:ctrlPr></span></m:accPr><m:e><i style='mso-bidi-font-style: |
---|
1682 | normal'><span style='font-family:"Cambria Math",serif'><m:r>6</m:r></span></i></m:e></m:acc></m:oMath><![endif]--><![if !msEquation]><span |
---|
1683 | style='font-size:12.0pt;font-family:"Times New Roman",serif;mso-fareast-font-family: |
---|
1684 | "Times New Roman";mso-fareast-theme-font:minor-fareast;position:relative; |
---|
1685 | top:3.0pt;mso-text-raise:-3.0pt;mso-ansi-language:EN-US;mso-fareast-language: |
---|
1686 | EN-US;mso-bidi-language:AR-SA'><!--[if gte vml 1]><v:shape id="_x0000_i1025" |
---|
1687 | type="#_x0000_t75" style='width:6.75pt;height:14.25pt'> |
---|
1688 | <v:imagedata src="Magnetic-III_files/image036.png" o:title="" chromakey="white"/> |
---|
1689 | </v:shape><![endif]--><![if !vml]><img width=9 height=19 |
---|
1690 | src="Magnetic-III_files/image004.gif" v:shapes="_x0000_i1025"><![endif]></span><![endif]>m2) |
---|
1691 | is taken from the Space Group entry on the Unit Cells window. Since we just |
---|
1692 | discovered the propagation vector as (0<span class=GramE>,0,1</span>/2) change <b |
---|
1693 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1694 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1695 | minor-latin'>kz1</span></b> to <b style='mso-bidi-font-weight:normal'><span |
---|
1696 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1697 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>œ</span></b>. |
---|
1698 | The available selections were determined by surveying the known magnetic |
---|
1699 | crystal structures given in the Bilbao Magnetic Structures database. Select <b |
---|
1700 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1701 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1702 | minor-latin'>Co</span></b> for the <b style='mso-bidi-font-weight:normal'><span |
---|
1703 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1704 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>test for mag |
---|
1705 | atoms</span></b> and then press <b style='mso-bidi-font-weight:normal'><span |
---|
1706 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1707 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
1708 | A popup dialog will appear reminding you how to cite the Bilbao routine in any |
---|
1709 | paper you write using this facility.</p> |
---|
1710 | |
---|
1711 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1712 | id="Picture_x0020_15" o:spid="_x0000_i1044" type="#_x0000_t75" style='width:357.75pt; |
---|
1713 | height:123.75pt;visibility:visible;mso-wrap-style:square'> |
---|
1714 | <v:imagedata src="Magnetic-III_files/image023.png" o:title=""/> |
---|
1715 | </v:shape><![endif]--><![if !vml]><img border=0 width=477 height=165 |
---|
1716 | src="Magnetic-III_files/image026.gif" v:shapes="Picture_x0020_15"><![endif]></span></p> |
---|
1717 | |
---|
1718 | <p class=MsoNormal>Press <b style='mso-bidi-font-weight:normal'><span |
---|
1719 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1720 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ok</span></b>, |
---|
1721 | the nag note will also appear on the console and after a pause, the console |
---|
1722 | will show request OK indicating that the Bilbao site has responded with some |
---|
1723 | results. GSAS-II will next display a File Dialog asking for a project name to |
---|
1724 | save this project; change the directory to a useful place for your work on this |
---|
1725 | tutorial and give the project a name; I used <b style='mso-bidi-font-weight: |
---|
1726 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1727 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6.<o:p></o:p></span></b></p> |
---|
1728 | |
---|
1729 | <p class=MsoNormal>The GSAS-II data window will display the results from |
---|
1730 | k-SUBGROUPSMAG. (If k-SUBGROUPSMAG failed because you lack internet access, |
---|
1731 | this file is located in the same location as the powder data and <span |
---|
1732 | class=SpellE>cif</span> files used above were found. Do <b style='mso-bidi-font-weight: |
---|
1733 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1734 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>File/Open |
---|
1735 | Project</span></b> from the main menu to access it as <b style='mso-bidi-font-weight: |
---|
1736 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1737 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6.gpx</span></b>). |
---|
1738 | The Unit Cells List window will show the results</p> |
---|
1739 | |
---|
1740 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1741 | id="Picture_x0020_16" o:spid="_x0000_i1043" type="#_x0000_t75" style='width:362.25pt; |
---|
1742 | height:192pt;visibility:visible;mso-wrap-style:square'> |
---|
1743 | <v:imagedata src="Magnetic-III_files/image025.png" o:title=""/> |
---|
1744 | </v:shape><![endif]--><![if !vml]><img border=0 width=483 height=256 |
---|
1745 | src="Magnetic-III_files/image028.gif" v:shapes="Picture_x0020_16"><![endif]></span></p> |
---|
1746 | |
---|
1747 | <p class=MsoNormal>Use the <b style='mso-bidi-font-weight:normal'><span |
---|
1748 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1749 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Try</span></b> |
---|
1750 | on the first two entries; they both index every reflection. The two seem |
---|
1751 | identical except for the translation vector. Double click the row number for |
---|
1752 | the 1<sup>st</sup> one; a popup will appear</p> |
---|
1753 | |
---|
1754 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1755 | id="Picture_x0020_17" o:spid="_x0000_i1042" type="#_x0000_t75" style='width:304.5pt; |
---|
1756 | height:329.25pt;visibility:visible;mso-wrap-style:square'> |
---|
1757 | <v:imagedata src="Magnetic-III_files/image027.png" o:title=""/> |
---|
1758 | </v:shape><![endif]--><![if !vml]><img border=0 width=406 height=439 |
---|
1759 | src="Magnetic-III_files/image030.gif" v:shapes="Picture_x0020_17"><![endif]></span></p> |
---|
1760 | |
---|
1761 | <p class=MsoNormal>These are the magnetic symmetry operations for P<sub>c</sub> |
---|
1762 | -6 c 2. The subscript c on the lattice symbol indicates the c-axis magnetic |
---|
1763 | centering operation; see the entry <b style='mso-bidi-font-weight:normal'><span |
---|
1764 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1765 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>for (0<span |
---|
1766 | class=GramE>,0,1</span>/2)+1</span></b>. The list of operators below it are |
---|
1767 | in red to indicate the spin inversion is applied for all of them. The Print Ops |
---|
1768 | button makes a full list on the console; these can be cut & pasted into |
---|
1769 | other programs is needed. Press <b style='mso-bidi-font-weight:normal'><span |
---|
1770 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1771 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b>. |
---|
1772 | Since the 1<sup>st</sup> two solutions seem reasonable, well try these.</p> |
---|
1773 | |
---|
1774 | <h3>Step 5. Select 1<sup>st</sup> magnetic structure</h3> |
---|
1775 | |
---|
1776 | <p class=MsoNormal>Select the <b style='mso-bidi-font-weight:normal'><span |
---|
1777 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1778 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6</span></b> |
---|
1779 | phase from the GSAS-II data tree (under Phases). The General tab is shown for |
---|
1780 | this nuclear phase.</p> |
---|
1781 | |
---|
1782 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1783 | id="Picture_x0020_18" o:spid="_x0000_i1041" type="#_x0000_t75" style='width:359.25pt; |
---|
1784 | height:184.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1785 | <v:imagedata src="Magnetic-III_files/image029.png" o:title=""/> |
---|
1786 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=246 |
---|
1787 | src="Magnetic-III_files/image032.gif" v:shapes="Picture_x0020_18"><![endif]></span></p> |
---|
1788 | |
---|
1789 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
1790 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1791 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Compute/Select |
---|
1792 | magnetic phase</span></b>; that will make a small popup dialog</p> |
---|
1793 | |
---|
1794 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1795 | id="Picture_x0020_19" o:spid="_x0000_i1040" type="#_x0000_t75" style='width:222.75pt; |
---|
1796 | height:222.75pt;visibility:visible;mso-wrap-style:square'> |
---|
1797 | <v:imagedata src="Magnetic-III_files/image031.png" o:title=""/> |
---|
1798 | </v:shape><![endif]--><![if !vml]><img border=0 width=297 height=297 |
---|
1799 | src="Magnetic-III_files/image034.gif" v:shapes="Picture_x0020_19"><![endif]></span></p> |
---|
1800 | |
---|
1801 | <p class=MsoNormal>This shows all magnetic phases that were marked <span |
---|
1802 | class=GramE>Keep</span> in the Unit Cells List; for each you see the |
---|
1803 | transformation and vector (the first two results will have the same space group |
---|
1804 | but are different translations). Select the 1<sup>st</sup> one and press <b |
---|
1805 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1806 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1807 | minor-latin'>OK</span></b>; a new popup dialog will appear.</p> |
---|
1808 | |
---|
1809 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1810 | id="Picture_x0020_20" o:spid="_x0000_i1039" type="#_x0000_t75" style='width:283.5pt; |
---|
1811 | height:123.75pt;visibility:visible;mso-wrap-style:square'> |
---|
1812 | <v:imagedata src="Magnetic-III_files/image033.png" o:title=""/> |
---|
1813 | </v:shape><![endif]--><![if !vml]><img border=0 width=378 height=165 |
---|
1814 | src="Magnetic-III_files/image038.gif" v:shapes="Picture_x0020_20"><![endif]></span></p> |
---|
1815 | |
---|
1816 | <p class=MsoNormal>Since the chemical phase had three Co atoms, having three |
---|
1817 | magnetic ones is no surprise. All have a possible magnetic moment; all <span |
---|
1818 | class=SpellE>Mz</span> only. Press <span class=GramE><b style='mso-bidi-font-weight: |
---|
1819 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1820 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Yes</span></b></span> |
---|
1821 | to use it. The project will be saved first, then a file dialog box will appear |
---|
1822 | offering a project name for this magnetic structure. It is named with the |
---|
1823 | number from the space group list (<b style='mso-bidi-font-weight:normal'><span |
---|
1824 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1825 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6 mag_1.gpx</span></b>); |
---|
1826 | press <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1827 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1828 | minor-latin'>Save.</span></b> The new project will be opened to the General tab |
---|
1829 | for the P<sub>c</sub> <!--[if gte msEquation 12]><m:oMath><m:acc><m:accPr><m:chr |
---|
1830 | m:val="̅"/><span style='font-family:"Cambria Math",serif;mso-ascii-font-family: |
---|
1831 | "Cambria Math";mso-hansi-font-family:"Cambria Math";font-style:italic; |
---|
1832 | mso-bidi-font-style:normal'><m:ctrlPr></m:ctrlPr></span></m:accPr><m:e><i |
---|
1833 | style='mso-bidi-font-style:normal'><span style='font-family:"Cambria Math",serif'><m:r>6</m:r></span></i></m:e></m:acc></m:oMath><![endif]--><![if !msEquation]><span |
---|
1834 | style='font-size:12.0pt;font-family:"Times New Roman",serif;mso-fareast-font-family: |
---|
1835 | "Times New Roman";mso-fareast-theme-font:minor-fareast;position:relative; |
---|
1836 | top:3.0pt;mso-text-raise:-3.0pt;mso-ansi-language:EN-US;mso-fareast-language: |
---|
1837 | EN-US;mso-bidi-language:AR-SA'><!--[if gte vml 1]><v:shape id="_x0000_i1025" |
---|
1838 | type="#_x0000_t75" style='width:6.75pt;height:14.25pt'> |
---|
1839 | <v:imagedata src="Magnetic-III_files/image036.png" o:title="" chromakey="white"/> |
---|
1840 | </v:shape><![endif]--><![if !vml]><img width=9 height=19 |
---|
1841 | src="Magnetic-III_files/image004.gif" v:shapes="_x0000_i1025"><![endif]></span><![endif]>m2 |
---|
1842 | magnetic phase just created.</p> |
---|
1843 | |
---|
1844 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1845 | id="Picture_x0020_21" o:spid="_x0000_i1038" type="#_x0000_t75" style='width:468pt; |
---|
1846 | height:247.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1847 | <v:imagedata src="Magnetic-III_files/image037.png" o:title=""/> |
---|
1848 | </v:shape><![endif]--><![if !vml]><img border=0 width=624 height=330 |
---|
1849 | src="Magnetic-III_files/image040.gif" v:shapes="Picture_x0020_21"><![endif]></span></p> |
---|
1850 | |
---|
1851 | <p class=MsoNormal>Select Atoms, enter <b style='mso-bidi-font-weight:normal'><span |
---|
1852 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1853 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1.0</span></b> |
---|
1854 | for all three Co atoms <span class=SpellE>Mz</span> values. Then go to Draw |
---|
1855 | Atoms, select them all and do <span class=GramE><b style='mso-bidi-font-weight: |
---|
1856 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1857 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Edit</span></b></span><b |
---|
1858 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1859 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1860 | minor-latin'> Figure/Fill unit cell</span></b>; youll see this |
---|
1861 | antiferromagnetic structure</p> |
---|
1862 | |
---|
1863 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1864 | id="Picture_x0020_22" o:spid="_x0000_i1037" type="#_x0000_t75" style='width:340.5pt; |
---|
1865 | height:9in;visibility:visible;mso-wrap-style:square'> |
---|
1866 | <v:imagedata src="Magnetic-III_files/image039.png" o:title=""/> |
---|
1867 | </v:shape><![endif]--><![if !vml]><img border=0 width=454 height=864 |
---|
1868 | src="Magnetic-III_files/image042.gif" v:shapes="Picture_x0020_22"><![endif]></span></p> |
---|
1869 | |
---|
1870 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
1871 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1872 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine |
---|
1873 | </span></b>for the initial refinement. An error popup will show</p> |
---|
1874 | |
---|
1875 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1876 | id="Picture_x0020_23" o:spid="_x0000_i1036" type="#_x0000_t75" style='width:363.75pt; |
---|
1877 | height:123pt;visibility:visible;mso-wrap-style:square'> |
---|
1878 | <v:imagedata src="Magnetic-III_files/image041.png" o:title=""/> |
---|
1879 | </v:shape><![endif]--><![if !vml]><img border=0 width=485 height=164 |
---|
1880 | src="Magnetic-III_files/image044.gif" v:shapes="Picture_x0020_23"><![endif]></span></p> |
---|
1881 | |
---|
1882 | <p class=MsoNormal>This is similar to what happened in the previous tutorial |
---|
1883 | (and is a bug). Press <b style='mso-bidi-font-weight:normal'><span |
---|
1884 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1885 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>OK</span></b> |
---|
1886 | & go to the Constraints entry; well see this same message again. Press <b |
---|
1887 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1888 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1889 | minor-latin'>OK</span></b> and the constraints will show</p> |
---|
1890 | |
---|
1891 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1892 | id="Picture_x0020_24" o:spid="_x0000_i1035" type="#_x0000_t75" style='width:361.5pt; |
---|
1893 | height:269.25pt;visibility:visible;mso-wrap-style:square'> |
---|
1894 | <v:imagedata src="Magnetic-III_files/image043.png" o:title=""/> |
---|
1895 | </v:shape><![endif]--><![if !vml]><img border=0 width=482 height=359 |
---|
1896 | src="Magnetic-III_files/image046.gif" v:shapes="Picture_x0020_24"><![endif]></span></p> |
---|
1897 | |
---|
1898 | <p class=MsoNormal>The actual conflict is the 2<sup>nd</sup> from last one <b |
---|
1899 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1900 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1901 | minor-latin'>EQUIV 1::A0 = 1.000*0::A0</span></b> which is a duplicate of the |
---|
1902 | one above it. <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1903 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1904 | minor-latin;mso-bidi-theme-font:minor-latin'>Delete</span></b> it; the error is |
---|
1905 | cleared</p> |
---|
1906 | |
---|
1907 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1908 | id="Picture_x0020_25" o:spid="_x0000_i1034" type="#_x0000_t75" style='width:359.25pt; |
---|
1909 | height:267.75pt;visibility:visible;mso-wrap-style:square'> |
---|
1910 | <v:imagedata src="Magnetic-III_files/image045.png" o:title=""/> |
---|
1911 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=357 |
---|
1912 | src="Magnetic-III_files/image048.gif" v:shapes="Picture_x0020_25"><![endif]></span></p> |
---|
1913 | |
---|
1914 | <p class=MsoNormal>Now try <b style='mso-bidi-font-weight:normal'><span |
---|
1915 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1916 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
1917 | again. The <span class=SpellE>wR</span> ~18% with some intensity for all the |
---|
1918 | peaks in the pattern, but the magnetic moments are probably wrong. Go to the |
---|
1919 | magnetic phase Atoms tab and select refine <b style='mso-bidi-font-weight:normal'><span |
---|
1920 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1921 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>M</span></b> |
---|
1922 | for all three Co atoms. Do <b style='mso-bidi-font-weight:normal'><span |
---|
1923 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1924 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
1925 | again; the residual drops a bit but now the errors seem to be mostly peak |
---|
1926 | position. Go to the General tab for both phases and check the <b |
---|
1927 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1928 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1929 | minor-latin'>Refine unit cell</span></b> box for each. Then go to Sample |
---|
1930 | parameters for the PWDR data set, set goniometer radius to <b style='mso-bidi-font-weight: |
---|
1931 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1932 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>650</span></b> |
---|
1933 | and check both <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
1934 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
1935 | minor-latin;mso-bidi-theme-font:minor-latin'>Sample X & Y <span |
---|
1936 | class=SpellE>displ</span></span></b> parameters. Do <b style='mso-bidi-font-weight: |
---|
1937 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1938 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
1939 | again; <span class=SpellE>wR</span> ~ 15% now. To finish the refinement, |
---|
1940 | include Instrument parameters <b style='mso-bidi-font-weight:normal'><span |
---|
1941 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1942 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>U, V, W, X, Y |
---|
1943 | and SH/L</span></b>; use <b style='mso-bidi-font-weight:normal'><span |
---|
1944 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1945 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>6</span></b> |
---|
1946 | Background term and refine <b style='mso-bidi-font-weight:normal'><span |
---|
1947 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1948 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>XU</span></b> |
---|
1949 | for all atoms in the chemical phase and <b style='mso-bidi-font-weight:normal'><span |
---|
1950 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1951 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>UM</span></b> |
---|
1952 | in the magnetic phase. After 2-3 sets of <b style='mso-bidi-font-weight:normal'><span |
---|
1953 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
1954 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
1955 | my residual was <span class=SpellE>wR</span>=7.49% and the magnetic atoms |
---|
1956 | showed most of the moment on Co2_1 (<span class=SpellE>Mz</span> = 3.2) with |
---|
1957 | the other two much smaller. </p> |
---|
1958 | |
---|
1959 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1960 | id="Picture_x0020_26" o:spid="_x0000_i1033" type="#_x0000_t75" style='width:356.25pt; |
---|
1961 | height:598.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1962 | <v:imagedata src="Magnetic-III_files/image047.png" o:title=""/> |
---|
1963 | </v:shape><![endif]--><![if !vml]><img border=0 width=475 height=798 |
---|
1964 | src="Magnetic-III_files/image050.gif" v:shapes="Picture_x0020_26"><![endif]></span></p> |
---|
1965 | |
---|
1966 | <p class=MsoNormal>The fit to the powder pattern looks quite good</p> |
---|
1967 | |
---|
1968 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1969 | id="Picture_x0020_27" o:spid="_x0000_i1032" type="#_x0000_t75" style='width:5in; |
---|
1970 | height:282.75pt;visibility:visible;mso-wrap-style:square'> |
---|
1971 | <v:imagedata src="Magnetic-III_files/image049.png" o:title=""/> |
---|
1972 | </v:shape><![endif]--><![if !vml]><img border=0 width=480 height=377 |
---|
1973 | src="Magnetic-III_files/image052.gif" v:shapes="Picture_x0020_27"><![endif]></span></p> |
---|
1974 | |
---|
1975 | <p class=MsoNormal>But we should try the other solution to see if it is better. |
---|
1976 | <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1977 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1978 | minor-latin'>Save</span></b> the project first.</p> |
---|
1979 | |
---|
1980 | <h3>Step 7. Select 2nd magnetic structure</h3> |
---|
1981 | |
---|
1982 | <p class=MsoNormal>To continue the selection process, we need to use the saved |
---|
1983 | project used for the first selection because it contains the table of possible |
---|
1984 | magnetic space groups generated by k-SUBGROUPSMAG. Do <b style='mso-bidi-font-weight: |
---|
1985 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1986 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Open |
---|
1987 | project</span></b> from the main menu and select <b style='mso-bidi-font-weight: |
---|
1988 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
1989 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6.gpx</span></b>; |
---|
1990 | youll see a reminder to save the old project (we just did this) and select the |
---|
1991 | <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
1992 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
1993 | minor-latin'>Ba6Co6</span></b> phase (should be the only one); the General tab |
---|
1994 | will be shown</p> |
---|
1995 | |
---|
1996 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
1997 | id="Picture_x0020_28" o:spid="_x0000_i1031" type="#_x0000_t75" style='width:359.25pt; |
---|
1998 | height:184.5pt;visibility:visible;mso-wrap-style:square'> |
---|
1999 | <v:imagedata src="Magnetic-III_files/image051.png" o:title=""/> |
---|
2000 | </v:shape><![endif]--><![if !vml]><img border=0 width=479 height=246 |
---|
2001 | src="Magnetic-III_files/image054.gif" v:shapes="Picture_x0020_28"><![endif]></span></p> |
---|
2002 | |
---|
2003 | <p class=MsoNormal>Do <b style='mso-bidi-font-weight:normal'><span |
---|
2004 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2005 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Compute/Select |
---|
2006 | magnetic phase</span></b> from the menu; the popup should look like</p> |
---|
2007 | |
---|
2008 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2009 | id="_x0000_i1030" type="#_x0000_t75" style='width:222.75pt;height:222.75pt; |
---|
2010 | visibility:visible;mso-wrap-style:square'> |
---|
2011 | <v:imagedata src="Magnetic-III_files/image031.png" o:title=""/> |
---|
2012 | </v:shape><![endif]--><![if !vml]><img border=0 width=297 height=297 |
---|
2013 | src="Magnetic-III_files/image034.gif" v:shapes="_x0000_i1030"><![endif]></span></p> |
---|
2014 | |
---|
2015 | <p class=MsoNormal>We already tried the 1<sup>st</sup> one; now select the 2<sup>nd</sup> |
---|
2016 | and press OK; a popup will appear</p> |
---|
2017 | |
---|
2018 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2019 | id="_x0000_i1029" type="#_x0000_t75" style='width:283.5pt;height:123.75pt; |
---|
2020 | visibility:visible;mso-wrap-style:square'> |
---|
2021 | <v:imagedata src="Magnetic-III_files/image053.png" o:title=""/> |
---|
2022 | </v:shape><![endif]--><![if !vml]><img border=0 width=378 height=165 |
---|
2023 | src="Magnetic-III_files/image056.gif" v:shapes="_x0000_i1029"><![endif]></span></p> |
---|
2024 | |
---|
2025 | <p class=MsoNormal>It looks very similar to what we had before; close |
---|
2026 | comparison will show these to be shifted on z by Œ. Press <span class=GramE><b |
---|
2027 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2028 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2029 | minor-latin'>Yes</span></b></span> to use them. The project will be saved and a |
---|
2030 | new project <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2031 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2032 | minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6 mag_2.gpx</span></b> will |
---|
2033 | be created. The General tab for this new phase will be shown</p> |
---|
2034 | |
---|
2035 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2036 | id="_x0000_i1028" type="#_x0000_t75" style='width:363.75pt;height:186.75pt; |
---|
2037 | visibility:visible;mso-wrap-style:square'> |
---|
2038 | <v:imagedata src="Magnetic-III_files/image055.png" o:title=""/> |
---|
2039 | </v:shape><![endif]--><![if !vml]><img border=0 width=485 height=249 |
---|
2040 | src="Magnetic-III_files/image090.gif" v:shapes="_x0000_i1028"><![endif]></span></p> |
---|
2041 | |
---|
2042 | <p class=MsoNormal>Select the Atoms tab & set <span class=SpellE>Mz</span> |
---|
2043 | for each Co atom to <b style='mso-bidi-font-weight:normal'><span |
---|
2044 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2045 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>1.0</span></b>. |
---|
2046 | Then do the refinement steps we outlined for the 1<sup>st</sup> magnetic |
---|
2047 | structure. Do <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2048 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2049 | minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> first |
---|
2050 | youll again have to correct he constraints by deleting the duplicate one. |
---|
2051 | Then set the <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2052 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2053 | minor-latin;mso-bidi-theme-font:minor-latin'>M</span></b> refine flags for the |
---|
2054 | magnetic atoms; do <b style='mso-bidi-font-weight:normal'><span |
---|
2055 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2056 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b>. |
---|
2057 | Add <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2058 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2059 | minor-latin'>sample X & Y displacements</span></b> (radius = <b |
---|
2060 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2061 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2062 | minor-latin'>650</span></b>) and both lattice parameters; do <b |
---|
2063 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2064 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2065 | minor-latin'>Calculate/Refine</span></b>. Then add Instrument parameters <b |
---|
2066 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2067 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2068 | minor-latin'>U, V, W, X, Y & SH/L</span></b>; do <b style='mso-bidi-font-weight: |
---|
2069 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2070 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b>. |
---|
2071 | Finally use <b style='mso-bidi-font-weight:normal'><span style='font-family: |
---|
2072 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
---|
2073 | minor-latin;mso-bidi-theme-font:minor-latin'>6</span></b> background |
---|
2074 | coefficients and refine <b style='mso-bidi-font-weight:normal'><span |
---|
2075 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2076 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>XU</span></b> |
---|
2077 | for the chemical phase atoms and <b style='mso-bidi-font-weight:normal'><span |
---|
2078 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2079 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>XUM</span></b> |
---|
2080 | for the magnetic atoms. Do <b style='mso-bidi-font-weight:normal'><span |
---|
2081 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2082 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Calculate/Refine</span></b> |
---|
2083 | a few times until it converges. I got <span class=SpellE>wR</span> = 7.46% |
---|
2084 | which is only slightly better than the result for the first model. In this case |
---|
2085 | the tetrahedral Co atom carries the large magnetic moment while the octahedral |
---|
2086 | ones have nearly zero moment. This is probably the better model because it is |
---|
2087 | similar to the magnetic structures found for related materials. We can see if |
---|
2088 | the moment is fully on the tetrahedral Co; set <span class=SpellE><b |
---|
2089 | style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2090 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2091 | minor-latin'>Mz</span></b></span><b style='mso-bidi-font-weight:normal'><span |
---|
2092 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2093 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>=0</span></b> |
---|
2094 | for the other two and set their refinement flags to just <b style='mso-bidi-font-weight: |
---|
2095 | normal'><span style='font-family:"Calibri",sans-serif;mso-ascii-theme-font: |
---|
2096 | minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>XU</span></b>. |
---|
2097 | Do <b style='mso-bidi-font-weight:normal'><span style='font-family:"Calibri",sans-serif; |
---|
2098 | mso-ascii-theme-font:minor-latin;mso-hansi-theme-font:minor-latin;mso-bidi-theme-font: |
---|
2099 | minor-latin'>Calculate/Refine</span></b>. My final <span class=SpellE>wR</span>=7.462% |
---|
2100 | shows that probably all the magnetic moment is on the tetrahedral Co atoms. The |
---|
2101 | Atoms list </p> |
---|
2102 | |
---|
2103 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2104 | id="Picture_x0020_29" o:spid="_x0000_i1027" type="#_x0000_t75" style='width:361.5pt; |
---|
2105 | height:82.5pt;visibility:visible;mso-wrap-style:square'> |
---|
2106 | <v:imagedata src="Magnetic-III_files/image084.png" o:title=""/> |
---|
2107 | </v:shape><![endif]--><![if !vml]><img border=0 width=482 height=110 |
---|
2108 | src="Magnetic-III_files/image091.gif" v:shapes="Picture_x0020_29"><![endif]></span></p> |
---|
2109 | |
---|
2110 | <p class=MsoNormal><span class=GramE>gives</span> <span class=SpellE>Mz</span>=3.296(35); |
---|
2111 | the <span class=SpellE>esd</span> is from <b style='mso-bidi-font-weight:normal'><span |
---|
2112 | style='font-family:"Calibri",sans-serif;mso-ascii-theme-font:minor-latin; |
---|
2113 | mso-hansi-theme-font:minor-latin;mso-bidi-theme-font:minor-latin'>Ba6Co6 mag_2.lst</span></b>. |
---|
2114 | The structure is then</p> |
---|
2115 | |
---|
2116 | <p class=MsoNormal><span style='mso-no-proof:yes'><!--[if gte vml 1]><v:shape |
---|
2117 | id="Picture_x0020_30" o:spid="_x0000_i1026" type="#_x0000_t75" style='width:177.75pt; |
---|
2118 | height:5in;visibility:visible;mso-wrap-style:square'> |
---|
2119 | <v:imagedata src="Magnetic-III_files/image086.png" o:title=""/> |
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2120 | </v:shape><![endif]--><![if !vml]><img border=0 width=237 height=480 |
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2121 | src="Magnetic-III_files/image092.gif" v:shapes="Picture_x0020_30"><![endif]><!--[if gte vml 1]><v:shape |
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2122 | id="Picture_x0020_31" o:spid="_x0000_i1025" type="#_x0000_t75" style='width:187.5pt; |
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2123 | height:358.5pt;visibility:visible;mso-wrap-style:square'> |
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2124 | <v:imagedata src="Magnetic-III_files/image088.png" o:title=""/> |
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2125 | </v:shape><![endif]--><![if !vml]><img border=0 width=250 height=478 |
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2126 | src="Magnetic-III_files/image093.gif" v:shapes="Picture_x0020_31"><![endif]></span></p> |
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2127 | |
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2128 | <p class=MsoNormal>Ive placed the doubled c-axis chemical structure so you can |
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2129 | see the relationship between them.</p> |
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2130 | |
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2131 | <p class=MsoNormal>If I impose a similar constraint for the 1<sup>st</sup> |
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2132 | model, the final <span class=SpellE>wR</span>=7.524% is slightly higher than for |
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2133 | the 2<sup>nd</sup> model. This concludes this tutorial; you probably want to <span |
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2134 | class=GramE><b style='mso-bidi-font-weight:normal'><span style='font-family: |
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2135 | "Calibri",sans-serif;mso-ascii-theme-font:minor-latin;mso-hansi-theme-font: |
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2136 | minor-latin;mso-bidi-theme-font:minor-latin'>Save</span></b></span> both |
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2137 | projects before closing GSAS-II.</p> |
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2138 | |
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2139 | </div> |
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2140 | |
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2141 | </body> |
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2142 | |
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2143 | </html> |
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